scholarly journals Enhanced High-Temperature Cycling Stability of LiMn<SUB>2</SUB>O<SUB>4</SUB> by LiCoO<SUB>2</SUB> Coating as Cathode Material for Lithium Ion Batteries

2014 ◽  
Vol 02 (12) ◽  
pp. 12-18 ◽  
Author(s):  
Jing Yan ◽  
Haohan Liu ◽  
Yuelei Wang ◽  
Xinxin Zhao ◽  
Yiming Mi ◽  
...  
Ionics ◽  
2015 ◽  
Vol 21 (7) ◽  
pp. 1835-1842 ◽  
Author(s):  
Jing Yan ◽  
Haohan Liu ◽  
Yuelei Wang ◽  
Xinxin Zhao ◽  
Yiming Mi ◽  
...  

Ionics ◽  
2019 ◽  
Vol 26 (3) ◽  
pp. 1181-1187
Author(s):  
Ting-ting Lv ◽  
Zheng-guang Zou ◽  
Yan-wei Li ◽  
Shu-chao Zhang

Materials ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4751
Author(s):  
Lian-Bang Wang ◽  
He-Shan Hu ◽  
Wei Lin ◽  
Qing-Hong Xu ◽  
Jia-Dong Gong ◽  
...  

Lithium-rich manganese oxide is a promising candidate for the next-generation cathode material of lithium-ion batteries because of its low cost and high specific capacity. Herein, a series of xLi2MnO3·(1 − x)LiMnO2 nanocomposites were designed via an ingenious one-step dynamic hydrothermal route. A high concentration of alkaline solution, intense hydrothermal conditions, and stirring were used to obtain nanoparticles with a large surface area and uniform dispersity. The experimental results demonstrate that 0.072Li2MnO3·0.928LiMnO2 nanoparticles exhibit a desirable electrochemical performance and deliver a high capacity of 196.4 mAh g−1 at 0.1 C. This capacity was maintained at 190.5 mAh g−1 with a retention rate of 97.0% by the 50th cycle, which demonstrates the excellent cycling stability. Furthermore, XRD characterization of the cycled electrode indicates that the Li2MnO3 phase of the composite is inert, even under a high potential (4.8 V), which is in contrast with most previous reports of lithium-rich materials. The inertness of Li2MnO3 is attributed to its high crystallinity and few structural defects, which make it difficult to activate. Hence, the final products demonstrate a favorable electrochemical performance with appropriate proportions of two phases in the composite, as high contents of inert Li2MnO3 lower the capacity, while a sufficient structural stability cannot be achieved with low contents. The findings indicate that controlling the composition through a dynamic hydrothermal route is an effective strategy for developing a Mn-based cathode material for lithium-ion batteries.


2013 ◽  
Vol 39 (3) ◽  
pp. 3087-3094 ◽  
Author(s):  
Yan-Rong Zhu ◽  
Ting-Feng Yi ◽  
Rong-Sun Zhu ◽  
An-Na Zhou

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