scholarly journals Highly Dispersed Cu-Base Catalyst Derived from Layered Double Hydroxides for CO Hydrogenation

2014 ◽  
Vol 02 (06) ◽  
pp. 1-3
Author(s):  
Xinyou Han ◽  
Kegong Fang ◽  
Minggui Lin ◽  
Yuhan Sun
Keyword(s):  
Layered Double Hydroxides ◽  
Co Hydrogenation ◽  
Base Catalyst ◽  
Highly Dispersed ◽  
Double Hydroxides

Selective hydrogenation of 2-pentenal using highly dispersed Pt catalysts supported on ZnSnAl mixed metal oxides derived from layered double hydroxides

2020 ◽  
Vol 10 (4) ◽  
pp. 1106-1116
Author(s):  
Huanjun Wang ◽  
Xiaocheng Lan ◽  
Shiqing Wang ◽  
Babar Ali ◽  
Tiefeng Wang
Keyword(s):  
Metal Oxides ◽  
Layered Double Hydroxides ◽  
Selective Hydrogenation ◽  
High Selectivity ◽  
Mixed Metal Oxides ◽  
Pt Catalysts ◽  
Mixed Metal ◽  
Highly Dispersed ◽  
Double Hydroxides

Highly dispersed Pt catalysts supported on ZnSnAl mixed metal oxides showed high selectivity for 2-pentenol in selective hydrogenation of 2-pentenal.

Acceptorless amine dehydrogenation and transamination using Pd-doped layered double hydroxides

2018 ◽  
Author(s):  
Diana Ainembabazi ◽  
Nan An ◽  
Jinesh Manayil ◽  
Kare Wilson ◽  
Adam Lee ◽  
...  
Keyword(s):  
Layered Double Hydroxides ◽  
Oxidation States ◽  
Secondary Amines ◽  
Primary Amines ◽  
Acid Dissolution ◽  
Oxidative Amination ◽  
Strong Function ◽  
Excellent Activity ◽  
High Yields ◽  
Double Hydroxides

<div> <p>The synthesis, characterization, and activity of Pd-doped layered double hydroxides (Pd-LDHs) for for acceptorless amine dehydrogenation is reported. These multifunctional catalysts comprise Brønsted basic and Lewis acidic surface sites that stabilize Pd species in 0, 2+, and 4+ oxidation states. Pd speciation and corresponding cataytic performance is a strong function of metal loading. Excellent activity is observed for the oxidative transamination of primary amines and acceptorless dehydrogenation of secondary amines to secondary imines using a low Pd loading (0.5 mol%), without the need for oxidants. N-heterocycles, such as indoline, 1,2,3,4-tetrahydroquinoline, and piperidine, are dehydrogenated to the corresponding aromatics with high yields. The relative yields of secondary imines are proportional to the calculated free energy of reaction, while yields for oxidative amination correlate with the electrophilicity of primary imine intermediates. Reversible amine dehydrogenation and imine hydrogenation determine the relative imine:amine selectivity. Poisoning tests evidence that Pd-LDHs operate heterogeneously, with negligible metal leaching; catalysts can be regenerated by acid dissolution and re-precipitation.</p> </div> <br>

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