INORGANIC SOIL PHOSPHORUS FRACTIONS OF SOME ONTARIO SOILS AS STUDIED USING ISOTOPIC EXCHANGE AND SOLUBILITY CRITERIA

1962 ◽  
Vol 42 (1) ◽  
pp. 150-156 ◽  
Author(s):  
A. F. MacKenzie

The water soluble and inorganic phosphates associated with aluminum (Al-P), iron (Fe-P) and calcium (Ca-P) were studied in eight Ontario soils. Isotopic exchange studies indicated that in most of the soils the Al-P fraction was in equilibrium with the water soluble phosphorus. Exceptions were thought to be a result of high or low pH values. Solubility studies in 0.01M CaCl2 indicated that the Al-P fraction supplied most of the phosphorus to the soil solution. In one soil the Fe-P fraction may have supplied a measurable amount of phosphorus to the soil solution also.

Holzforschung ◽  
2006 ◽  
Vol 60 (6) ◽  
pp. 678-684 ◽  
Author(s):  
Gunnar Almkvist ◽  
Ingmar Persson

Abstract In 2000, salt precipitates were found on surfaces of the Swedish warship Vasa, accompanied by low pH values, partly as a result of oxidation of accumulated sulfur compounds. One hypothesis is that oxidation of the sulfur compounds was catalysed by the large amounts of diverse iron compounds present in the wood. It is therefore of interest to develop a method to extract the iron compounds and simultaneously neutralise the acids. The iron compounds could be extracted using an aqueous solution of ethylenediimino-bis(2-hydroxy-4-methylphenyl)acetic acid (EDDHMA) or diethylenetriamine penta-acetic acid (DTPA) at alkaline pH, leaving only small amounts of iron compounds. The polyethylene glycol (PEG) used as the conservation agent, salts and other water-soluble compounds were co-extracted. The extraction rate was enhanced by stirring and by higher concentrations of the chelator, but diffusion of compounds through the wood was the most important factor for the overall extraction efficiency. Extraction of iron compounds from deep inside the wood is time-consuming and may take years. The results from this study imply that aqueous extraction with strong chelators at relatively high pH, 9–11, effectively removes iron compounds and neutralises the acids present. Although the results are promising, it is still too early to start major re-conservation of Vasa wood using extraction, as all the effects on the wood are not known, but such studies are in progress.


2011 ◽  
Vol 77 (10) ◽  
pp. 3406-3412 ◽  
Author(s):  
Gino Vrancken ◽  
Luc De Vuyst ◽  
Tom Rimaux ◽  
Joke Allemeersch ◽  
Stefan Weckx

ABSTRACTSourdough is a very competitive and challenging environment for microorganisms. Usually, a stable microbiota composed of lactic acid bacteria (LAB) and yeasts dominates this ecosystem. Although sourdough is rich in carbohydrates, thus providing an ideal environment for microorganisms to grow, its low pH presents a particular challenge. The nature of the adaptation to this low pH was investigated forLactobacillus plantarumIMDO 130201, an isolate from a laboratory wheat sourdough fermentation. Batch fermentations were carried out in wheat sourdough simulation medium, and total RNA was isolated from mid-exponential-growth-phase cultures, followed by differential gene expression analysis using a LAB functional gene microarray. At low pH values, an increased expression of genes involved in peptide and amino acid metabolism was found as well as that of genes involved in plantaricin production and lipoteichoic acid biosynthesis. The results highlight cellular mechanisms that allowL. plantarumto function at a low environmental pH.


1970 ◽  
Vol 73 (5) ◽  
pp. 874-878 ◽  
Author(s):  
Takao YOTSUYANAGI ◽  
Katsumi GOTO ◽  
Masaichi NAGAYAMA
Keyword(s):  
Low Ph ◽  

2018 ◽  
Vol 93 (4) ◽  
Author(s):  
Ezequiel Dantas ◽  
Fernando Erra Díaz ◽  
Pehuén Pereyra Gerber ◽  
Augusto Varese ◽  
Diana Alicia Jerusalinsky ◽  
...  

ABSTRACTHistidine-rich glycoprotein (HRG) is an abundant plasma protein with a multidomain structure, allowing its interaction with many ligands, including phospholipids, plasminogen, fibrinogen, IgG antibodies, and heparan sulfate. HRG has been shown to regulate different biological responses, such as angiogenesis, coagulation, and fibrinolysis. Here, we found that HRG almost completely abrogated the infection of Ghost cells, Jurkat cells, CD4+T cells, and macrophages by HIV-1 at a low pH (range, 6.5 to 5.5) but not at a neutral pH. HRG was shown to interact with the heparan sulfate expressed by target cells, inhibiting an early postbinding step associated with HIV-1 infection. More importantly, by acting on the viral particle itself, HRG induced a deleterious effect, which reduces viral infectivity. Because cervicovaginal secretions in healthy women show low pH values, even after semen deposition, our observations suggest that HRG might represent a constitutive defense mechanism in the vaginal mucosa. Of note, low pH also enabled HRG to inhibit the infection of HEp-2 cells and Vero cells by respiratory syncytial virus (RSV) and herpes simplex virus 2 (HSV-2), respectively, suggesting that HRG might display broad antiviral activity under acidic conditions.IMPORTANCEVaginal intercourse represents a high-risk route for HIV-1 transmission. The efficiency of male-to-female HIV-1 transmission has been estimated to be 1 in every 1,000 episodes of sexual intercourse, reflecting the high degree of protection conferred by the genital mucosa. However, the contribution of different host factors to the protection against HIV-1 at mucosal surfaces remains poorly defined. Here, we report for the first time that acidic values of pH enable the plasma protein histidine-rich glycoprotein (HRG) to strongly inhibit HIV-1 infection. Because cervicovaginal secretions usually show low pH values, our observations suggest that HRG might represent a constitutive antiviral mechanism in the vaginal mucosa. Interestingly, infection by other viruses, such as respiratory syncytial virus and herpes simplex virus 2, was also markedly inhibited by HRG at low pH values, suggesting that extracellular acidosis enables HRG to display broad antiviral activity.


1962 ◽  
Vol 40 (1) ◽  
pp. 1019-1024 ◽  
Author(s):  
Seiichi Yoshida

A water-soluble pigment excreted from Serratia marcescens has been purified by precipitation with ammonium sulphate, dialysis, and ultracentrifugation at different pH values. The purified pigment showed a single band in the ultracentrifuge and by electrophoretic analysis at several pH values. An average molecular weight of 5 × 106 was calculated from light-scattering measurements. This pigment is composed of carbohydrate and protein combined with prodigiosin, and several properties of the complex are described.


2018 ◽  
Vol 21 (0) ◽  
Author(s):  
Melicia Cintia Galdeano ◽  
Allan Eduardo Wilhelm ◽  
Isabella Borges Goulart ◽  
Renata Valeriano Tonon ◽  
Otniel Freitas-Silva ◽  
...  

Abstract Ozone has been used for many years to disinfect water due to its oxidizing potential. Since it decomposes quickly into molecular oxygen, leaving no residue, it has important advantages for use. The decomposition of ozone is affected by the temperature and pH of the medium, low pH values and temperatures increasing its half-life, which can result in more efficient disinfection. With the objective of increasing the effectiveness of ozonation, this study investigated the effect of temperature (8 ºC and 25 °C) and pH (3.0 and 6.0) of the water on the saturation time and gas concentration, employing two initial gas concentrations (13.3 and 22.3 mg L-1). The concentration of ozone saturation increased as the temperature and pH of the medium decreased, as also with the higher initial gas concentration ( C0). The highest saturation concentrations were obtained at pH 3.0 and 8 °C (4.50 and 8.03 mg L-1 with C0 of 13.3 and 22.3 mg L-1, respectively). This higher ozone content could result in greater decontamination efficiency of the food products washed with this water.


SPE Journal ◽  
2017 ◽  
Vol 22 (05) ◽  
pp. 1467-1477 ◽  
Author(s):  
Mobin Salasi ◽  
Thunyaluk Pojtanabuntoeng ◽  
Sindee Wong ◽  
Marc Lehmann

Summary This study investigates the oxygen-scavenging behavior of bisulfite ions in monoethylene glycol (MEG)/water mixtures at concentrations commonly found in gas-transportation pipelines. Temperatures and pH values were varied. The influence of transition-metal (TM) ions to catalyze the bisulfite oxygen scavenging was studied. Experimental results indicate that MEG significantly inhibits bisulfite oxygen removal, which is hindered at low pH values and, to some extent, temperature. TMs can accelerate the oxygen-scavenging reaction in pH-unadjusted solutions, although the rate was still lower than that of the pH-adjusted solutions. The possible mechanism for such behavior and industrial implications are discussed.


2014 ◽  
Vol 78 (7) ◽  
pp. 1671-1675 ◽  
Author(s):  
Adam J. Roper ◽  
Peter Leverett ◽  
Timothy D. Murphy ◽  
Peter A. Williams

AbstractSynthesis and solubility studies of onoratoite have been undertaken to determine the role of this rare secondary phase in the immobilization of Sb and the conditions responsible for its formation in the supergene zone. Solubility studies were undertaken at 298.15 K. A value of ΔGfθ (Sb8O11Cl2, s, 298.15 K) = –2576 ±12 kJ mol–1 was derived. Calculations involving sénarmontite, Sb2O3, klebelsbergite, Sb4O4SO4(OH)2 and schafarzikite, FeSb2O4, show that onoratoite is a thermodynamically stable phase only at negligible activities of SO42–(aq) and low activities of Fe2+(aq), at low pH and very high activities of Cl–(aq). This explains why onoratoite is such a rare secondary phase and why it cannot exert any significant influence on the dispersion of Sb in the supergene environment.


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