scholarly journals Visible Light Photoelectrocatalytic Degradation of Rhodamine B Using Ti/TiO2-NiO Photoanode

2014 ◽  
Vol 05 (17) ◽  
pp. 1630-1640 ◽  
Author(s):  
Sayekti Wahyuningsih ◽  
Candra Purnawan ◽  
Teguh Endah Saraswati ◽  
Edi Pramono ◽  
Ari Handono Ramelan ◽  
...  
2014 ◽  
Vol 68 (9) ◽  
Author(s):  
Sayekti Wahyuningsih ◽  
Candra Purnawan ◽  
Puspa Kartikasari ◽  
Novita Praistia

AbstractTitanium dioxide is a promising catalyst for application in the photodegradation of organic pollutants in water due to its powerful oxidising property and long-term photostability. This study presents the production of titanium dioxide using the sol-gel process, dye sensitisation of the TiO2 electrode, and the performance of that cell. Sensitisation of titanium dioxide was performed using a dye, i.e., Fe(II)-polypyridyl complexes. The photoelectrocatalytic degradation of rhodamine B (RB) using ITO/TiO2/dye as electrode was investigated via a series of potentials, from +1.0 V to −1.0 V, and at various pH and NaCl concentration values (ITO is indium tin oxide conductive glass). The photoelectrocatalytic degradation of RB was performed with a visible light lamp. The change in the absorbance of RB with various potentials indicated that the absorbance of RB in solution systems with the sensitised TiO2 electrodes decreased with increasing anodic potential bias. The degradation cell exhibited better performance when the positive anodic bias was applied. The pH values of RB in solution systems also influence the photoelectrodegradation process because of the different RB species present. NaCl concentration also affects the activity of RB photoelectrocatalytic degradation due to changes in the ionic strength character of the electrolyte.


Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2206
Author(s):  
Gaoqian Yuan ◽  
Gen Zhang ◽  
Kezhuo Li ◽  
Faliang Li ◽  
Yunbo Cao ◽  
...  

Loading a noble metal on Bi4Ti3O12 could enable the formation of the Schottky barrier at the interface between the former and the latter, which causes electrons to be trapped and inhibits the recombination of photoelectrons and photoholes. In this paper, AgPt/Bi4Ti3O12 composite photocatalysts were prepared using the photoreduction method, and the effects of the type and content of noble metal on the photocatalytic performance of the catalysts were investigated. The photocatalytic degradation of rhodamine B (RhB) showed that the loading of AgPt bimetallic nanoparticles significantly improved the catalytic performance of Bi4Ti3O12. When 0.10 wt% noble metal was loaded, the degradation rate for RhB of Ag0.7Pt0.3/Bi4Ti3O12 was 0.027 min−1, which was respectively about 2, 1.7 and 3.7 times as that of Ag/Bi4Ti3O12, Pt/Bi3Ti4O12 and Bi4Ti3O12. The reasons may be attributed as follows: (i) the utilization of visible light was enhanced due to the surface plasmon resonance effect of Ag and Pt in the visible region; (ii) Ag nanoparticles mainly acted as electron acceptors to restrain the recombination of photogenerated electron-hole pairs under visible light irradiation; and (iii) Pt nanoparticles acted as electron cocatalysts to further suppress the recombination of photogenerated electron-hole pairs. The photocatalytic performance of Ag0.7Pt0.3/Bi4Ti3O12 was superior to that of Ag/Bi4Ti3O12 and Pt/Bi3Ti4O12 owing to the synergistic effect between Ag and Pt nanoparticles.


2021 ◽  
Vol 4 (2) ◽  
pp. 1149-1161 ◽  
Author(s):  
Ana Rovisco ◽  
Rita Branquinho ◽  
Jonas Deuermeier ◽  
Tomás Freire ◽  
Elvira Fortunato ◽  
...  

Author(s):  
Asim Ali Yaqoob ◽  
Nur Habibah binti Mohd Noor ◽  
Khalid Umar ◽  
Rohana Adnan ◽  
Mohamad Nasir Mohamad Ibrahim ◽  
...  

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