scholarly journals Rhodium Nanoparticle-Loaded Carbon Black Electrocatalyst for the Glycerol Oxidation Reaction in Alkaline Medium

2016 ◽  
Vol 05 (01) ◽  
pp. 60-66 ◽  
Author(s):  
Binh Thi Xuan Lam ◽  
Masanobu Chiku ◽  
Eiji Higuchi ◽  
Hiroshi Inoue
Keyword(s):  
Carbon Black ◽  
Alkaline Medium ◽  
Oxidation Reaction ◽  
Glycerol Oxidation ◽  
Rhodium Nanoparticle

scholarly journals PtAg Nanoparticle Electrocatalysts for the Glycerol Oxidation Reaction in Alkaline Medium

2016 ◽  
Vol 05 (03) ◽  
pp. 167-175 ◽  
Author(s):  
Binh Thi Xuan Lam ◽  
Masanobu Chiku ◽  
Eiji Higuchi ◽  
Hiroshi Inoue
Keyword(s):  
Alkaline Medium ◽  
Oxidation Reaction ◽  
Glycerol Oxidation

Mechanism of glycerol oxidation reaction on silver-modified palladium electrode in alkaline medium

2018 ◽  
Vol 43 (40) ◽  
pp. 18664-18671 ◽  
Author(s):  
Hiroshi Inoue ◽  
Shohei Kimura ◽  
Yuki Teraoka ◽  
Masanobu Chiku ◽  
Eiji Higuchi ◽  
...  
Keyword(s):  
Alkaline Medium ◽  
Oxidation Reaction ◽  
Glycerol Oxidation ◽  
Palladium Electrode

Adsorption and Oxidation of Thiosulfate on the Platinum Electrode in a Slightly Alkaline Medium

2000 ◽  
Vol 65 (1) ◽  
pp. 1-8 ◽  
Author(s):  
Tomáš Loučka
Keyword(s):  
Alkaline Medium ◽  
Oxidation Reaction ◽  
Open Circuit Potential ◽  
Platinum Electrode ◽  
Adsorbed Layer ◽  
Open Circuit ◽  
Adsorbed Hydrogen ◽  
Oxidation Number ◽  
Hydrogen Electrode ◽  
Layer Region

The aim of this research was to study the oxidation and reduction of the adsorbed thiosulfate on the platinum electrode in a slightly alkaline medium. The adsorption was performed at the open circuit conditions. The reduction of the adsorbed layer in the hydrogen region is slower in a slightly alkaline medium than in acid. The mechanism of reduction and oxidation of adsorbed molecules is probably the same. The nonstationary currents measured in presence of thiosulfates showed that the change in the oxidation number does not take place during the adsorption in the double layer region. In the hydrogen region, thiosulfate replaces the adsorbed hydrogen while beeing reduced. Nonstationary currents at higher concentrations of thiosulfate indicate the presence of more layers on the electrode. Upon reaching higher concentrations of thiosulfate the oxidation reaction takes place between thiosulfate in solution and adsorbed product of its reduction. The open circuit potential of the platinum electrode measured in a thiosulfate solution was 0.780 and 0.783 V against the hydrogen electrode in the same solution.

Glycerol Oxidation Assisted Electrochemical CO2 Reduction for the Dual Production of Formate

2021 ◽  
Author(s):  
Yuhou Pei ◽  
Zhenfeng Pi ◽  
Heng Zhong ◽  
Jiong Cheng ◽  
Fangming Jin
Keyword(s):  
Redox Potential ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Oxidation Reaction ◽  
Co2 Reduction ◽  
Glycerol Oxidation ◽  
Electrochemical Co2 Reduction ◽  
Organic Oxidation

The sluggish oxygen evolution reaction (OER) is one of the main bottlenecks for efficient CO2 electroreduction (CO2ER). Seeking a suitable organic oxidation reaction with a lower redox potential to replace...

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