Lean Breakthrough Phenomena Analysis for TWC OBD on a Natural Gas Engine using a Dual-Site Dynamic Oxygen Storage Capacity Model

2017 ◽  
Author(s):  
Jian Gong ◽  
Di Wang ◽  
Avra Brahma ◽  
Junhui Li ◽  
Neal Currier ◽  
...  
Keyword(s):  
Natural Gas ◽  
Storage Capacity ◽  
Oxygen Storage Capacity ◽  
Oxygen Storage ◽  
Gas Engine ◽  
Natural Gas Engine ◽  
Capacity Model ◽  
Dual Site

Autothermal Reforming of Propane Over Ni Catalysts Supported on a Variety of Perovskites

2007 ◽  
Vol 7 (11) ◽  
pp. 4013-4016 ◽  
Author(s):  
SeungSoo Lim ◽  
DongJu Moon ◽  
JongHo Kim ◽  
YoungChul Kim ◽  
NamCook Park ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Storage Capacity ◽  
Flow Reactor ◽  
Oxygen Storage Capacity ◽  
Autothermal Reforming ◽  
Oxygen Storage ◽  
Hydrogen Yield ◽  
Impregnation Method ◽  
Ni Catalysts ◽  
Atmospheric Flow

Autothermal reforming of propane for hydrogen over Ni catalysts supported on a variety of perovskites was performed in an atmospheric flow reactor. Perovskite is known for its higher thermal stability and oxygen storage capacity, but catalytic activity of itself is low. A sites of the ABO3 structured perovskites were occupied by La while B sites by one of Fe, Co, Ni, and Al by citrate method. The composition of the reactant mixture was H2O/C/O2 = 8.96/1.0/1.1. The changes in the states of the catalysts after reaction were analyzed by XRD, TPD, and TGA. Ni/LaAlO3 catalyst maintained the perovskite structure after reaction. It showed higher hydrogen yield and thermal stability compared to those of the catalysts with Fe, Co, or Ni in B sites. Catalysts prepared by deposition-precipitation (DP) method showed higher activity than those prepared by impregnation method, presumably due to the smaller sizes of the NiO crystal particles.

Measured and Predicted Performance of a Downsized, Medium Duty, Natural Gas Engine

2017 ◽  
Author(s):  
Robert Draper ◽  
Brendan Lenski ◽  
Franz-Joseph Foltz ◽  
Roderick Beazley ◽  
William Tenny
Keyword(s):  
Natural Gas ◽  
Gas Engine ◽  
Natural Gas Engine
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