CATION EXCHANGE CAPACITIES AND SURFACE AREAS OF HUMIC GLEYSOLIC Ap HORIZONS FROM SOUTHWESTERN ONTARIO

1982 ◽  
Vol 62 (2) ◽  
pp. 291-296 ◽  
Author(s):  
L. J. EVANS
Keyword(s):  
Organic Matter ◽  
Regression Analysis ◽  
Cation Exchange ◽  
Multiple Regression Analysis ◽  
Surface Area ◽  
Cation Exchange Capacity ◽  
Exchange Capacity ◽  
Organic C ◽  
Surface Areas ◽  
A Value

Thirty-four samples from the Ap horizons of heavy-textured Orthic Humic Gleysols (Typic Haplaquolls) were sampled in southwestern Ontario. Surface areas of the soils ranged from 79–223 m2/g and multiple regression analysis indicated that the surface area of the clay fractions was 207 m2/g and that of the organic matter 805 m2/g. Approximately 74% of the variability in cation exchange capacity could be attributed to their clay and organic C contents at pH 4 and about 86% at pH 8. A value of 181 meq/100 g was calculated as the cation exchange capacity of organic matter at pH 4 and of 316 meq/100 g at pH 8. Mean cation exchange capacities at pH 4 were 20.3 meq/100 g and 31.6 meq/100 g at pH 8.

A note on resolving soil cation exchange capacity into ‘mineral’ and ‘organic’ fractions

1970 ◽  
Vol 75 (2) ◽  
pp. 365-367 ◽  
Author(s):  
T. M. Addiscott
Keyword(s):  
Hydrogen Peroxide ◽  
Organic Matter ◽  
Regression Analysis ◽  
Cation Exchange ◽  
Multiple Regression Analysis ◽  
Cation Exchange Capacity ◽  
Exchange Capacity ◽  
Before And After ◽  
Organic Fractions ◽  
Soil Cation Exchange Capacity

Two methods have been used previously to resolve the ‘mineral’ and ‘organic’ fractions of the cation exchange capacities of soils. Williams (1932) and Hallsworth & Wilkinson (1958) used multiple regression analysis to relate cation exchange capacity (CEC) in several soils to percentage organic matter (OM) and percentage clay, and thence to calculate the average values of the CECs of OM and clay. For individual soils, Davies & Davies (1965) and Clark & Nichol (1968) measured the CEC before and after oxidizing the OM with hydrogen peroxide.

Trifluralin Interactions with Soil Constituents

Weed Science ◽  
1971 ◽  
Vol 19 (1) ◽  
pp. 11-16 ◽  
Author(s):  
R. L. Hollist ◽  
C. L. Foy
Keyword(s):  
Organic Matter ◽  
Cation Exchange ◽  
Surface Area ◽  
Anion Exchange ◽  
Cation Exchange Capacity ◽  
Active Sites ◽  
Foxtail Millet ◽  
Exchange Capacity ◽  
Anion Exchange Capacity ◽  
Nutrient Culture

Concentrations ofα,α,α-trifluoro-2,6-dinitro-N,N-dipropyl-p-toluidine (trifluralin) causing 50% growth reduction (hereinafter referred to as GR50) were determined in nutrient culture and 64 simulated soils using foxtail millet (Setaria italica(L.) Beau.) as an indicator species. The relative order of effectiveness of soil components in reducing trifluralin phytotoxicity was steamed organic matter ≫ organic matter ≫ steamed montomorillonite ≥ steamed kaolinite ≃ kaolinite ≃ montmorillonite. Steaming the organic matter more than doubled the anion exchange capacity. Anion exchange capacity was a better parameter than cation exchange capacity for assessing the potential of an adsorbent to reduce phytotoxicity. Surface area, cation exchange capacity, and adsorption of trifluralin from solution were less reliable indices. The effectiveness of organic matter in reducing phytotoxicity may be due to the exchange capacity and high surface area. Montomorillonite apparently interacted synergistically with other adsorbents to reduce phytotoxicity. Trifluralin did not adsorb on the internal surfaces of montmorillonite as judged by surface area comparisons and X-ray diffraction determinations. Increasing moisture content appeared to block the active sites of trifluralin adsorption. This may be concluded from greater vapor movement and decreased adsorption from a xylene solvent system for moist compared to air dry soils.

scholarly journals Effect of Low Zeolite Doses on Plants and Soil Physicochemical Properties

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2617
Author(s):  
Alicja Szatanik-Kloc ◽  
Justyna Szerement ◽  
Agnieszka Adamczuk ◽  
Grzegorz Józefaciuk
Keyword(s):  
Plant Growth ◽  
Physicochemical Properties ◽  
Cation Exchange ◽  
Surface Area ◽  
Cation Exchange Capacity ◽  
N Fertilization ◽  
Exchange Capacity ◽  
First Year ◽  
Soil Physicochemical Properties ◽  
Water Holding

Thousands of tons of zeolitic materials are used yearly as soil conditioners and components of slow-release fertilizers. A positive influence of application of zeolites on plant growth has been frequently observed. Because zeolites have extremely large cation exchange capacity, surface area, porosity and water holding capacity, a paradigm has aroused that increasing plant growth is caused by a long-lasting improvement of soil physicochemical properties by zeolites. In the first year of our field experiment performed on a poor soil with zeolite rates from 1 to 8 t/ha and N fertilization, an increase in spring wheat yield was observed. Any effect on soil cation exchange capacity (CEC), surface area (S), pH-dependent surface charge (Qv), mesoporosity, water holding capacity and plant available water (PAW) was noted. This positive effect of zeolite on plants could be due to extra nutrients supplied by the mineral (primarily potassium—1 ton of the studied zeolite contained around 15 kg of exchangeable potassium). In the second year of the experiment (NPK treatment on previously zeolitized soil), the zeolite presence did not impact plant yield. No long-term effect of the zeolite on plants was observed in the third year after soil zeolitization, when, as in the first year, only N fertilization was applied. That there were no significant changes in the above-mentioned physicochemical properties of the field soil after the addition of zeolite was most likely due to high dilution of the mineral in the soil (8 t/ha zeolite is only ~0.35% of the soil mass in the root zone). To determine how much zeolite is needed to improve soil physicochemical properties, much higher zeolite rates than those applied in the field were studied in the laboratory. The latter studies showed that CEC and S increased proportionally to the zeolite percentage in the soil. The Qv of the zeolite was lower than that of the soil, so a decrease in soil variable charge was observed due to zeolite addition. Surprisingly, a slight increase in PAW, even at the largest zeolite dose (from 9.5% for the control soil to 13% for a mixture of 40 g zeolite and 100 g soil), was observed. It resulted from small alterations of the soil macrostructure: although the input of small zeolite pores was seen in pore size distributions, the larger pores responsible for the storage of PAW were almost not affected by the zeolite addition.

Characteristics of variably saturated granular bentonite after long-term storage at near-field relevant temperatures

Clay Minerals ◽  
2013 ◽  
Vol 48 (2) ◽  
pp. 343-361 ◽  
Author(s):  
M. Valter ◽  
M. Plötze
Keyword(s):  
Physicochemical Properties ◽  
Cation Exchange ◽  
Surface Area ◽  
Cation Exchange Capacity ◽  
Elevated Temperatures ◽  
Near Field ◽  
Exchange Capacity ◽  
Hydraulic Permeability ◽  
Cation Composition ◽  
Retention Capacity

AbstractBentonite is a potential material for use in the engineered barrier of radioactive waste repositories because of its low hydraulic permeability, self-sealing capability and retention capacity. It is expected that bentonite would react at the elevated temperatures accompanying the radioactive decay in the nuclear waste. The presented study was started in order to improve understanding of the coupled influence of temperature and (pore) water on the physicochemical and mineralogical properties of bentonite during thermal treatment under near-field relevant conditions. Granular Na-bentonite MX-80 was differently saturated (Sr = 1–0.05) and stored at different temperatures (50–150°C) in a closed system. Upon dismantling after different periods of time (3 to 18 months), mineralogical characteristics, cation exchange capacity and content of leachable cations, as well as physicochemical properties such as surface area and water adsorption were investigated.The results showed a high mineralogical stability. A slight conversion from the sodium to an earth alkali form of the bentonite was observed. However, considerable changes in the physicochemical properties of the bentonite were observed, particularly by treatment above the critical temperature of 120°C. The cation exchange capacity decreased during heating at 150°C by approximately. 10%. The specific surface area dropped by more than 50%. The water uptake capacity under free swelling conditions showed a slight tendency to lower values especially for samples heated for more than 12 months. The water vapour adsorption ability in contrast drops by 25% already within three months at T = 120°C. These changes are mostly related to the variations in the interlayer cation composition and to smectite aggregation processes. The observed alterations are rather subtle. However, temperatures ⩾ 120°C had a remarkable negative influence on different properties of MX-80.

scholarly journals Boundary between Soil and Saprolite in Alisols in the South of Brazil

2015 ◽  
Vol 39 (3) ◽  
pp. 643-653 ◽  
Author(s):  
Fabrício de Araújo Pedron ◽  
Rodrigo Bomicieli de Oliveira ◽  
Ricardo Simão Diniz Dalmolin ◽  
Antonio Carlos de Azevedo ◽  
Ricardo Vargas Kilca
Keyword(s):  
Cation Exchange ◽  
Transition Zone ◽  
Cation Exchange Capacity ◽  
Analytical Data ◽  
Ammonium Oxalate ◽  
Exchange Capacity ◽  
Morphological Properties ◽  
Organic C ◽  
Rock Structure ◽  
Shallow Soils

Despite numerous studies conducted on the lower limit of soil and its contact with saprolite layers, a great deal of work is left to standardize identification and annotation of these variables in the field. In shallow soils, the appropriately noting these limits or contacts is essential for determining their behavior and potential use. The aims of this study were to identify and define the field contact and/or transition zone between soil and saprolite in profiles of an Alisol derived from fine sandstone and siltstone/claystone in subtropical southern Brazil and to subsequently validate the field observations through a multivariate analysis of laboratory analytical data. In the six Alisol profiles evaluated, the sequence of horizons found was A, Bt, C, and Cr, where C was considered part of the soil due to its pedogenetic structure, and Cr was considered saprolite due to its rock structure. The morphological properties that were determined in the field and that were different between the B and C horizons and the Cr layer were color, structure, texture, and fragments of saprolite. According to the test of means, the properties that support the inclusion of the C horizon as part of the soil are sand, clay, water-dispersible clay, silt/clay ratio, macroporosity, total porosity, resistance to penetration, cation exchange capacity, Fe extracted by DCB, Al, H+Al, and cation exchange capacity of clay. The properties that support the C horizon as a transition zone are silt, Ca, total organic C, and Fe extracted by ammonium oxalate. Discriminant analysis indicated differences among the three horizons evaluated.

Cation exchange capacity of loess and overlying soil in the non-carbonate loess sections, North-Western Croatia

2013 ◽  
Vol 5 (4) ◽  
Author(s):  
Nenad Tomašić ◽  
Štefica Kampić ◽  
Iva Cindrić ◽  
Kristina Pikelj ◽  
Mavro Lučić ◽  
...  
Keyword(s):  
Organic Matter ◽  
Cation Exchange ◽  
Transition Zone ◽  
Cation Exchange Capacity ◽  
Clay Fraction ◽  
Sample Pretreatment ◽  
Loess Soil ◽  
Exchange Capacity ◽  
Oxalate Extraction ◽  
North Western

AbstractThe adsorption properties in terms of cation exchange capacity and their relation to the soil and sediment constituents (clay minerals, Fe-, Mn-, and Al-oxyhydroxides, organic matter) were investigated in loess, soil-loess transition zone, and soil at four loess-soil sections in North-Western Croatia. Cation exchange capacity of the bulk samples, the samples after oxalate extraction of Fe, Mn and Al, and after removal of organic matter, as well as of the separated clay fraction, was determined using copper ethylenediamine. Cation exchange capacity (pH∼7) of the bulk samples ranges from 5 to 12 cmolc/kg in soil, from 7 to 15 cmolc/kg in the soil-loess transition zone, and from 12 to 20 cmolc/kg in loess. Generally, CEC values increase with depth. Oxalate extraction of Fe, Mn, and Al, and removal of organic matter cause a CEC decrease of 3–38% and 8–55%, respectively, proving a considerable influence of these constituents to the bulk CEC values. In the separated clay fraction (<2 μm) CEC values are up to several times higher relative to those in the bulk samples. The measured CEC values of the bulk samples generally correspond to the clay mineral content identified. Also, a slight increase in muscovite/illite content with depth and the vermiculite occurrence in the loess horizon are concomitant with the CEC increase in deeper horizons, irrespective of the sample pretreatment.

Sign in / Sign up

Export Citation Format

Share Document