Quantitative 2-D Fuel Distribution Measurements in an SI Engine Using Laser-Induced Fluorescence with Suitable Combination of Fluorescence Tracer and Excitation Wavelength

1997 ◽  
Author(s):  
Taketoshi Fujikawa ◽  
Yoshiaki Hattori ◽  
Kazuhiro Akihama
Photonics ◽  
2021 ◽  
Vol 8 (10) ◽  
pp. 411
Author(s):  
Vasily N. Lednev ◽  
Alexey F. Bunkin ◽  
Sergey M. Pershin ◽  
Mikhail Ya. Grishin ◽  
Diana G. Artemova ◽  
...  

The laser induced fluorescence spectroscopy was systematically utilized for remote sensing of different soils and rocks for the first time, to the best of our knowledge. Laser induced fluorescence spectroscopy measurements were carried out by the developed nanosecond LIDAR instrument with variable excitation wavelength (355, 532 and 1064 nm). LIDAR sensing of different Brazil soil samples have been carried out in order to construct a spectral database. The laser induced fluorescence spectra interpretation for different samples has been discussed in detail. The perspectives of LIDAR sensing of organic samples deposited at soils and rock have been discussed including future space exploration missions in the search for extraterrestrial life.


2021 ◽  
Author(s):  
Ming Xie ◽  
Yunpeng Jia ◽  
Ying Li ◽  
Xiaohua Cai ◽  
Kai Cao

Abstract Laser-induced fluorescence (LIF) is an effective, all-weather oil spill identification method that has been widely applied for oil spill monitoring. However, the distinguishability on oil types is seldom considered while selecting excitation wavelength. This study is intended to find the optimal excitation wavelength for fine-grained classification of refined oil pollutants using LIF by comparing the distinguishability of fluorometric spectra under various excitation wavelengths on some typical types of refined-oil samples. The results show that the fluorometric spectra of oil samples significantly vary under different excitation wavelengths, and the four types of oil applied in this study are most likely to be distinguished under the excitation wavelengths of 395 nm and 420 nm. This study is expected to improve the ability of oil types identification using LIF method without increasing time or other cost, and also provides theoretical basis for the development of portable LIF devices for oil spill identification.


2017 ◽  
Vol 10 (4) ◽  
pp. 1465-1481 ◽  
Author(s):  
Zhenkan Wang ◽  
Sara Lonn ◽  
Alexios Matamis ◽  
Oivind Andersson ◽  
Martin Tuner ◽  
...  

Holzforschung ◽  
2013 ◽  
Vol 67 (5) ◽  
pp. 531-538 ◽  
Author(s):  
Anni Lähdetie ◽  
Paula Nousiainen ◽  
Jussi Sipilä ◽  
Tarja Tamminen ◽  
Anna-Stiina Jääskeläinen

Abstract Raman spectroscopy is a technique that provides structural information on lignin and other components of wood and pulp in situ. However, especially lignin-containing samples may produce laser-induced fluorescence (LIF) that overlaps with Raman bands. In the worst case, this background signal can overwhelm the weaker Raman signal completely. In this study, the LIF of lignin was investigated with the excitation wavelength 532 nm applied in Raman spectroscopy to clarify the correlations between lignin structure and LIF intensity. Raman spectroscopic analyses with lignin model compounds illustrated that the 5-5′ structures induce LIF. It was also shown that the intensity of LIF was significantly less intense when the 5-5′ model compound was structurally rigid (as in dibenzodioxocin) compared with the flexible simple counterpart. The comparison between the free phenolic model compounds with the methylated analogue showed that the presence of the free phenolic structure was not a prerequisite for LIF. It was thus concluded that the conformation of the molecule is the key factor with respect to fluorescence. The role of conformational aspects was further investigated by comparing wood with chemical pulps and isolated lignins.


Author(s):  
Jian Yang ◽  
Wei Gong ◽  
Shuo Shi ◽  
Lin Du ◽  
Jia Sun ◽  
...  

Laser-induced fluorescence (LIF) served as an active technology has been widely used in many field, and it is closely related to excitation wavelength (EW). The objective of this investigation is to discuss the performance of different EWs of LIF LiDAR in identifying plant species. In this study, the 355, 460 and 556 nm lasers were utilized to excite the leaf fluorescence and the fluorescence spectra were measured by using the LIF LiDAR system built in the laboratory. Subsequently, the principal component analysis (PCA) with the help of support vector machine (SVM) was utilized to analyse fluorescence spectra. For the three EWs, the overall identification rates of the six plant species were 80 %, 83.3 % and 90 %. Experimental results demonstrated that 556 nm excitation light source is superior to 355 and 460 nm for the classification of the plant species for the same genus in this study. Thus, an appropriate excitation wavelength should be considered when the LIF LiDAR was utilized in the field of remote sensing based on the LIF technology.


2020 ◽  
Vol 13 (6) ◽  
pp. 3119-3146 ◽  
Author(s):  
Robert Woodward-Massey ◽  
Eloise J. Slater ◽  
Jake Alen ◽  
Trevor Ingham ◽  
Danny R. Cryer ◽  
...  

Abstract. Hydroxyl (OH) and hydroperoxy (HO2) radicals are central to the understanding of atmospheric chemistry. Owing to their short lifetimes, these species are frequently used to test the accuracy of model predictions and their underlying chemical mechanisms. In forested environments, laser-induced fluorescence–fluorescence assay by gas expansion (LIF–FAGE) measurements of OH have often shown substantial disagreement with model predictions, suggesting the presence of unknown OH sources in such environments. However, it is also possible that the measurements have been affected by instrumental artefacts, due to the presence of interfering species that cannot be discriminated using the traditional method of obtaining background signals via modulation of the laser excitation wavelength (“OHwave”). The interference hypothesis can be tested by using an alternative method to determine the OH background signal, via the addition of a chemical scavenger prior to sampling of ambient air (“OHchem”). In this work, the Leeds FAGE instrument was modified to include such a system to facilitate measurements of OHchem, in which propane was used to selectively remove OH from ambient air using an inlet pre-injector (IPI). The IPI system was characterised in detail, and it was found that the system did not reduce the instrument sensitivity towards OH (< 5 % difference to conventional sampling) and was able to efficiently scavenge external OH (> 99 %) without the removal of OH formed inside the fluorescence cell (< 5 %). Tests of the photolytic interference from ozone in the presence of water vapour revealed a small but potentially significant interference, equivalent to an OH concentration of ∼4×105 molec. cm−3 under typical atmospheric conditions of [O3] =50 ppbv and [H2O] =1 %. Laboratory experiments to investigate potential interferences from products of isoprene ozonolysis did result in interference signals, but these were negligible when extrapolated down to ambient ozone and isoprene levels. The interference from NO3 radicals was also tested but was found to be insignificant in our system. The Leeds IPI module was deployed during three separate field intensives that took place in summer at a coastal site in the UK and both in summer and winter in the megacity of Beijing, China, allowing for investigations of ambient OH interferences under a wide range of chemical and meteorological conditions. Comparisons of ambient OHchem measurements to the traditional OHwave method showed excellent agreement, with OHwave vs OHchem slopes of 1.05–1.16 and identical behaviour on a diel basis, consistent with laboratory interference tests. The difference between OHwave and OHchem (“OHint”) was found to scale non-linearly with OHchem, resulting in an upper limit interference of (5.0±1.4) ×106 molec. cm−3 at the very highest OHchem concentrations measured (23×106 molec. cm−3), accounting for ∼14 %–21 % of the total OHwave signal.


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