Air-to-fuel Ratio Modulation Experiments over a Pd/Rh Three-way Catalyst

2001 ◽  
Author(s):  
Stephen J. Cornelius ◽  
Nick Collings ◽  
Keith Glover ◽  
Daniel E. Davison
Author(s):  
N Ladommatos ◽  
D Rose

The mixture strength in a cylinder of a port-injected gasoline engine was monitored continuously during very rapid throttle openings. The data on mixture strength were combined with other engine data collected in order to obtain for each successive engine cycle: the air—fuel ratio within the cylinder and the change in the fuel mass accumulating on the inlet port of the cylinder being monitored. The four-cylinder spark-ignition engine used had a displacement of 1.6 litre, four valves per cylinder and multipoint sequential fuel injection controlled by an electronic management system programmed for three - way catalyst operation. All tests were conducted with the engine coolant at the temperature of 90°C and at a constant engine speed of 2000 r/min. The engine transient involved very rapid throttle openings which were completed within about 15 ms. Small and large throttle openings were investigated along with the effect of altering the type and condition of the fuel injectors. The engine response to the fast throttle opening comprised a sharp rise in the air—fuel ratio (maximum gravimetric air—fuel ratio of around 25:1) which lasted for only a single cycle, followed by a drop in the air-fuel ratio (minimum air—fuel ratio of about 10:1) and, subsequently, a gradual rise towards a stoichiometric air—fuel ratio within about 10 engine cycles.


2010 ◽  
Vol 177 ◽  
pp. 682-685
Author(s):  
Xiao Kun He ◽  
Jin Hu ◽  
Yong Bo Ji ◽  
Wen Yong Yang ◽  
Jia Lin Sun

The three-way catalyst with different cell shape substrates was prepared by the different washcoat loadings. Its catalyst’s light-off characteristics were investigated by the simulating calculation and the engine bench experiment. The experimental results showed that, heat transfer coefficient (Hs) couldn’t be improved by the increase of coating rate, in contrast heat transfer coefficient (Hs) and the catalytic conversion decreased when the coating rate was more than 45%. Therefore, it had some negative effects on the light-off characteristics and air-fuel ratio property. The calculation analyses and the engine bench experiment also proved that the best coating rate was 45% for the substrate of 400cpsi.


Author(s):  
K S Park ◽  
J Park ◽  
S K Kauh ◽  
S T Ro ◽  
J Lee

The jump—ramp control algorithm has been widely adopted for the air—fuel ratio control in a fuel injection spark ignition (SI) engine by using a conventional on—off type oxygen sensor. But the jump—ramp control method has limitations in improving the frequency and amplitude of the air—fuel ratio oscillation. This study suggests a new feedback control logic called modulated fuel feedback control, which has a concept of pretuned air—fuel ratio oscillation. In the modulation method, the oxygen sensor output is not treated as on—off but as an analogue for feedback. By using the modulation method, the frequency and amplitude of the air—fuel ratio oscillation can be controllable to some extent to improve the conversion efficiency of a three-way catalyst. The results show that the performance of the modulation method is better than that of the jump—ramp control method in reducing the amplitude of the air—fuel ratio oscillation as well as in increasing the frequency of the air—fuel ratio oscillation.


Author(s):  
Abdullah-al Mamun ◽  
Qilun Zhu ◽  
Mark Hoffman ◽  
Simona Onori

The Current practice of air-fuel ratio control relies on empirical models and traditional PID controllers, which require extensive calibration to maintain the post-catalyst air-fuel ratio close to stoichiometry. In contrast, this work utilizes a physics-based Three-Way Catalyst (TWC) model to develop a model predictive control (MPC) strategy for air-fuel ratio control based on internal TWC oxygen storage dynamics. In this paper, parameters of the physics-based temperature and oxygen storage models of the TWC are identified using vehicle test data for a catalyst aged to 150,000 miles. A linearized oxygen storage model is then developed from the identified nonlinear model, which is shown via simulation to follow the nonlinear model with minimal error during nominal operation. This motivates the development of a Linear MPC (LMPC) framework using the linearized TWC oxygen storage model, reducing the requisite computational effort relative to a nonlinear MPC strategy. In this work, the LMPC utilizing a linearized physics-based TWC model is proven suitable for tracking a desired oxygen storage level by controlling the commanded engine air-fuel ratio, which is also a novel contribution. The offline simulation results show successful tracking performance of the developed LMPC framework.


2020 ◽  
Vol 4 (1) ◽  
pp. 5-19
Author(s):  
Marcin Noga ◽  
Paweł Gorczyca ◽  
Radosław Hebda

Research on the effects of the use of the range extender developed for a small commercial electric vehicle was presented in this paper. The range extender has a maximum output power of 2.65 kW. The developed auxiliary power unit consists of a three-phase generator propelled by an industrial low-power spark-ignition engine. The exhaust system was improved using a more efficient muffler. The implemented motorcycle muffler has a three-way catalyst (TWC) integrated inside. The use of the more advanced exhaust system aimed at reducing noise and exhaust emissions of the range extender. The efficient operation of the three-way catalytic converter requires a stoichiometric air-fuel ratio. To enable desired air-fuel ratio a fuel system was modified. In the first stage of research, the effects of improvements of the exhaust system on the range extender noise emissions were quantified. The next step covered the research of the fuel conversion efficiency, the exhaust gas composition, and the efficiency of conversion of the three-way catalyst. A significant decrease of noise and toxic gas emissions and an increase in the fuel conversion efficiency were revealed. The mentioned research was conducted in stationary conditions. After that, in the final part research of the running vehicle with the range extender on was made. The beneficial outcome of these tests enabled the development of a set of rules of the control of the range extender.


2018 ◽  
Vol 4 (3) ◽  
pp. 136-142 ◽  
Author(s):  
Andrew Bean Getsoian ◽  
Joseph R. Theis ◽  
Christine K. Lambert

MRS Bulletin ◽  
2001 ◽  
Vol 26 (11) ◽  
pp. 885-889 ◽  
Author(s):  
Maria Flytzani-Stephanopoulos

Catalysts based on cerium oxide are now used as effective oxidation systems in numerous environmental applications. Cerium oxide was introduced into the catalysis field relatively recently, in 1976, and not as a catalyst initially. Rather, it was chosen as the key oxygen-storage component of the three-way catalyst (TWC) used in automotive exhausts. Accordingly, ceria is used to extend the air/fuel ratio window in the exhaust gas, releasing or accepting oxygen, respectively, under fuel-rich or fuellean conditions, so that the noble metal catalyst operates at the desirable stoichiometric air/fuel ratio, at which it effectively converts all three gaseous pollutants—CO, hydrocarbons, and NO—to innocuous products. A solid solution of cerium and zirconium oxides is used in today's catalytic converters because of its higher oxygen-storage capacity (OSC) compared with pure ceria. In the years that followed the introduction of ceria into the catalytic converter, many additional merits of cerium oxide were realized, first as an active catalytic component of the TWC and subsequently as a catalyst and sorbent in various industrial applications. A review article by Trovarelli on ceria-based catalysts is a good recent compilation.


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