CINÉTIQUE ET MÉCANISME DE L'HYDROLYSE ACIDE DE LA MATIÈRE ORGANIQUE D'UN SOL HUMIFÈRE DE MONTAGNE

1987 ◽  
Vol 67 (3) ◽  
pp. 647-658 ◽  
Author(s):  
E. BARRIUSO ◽  
J. M. PORTAL ◽  
F. ANDREUX
Keyword(s):  
Acid Hydrolysis ◽  
Fulvic Acids ◽  
Mineral Surfaces ◽  
Humic And Fulvic Acids ◽  
Carbon And Nitrogen ◽  
Fine Clay ◽  
Humification Degree ◽  
The Stability ◽  
Kinetics Of ◽  
Stable Material

From the surface horizon of an organic-rich mountain soil, humic and fulvic acids, and organo-mineral compounds including clay and hydroxy-metal colloids, were separated and purified. Each of these fractions was hydrolyzed in 3.0 M HCl under reflux, then the reaction parameters related to the solubilization of carbon and nitrogen and to the kinetics of hydrolysis were calculated. Acid hydrolysis was interpreted as the result of two successive steps: first a rapid electrophilic attack of heteroatomic C-O and C-N bonds by protons, then a slow nucleophilic hydration of the protonated bonds. Electron delocalization in these bonds, which increased with the polycondensation degree of organic compounds, and with their adsoprtion on mineral surfaces, resulted in an increase in their stability to hydrolysis. Fulvic acids were found to be the less stable material, and lead to predominantly anionic hydrolysis products. Clay-sized humin was the most stable material and yielded mainly cationic hydrolysates. The stability to hydrolysis and the humification degree of organic matter in the fractions generally coincided, and decreased in the following order: fine clay-sized humin > alkali dispersible organo-mineral colloids > > humic acids > hydroxy-ferric organic colloids > hydroxy-aluminium organic colloids = fulvic acids. Key words: Organo-mineral complex, humic substances, acid hydrolysis, carbon, nitrogen

Extraction Kinetics of Humic and Fulvic Acids in the Rotor-Stator Device

2017 ◽  
Vol 23 (2) ◽  
pp. 265-273 ◽  
Author(s):  
M. A. Promtov ◽  
◽  
A. Yu. Stepanov ◽  
A. V. Aleshin ◽  
◽  
...  
Keyword(s):  
Fulvic Acids ◽  
Extraction Kinetics ◽  
Humic And Fulvic Acids ◽  
Kinetics Of

Kinetics of Various 99mTc-Sn-Pyrophosphate Compounds in the Rat

1977 ◽  
Vol 16 (04) ◽  
pp. 157-162 ◽  
Author(s):  
C. Schümichen ◽  
B. Mackenbrock ◽  
G. Hoffmann
Keyword(s):  
Normal Saline ◽  
Half Life ◽  
Compound A ◽  
Short Half Life ◽  
Low Concentrations ◽  
The Stability ◽  
Kinetics Of ◽  
In Vitro Stability

SummaryThe bone-seeking 99mTc-Sn-pyrophosphate compound (compound A) was diluted both in vitro and in vivo and proved to be unstable both in vitro and in vivo. However, stability was much better in vivo than in vitro and thus the in vitro stability of compound A after dilution in various mediums could be followed up by a consecutive evaluation of the in vivo distribution in the rat. After dilution in neutral normal saline compound A is metastable and after a short half-life it is transformed into the other 99mTc-Sn-pyrophosphate compound A is metastable and after a short half-life in bone but in the kidneys. After dilution in normal saline of low pH and in buffering solutions the stability of compound A is increased. In human plasma compound A is relatively stable but not in plasma water. When compound B is formed in a buffering solution, uptake in the kidneys and excretion in urine is lowered and blood concentration increased.It is assumed that the association of protons to compound A will increase its stability at low concentrations while that to compound B will lead to a strong protein bond in plasma. It is concluded that compound A will not be stable in vivo because of a lack of stability in the extravascular space, and that the protein bond in plasma will be a measure of its in vivo stability.

Evaluation of the Properties of Humus Liquid of Earthworm Eisenia Foetida Obtained from Different Rachis

2017 ◽  
Vol 3 (02) ◽  
Author(s):  
Ramiro Remigio Gaibor Fernández ◽  
Abraham Adalberto Bayas Zamora ◽  
Galo Israel Muñoz Sánchez ◽  
Cristhian Adrián Rivas Santacruz
Keyword(s):  
Plant Growth ◽  
Fulvic Acids ◽  
Cattle Manure ◽  
Eisenia Foetida ◽  
Humic And Fulvic Acids ◽  
Livestock Manure ◽  
A Value ◽  
The One ◽  
Liquid Slurry

The objective of the present investigation was to evaluate the physical characteristics of the vermicompost and the quality of the purine of the red Californian (Eisenia foetida) using different substrates of feed for these worms. For this purpose, nine treatments were studied: 75% African palm rachis + 25% cattle manure, 50% African palm rachis + 50% cattle manure, 25% African palm rachis + 75% livestock manure, 50% manure of cattle, 50% of manure of cattle, 25% of manure of cattle, 50% of manure of cattle, 50% of manure of cattle, 50% of rach of coconut + 50% of manure of Livestock, 25% coccus rachis + 75% livestock manure. The substrate made up of 50% of rachis of coconut and 50% of livestock manure can be used in nurseries or nurseries for being the one that registered a value of pH 7.3 plus the closest to the neutral compared to the others, besides this (75% of oil palm rachis and 25% of cattle manure) showed a higher content of humic and fulvic acids (0.87 and 0.45 p / p, respectively), compounds that are important for agriculture by stimulating plant growth, in addition to this reflection 0.06% sulfur content, 4.0 ppm boron, 7.0 ppm copper, 47.5 ppm iron, 6.0 ppm manganese, with a presence of microorganisms of the species Trichoderma, Penicillium, Cladosporium sp. in amounts of 1.91x105 UFC / ml, however in this substrate was obtained between 13.3 and 43.5% less liquid slurry in Comparison with other treatments.

The impact of humic and fulvic acids on the dynamic properties of liposome membranes: the ESR method

2013 ◽  
Vol 24 (2) ◽  
pp. 106-112 ◽  
Author(s):  
Dariusz Man ◽  
Izabella Pisarek ◽  
Michał Braczkowski ◽  
Barbara Pytel ◽  
Ryszard Olchawa
Keyword(s):  
Dynamic Properties ◽  
Fulvic Acids ◽  
Humic And Fulvic Acids ◽  
The Impact

Modeling of sorption kinetics of U(VI) micro-quantities nanostructured materials with anatase mesoporous structures

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Veniamin Zheleznov ◽  
Aleksey Golikov ◽  
Tatiana Sokolnitskaya ◽  
Sergey Ivannikov
Keyword(s):  
Nanostructured Materials ◽  
Sorption Kinetics ◽  
Uranyl Ion ◽  
Competitive Sorption ◽  
Hydroxyl Groups ◽  
Complex Ions ◽  
The Stability ◽  
Kinetics Of ◽  
Mesoporous Structures ◽  
Ionic Forms

Abstract The sorption kinetics of uranyl ions micro-quantities from fluoride solutions by nanostructured materials with anatase mesoporous structures has been studied. Using the model of competitive sorption of ions and positively charged complexes of uranyl ion on deprotonated hydroxyl groups of an anatase, kinetic curves of changes in the ratio of ionic forms of uranium in solution were calculated. Modeling was carried out under the assumption of a two-stage mechanism of uranium complex ions sorption. The modeling considered the influence of the uranyl ion carbonate complexes formation. The shift in equilibrium among ionic forms of uranyl correlates with the stability of the complexes in solution.

Degradation kinetics of 4-amino naphthalene-1-sulfonic acid by a biofilm-forming bacterial consortium under carbon and nitrogen limitations

2012 ◽  
Vol 39 (8) ◽  
pp. 1169-1177 ◽  
Author(s):  
C. Juárez-Ramírez ◽  
R. Velázquez-García ◽  
N. Ruiz-Ordaz ◽  
J. Galíndez-Mayer ◽  
O. Ramos Monroy
Keyword(s):  
Sulfonic Acid ◽  
Degradation Kinetics ◽  
Bacterial Consortium ◽  
Carbon And Nitrogen ◽  
Kinetics Of

scholarly journals Experimental Study on the Softening Characteristics of Sandstone and Mudstone in Relation to Moisture Content

2017 ◽  
Vol 2017 ◽  
pp. 1-14 ◽  
Author(s):  
Gui-chen Li ◽  
Chong-chong Qi ◽  
Yuan-tian Sun ◽  
Xiao-lin Tang ◽  
Bao-quan Hou
Keyword(s):  
Moisture Content ◽  
Vertical Displacement ◽  
Surface Porosity ◽  
Shear Tests ◽  
Moisture Contents ◽  
Dynamic Finite Element ◽  
Rock Types ◽  
Underground Roadway ◽  
The Stability ◽  
Kinetics Of

The kinetics of fluid-solid coupling during immersion is an important topic of investigation in rock engineering. Two rock types, sandstone and mudstone, are selected in this work to study the correlation between the softening characteristics of the rocks and moisture content. This is achieved through detailed studies using scanning electron microscopy, shear tests, and evaluation of rock index properties during exposure to different moisture contents. An underground roadway excavation is simulated by dynamic finite element modeling to analyze the effect of moisture content on the stability of the roadway. The results show that moisture content has a significant effect on shear properties reduction of both sandstone and mudstone, which must thus be considered in mining or excavation processes. Specifically, it is found that the number, area, and diameter of micropores, as well as surface porosity, increase with increasing moisture content. Additionally, stress concentration is negatively correlated with moisture content, while the influenced area and vertical displacement are positively correlated with moisture content. These findings may provide useful input for the design of underground roadways.

Sign in / Sign up

Export Citation Format

Share Document