Use of ion exchange membrane to assess soil N supply to canola as affected by addition of liquid swine manure and urea

2000 ◽  
Vol 80 (1) ◽  
pp. 213-218 ◽  
Author(s):  
P. Qian ◽  
J. J. Schoenau

A growth chamber study was conducted using two Saskatchewan soils to evaluate how addition of urea and swine manure affects the supply of plant-available nitrogen (ammonium and nitrate) and its relationship with plant N uptake. Treatments consisted of two different N rates applied as urea and manure (100 and 800 mg N kg−1) and a control. Ion exchange membrane probes were used to measure plant-available N supply rate. Canola was grown under the same environmental conditions to determine plant N uptake. Additions of fertilizer and manure significantly increased the supply of plant-available N measured in the soil. Over an 84-d period the available N supply in the manured soil was about 40% lower than in the urea-fertilized soil at equivalent rates of total N addition due to incomplete mineralization of organic N in the manure. However, plant N uptake was similar between manure and urea-treated soils, which was attributed to other nutrients present in the manure that may have enhanced root growth and plant N uptake. High proportions of ammonium N were measured initially, especially at the high rates of urea and manure. However, inorganic N in the form of ammonium rapidly decreased with time and nitrate N became the main inorganic N form supplied. Overall, there was good correlation (r value 0.79 to 0.96) between plant N uptake and available N supply rate in the soil as measured by ion exchange membrane. Key words: Ion exchange membrane, available N supply rate, urea, swine manure, canola, plant N uptake

2004 ◽  
Vol 34 (3) ◽  
pp. 754-761 ◽  
Author(s):  
Ryan D Hangs ◽  
Ken J Greer ◽  
Catharine A Sulewski

During the early establishment phase, outplanted white spruce (Picea glauca (Moench) Voss) and jack pine (Pinus banksiana Lamb.) seedlings are vulnerable to lethargic growth or mortality because of interspecific competition for soil nutrients, particularly N. Accurately quantifying the degree of N competition is essential for supporting effective vegetation management (VM) decisions. This study evaluated the use of in situ burials of ion-exchange membrane (IEM; Plant Root SimulatorTM-probes) for quantifying differences in soil N supply rate between different VM treatments and the relationship of this N availability index to early growth of conifer seedlings at four boreal forest sites. At most sites, the effect of noncrop N uptake on soil N availability was apparent, with smaller NH4+-N, NO3–-N, and total dissolved inorganic N (DIN) supply rates in control plots than in VM plots. Total DIN supply rate was correlated (R2 = 0.60 to 0.73, P < 0.01) with seedling height, root-collar diameter, and stem volume growth. Ammonium-N supply rate was better correlated than NO3–-N supply rate with conifer seedling growth, which is in agreement with preferential NH4+-N uptake by conifer species. The results of this study support the use of in situ burials of IEM for measuring soil N availability during the early establishment phase.


2021 ◽  
Vol 629 ◽  
pp. 119271
Author(s):  
Jiří Charvát ◽  
Petr Mazúr ◽  
Martin Paidar ◽  
Jaromír Pocedič ◽  
Jiří Vrána ◽  
...  

Membranes ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 400
Author(s):  
Hajime Kamebuchi ◽  
Satoshi Tamaki ◽  
Atsushi Okazawa ◽  
Norimichi Kojima

The development and the photophysical behavior of a transparent ion-exchange membrane based on a pH-sensitive polypyridyl ruthenium(II) complex, [(bpy)2RuII(H2bpib)RuII(bpy)2](ClO4)4 (bpy = 2,2′-bipyridine, H2bpib = 1,4-bis([1,10]phenanthroline[5,6-d]-imidazol-2-yl)benzene), are experimentally and theoretically reported. The emission spectra of [(bpy)2RuII(H2bpib)RuII(bpy)2]@Nafion film were observed between pH 2 and pH 11 and showed the highest relative emission intensity at pH 5 (λmaxem = 594.4 nm). The relative emission intensity of the film significantly decreased down to 75% at pH 2 and 11 compared to that of pH 5. The quantum yields (Φ) and lifetimes (τ) showed similar correlations with respect to pH, Φ = 0.13 and τ = 1237 ns at pH 5, and Φ = 0.087 and τ = 1014 ns and Φ = 0.069 and τ = 954 ns at pH 2 and pH 11, respectively. These photophysical data are overall considerably superior to those of the solution, with the radiative- (kr) and non-radiative rate constants (knr) at pH 5 estimated to be kr = 1.06 × 105 s−1 and knr = 7.03 × 105 s−1. Density functional theory calculations suggested the contribution of ligand-to-ligand- and intraligand charge transfer to the imidazolium moiety in Ru-H3bpib species, implying that the positive charge on the H3bpib ligand works as a quencher. The Ru-Hbpib species seems to enhance non-radiative deactivation by reducing the energy of the upper-lying metal-centered excited state. These would be responsible for the pH-dependent “off-on-off” emission behavior.


RSC Advances ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 4210-4220
Author(s):  
Mohd. Zeeshan ◽  
Rais Ahmad ◽  
Asif Ali Khan ◽  
Aftab Aslam Parwaz Khan ◽  
Guillermo C. Bazan ◽  
...  

A polycarbazole-Sn(iv) arsenotungstate (Pcz-SnAT) nanocomposite cation exchanger membrane (CEM) was prepared via the casting solution technique utilizing polycarbazole-Sn(iv) arsenotungstate and PVC (polyvinyl chloride) as a binder.


1981 ◽  
Vol 18 (5-6) ◽  
pp. 899-905 ◽  
Author(s):  
I. Ishigaki ◽  
T. Sugo ◽  
K. Senoo ◽  
T. Takayama ◽  
S. Machi ◽  
...  

1987 ◽  
Vol 60 (6) ◽  
pp. 2215-2219 ◽  
Author(s):  
Yutaka Hirata ◽  
Masashi Date ◽  
Yukiko Yamamoto ◽  
Akira Yamauchi ◽  
Hideo Kimizuka

Sign in / Sign up

Export Citation Format

Share Document