scholarly journals Fast measurement by infrared spectroscopy as support to woody biofuels quality determination

2016 ◽  
Vol 47 (1) ◽  
pp. 17 ◽  
Author(s):  
Daniele Duca ◽  
Andrea Pizzi ◽  
Manuela Mancini ◽  
Giorgio Rossini ◽  
Chiara Mengarelli ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Wood Chip ◽  
Principal Component ◽  
Calorific Value ◽  
International Standards ◽  
Biofuel Production ◽  
Production Chain ◽  
Biomass Quality ◽  
Fast Measurement ◽  
Solid Biofuel

The increase in the demand for energy supply during the past few decades has brought and will bring to a growth in the utilisation of renewable resources, in particular of solid biomasses. Considering the variability in the properties of biomass and the globalisation of the timber market, a chemical and physical characterisation is essential to determine the biomass quality. The specific international standards on solid biofuels (ISO 17225 series) describe proper specification and classification of wood chip and pellet, to ensure appropriate quality. Moreover, standard requires information about origin and source of the biomass, normally only to be declared by the producers. In order to fulfill the requirements for the biomass quality, the origin and the source should be assessed, even if currently is hard to determine, in particular on milled or densified biomass. Infrared spectroscopy can provide information on the biomass at the chemical level, directly linked also to its origin and source. This technique is fast and not destructive thus suitable also for online monitoring along the biofuel production chain. In this study, 60 samples belonging to 8 different species were collected and related spectra were acquired using a Fourier transform infrared (IR) spectrometer equipped with a module for solid analysis and analysed by principal component analysis. The results obtained show that the method is very efficient in the identification between coniferous and deciduous wood (99% confidence level) and good results were obtained in the recognition of coniferous/deciduous mixtures, too. Nevertheless, some clear differences have been also noted among intra-class grouping, but additional tests should be carried out. This technique can provide useful information to solid biofuel stakeholders about wood quality and origin, important especially for sustainability issues. Further work will be oriented to the development of IR methodologies for the fast measurement of other important biomass parameters (<em>e.g.</em>, ash content, high calorific value, nitrogen content, <em>etc</em>.).

scholarly journals USE OF CASTOR OIL PLANT PIE FOR SOLID BIOFUEL PRODUCTION

2019 ◽  
Vol 8 (3) ◽  
Author(s):  
Paula Martucheli Amaral ◽  
Luciano Donizeti Varanda ◽  
Gabriela Tami Nakashima ◽  
Pâmela Beatriz Moreira De Oliveira ◽  
Luis Ricardo Oliveira Santos ◽  
...  
Keyword(s):  
Castor Oil ◽  
Mechanical Test ◽  
Calorific Value ◽  
Biofuel Production ◽  
Residual Oil ◽  
Heating Value ◽  
High Heating Value ◽  
Solid Biofuel ◽  
High Heating ◽  
Oil Plant

The objective of this study was the characterization, analysis and compaction of residues from castor oil plant pie extraction to verify its potential as solid biofuel. The chemical analysis, the mechanical test and the gross calorific value had satisfactory results. With the extraction of residual oil of the material there was a decrease on the high heating value. The produced briquettes presented good longitudinal expansion as well as mechanical strenght, however the presence of residual oil had influence on their strenght. In conclusion, the castor oil plant pie possesses  energetic characteristics suitable for solid biofuel production, in addition it contributes with the reduction of industrial waste amount.

scholarly journals Biomass as a major component of pellets

2018 ◽  
pp. 81-92
Author(s):  
Monika Smaga ◽  
Grzegorz Wielgosiński ◽  
Aleksander Kochański ◽  
Katarzyna Korczak
Keyword(s):  
Production Line ◽  
Calorific Value ◽  
High Energy ◽  
Legal Aspects ◽  
Quality Parameters ◽  
Biofuel Production ◽  
Technical Aspects ◽  
Pellet Production ◽  
Solid Biofuel ◽  
Composite Pellets

The article describes the quality parameters of the selected elements of biomass as a potential ecological biofuel. Several selected elements of a type of biomass were tested to determine the calorific value, humidity, content of sulfur and amount of ash produced in burning process. The concept of biomass and the legal aspects of its combustion are described. The research of biomass samples revealed that they may be turned into a high-energy, ecologically solid biofuel. Production of biofuel from the tested biomass does not require any additional binders. Studies have shown that the tested material can also act as a component of composite pellets. The quality parameters of such pellets can be determined with the composite calculator that is described in this article. The article also describes the technical aspects of the pellet production line, which should be applied to produce good-quality pellets from the tested types of biomass.

scholarly journals Assessment of Guava (Psidium Guajava L.) Wood Biomass for Briquettes’ Production

Forests ◽  
2018 ◽  
Vol 9 (10) ◽  
pp. 613 ◽  
Author(s):  
Tatiana Ivanova ◽  
Amilkar Mendoza Hernández ◽  
Jiří Bradna ◽  
Eloy Fernández Cusimamani ◽  
Juan García Montoya ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Chemical Elements ◽  
Chemical Properties ◽  
Calorific Value ◽  
Wood Properties ◽  
Psidium Guajava ◽  
Ash Content ◽  
International Standards ◽  
Published Data ◽  
Solid Biofuel

Residual biomass from guava (Psidium guajava L.), a common and widespread fruit tree native to Latin America, has been analyzed in the present research in order to determine the biomass quality and its potential use for energy purposes. Obtained biomass was grinded and compacted into the form of fuel briquettes. Determinations of solid biofuel parameters, i.e., physical, mechanical and chemical properties such as calorific value, moisture, ash content, volatile matter, mechanical durability, contents of the main chemical elements and heavy metals were performed according to international standards. As a result, not inconsiderable traces of heavy metals were found, with a concentration of zinc 4.57 mg kg−1 as the highest. Guava’s moisture content (9.8%) comfortably fulfilled the minimum standard requirements and the net calorific value as received (17.11 MJ kg−1) met the average value of a wood. However, measured sulphur content (0.063%) as well as ash content (3.74%) exceeded the maximum allowed limits for the graded wood briquettes and, therefore, guava wood briquettes should be rather categorized as non-woody A class briquettes. The results of the study can contribute significantly to the knowledge of guava wood properties and its potential as renewable solid fuel since there is little published data about it.

scholarly journals Possibilities for Using Waste Hemp Straw for Solid Biofuel Production

2021 ◽  
Vol 9 (1) ◽  
pp. 18
Author(s):  
Jakub Frankowski ◽  
Dominika Sieracka
Keyword(s):  
Calorific Value ◽  
Heat Of Combustion ◽  
Biofuel Production ◽  
Waste Biomass ◽  
Solid Biofuel

Hemp biomass is useful in many branches of the economy. Hemp cultivation to obtain seeds has been gaining importance recently. In this process, shredded straw is a waste biomass which can be used for energy purposes. The possibilities for using waste hemp straw for solid biofuel production are described in this extended abstract, using the example of the Henola variety. The analyzed biomass was characterized by a high content of cellulose (over 40%) and hemicellulose (almost 30%), as well as a high calorific value (18,300 kJ·kg−1) and heat of combustion (17,100 kJ·kg−1).

QUALIDADE DOS PELLETS DE BIOMASSA FLORESTAL PRODUZIDOS EM SANTA CATARINA PARA A GERAÇÃO DE ENERGIA

FLORESTA ◽  
2015 ◽  
Vol 45 (4) ◽  
pp. 833 ◽  
Author(s):  
Alana Spanhol ◽  
Daniela Letícia Nones ◽  
Fabricio Junki Blanco Kumabe ◽  
Martha Andreia Brand
Keyword(s):  
Moisture Content ◽  
Forest Biomass ◽  
Calorific Value ◽  
Quality Standards ◽  
International Standards ◽  
Santa Catarina ◽  
Production Chain ◽  
Fines Content ◽  
Mechanical Durability ◽  
Pinus Spp

Este estudo objetivou determinar as propriedades físicas, químicas e energéticas de pellets de biomassa residual de Pinus spp. produzidos em Santa Catarina, e realizar a comparação com os parâmetros estabelecidos pelas normas internacionais existentes. Foram coletadas nove amostras, onde foram determinadas as propriedades de: dimensões dos pellets, densidade aparente e da unidade, teor de umidade, análise imediata, poder calorífico, durabilidade mecânica e teor de finos. Comparativamente à literatura e aos parâmetros de qualidade das normas: os pellets apresentaram densidade aparente (663,46 kg/m³), densidade da unidade (1711 kg / m³), durabilidade mecânica (99,07%) e poder calorífico superior (20,21 MJ / kg) altos; teor de umidade (7,89%) e de cinzas (0,38%) baixos, indicando boa qualidade dos pellets. Os pellets apresentaram alto teor de finos (1,05%), como característica negativa. Tiveram diâmetro de 6,58 mm; comprimento de 17,31 mm; teor de materiais voláteis de 81,29% e carbono fixo de 18,33%. Os valores médios das propriedades dos pellets atenderam plenamente as normas alemã (DIN Plus) e austríaca (Önorm M7135) e as classes G2 e G3 da suéca (SS 187120), e as classes I1, I2 e I3 da ISO (17225-2), podendo ser usados no setor de serviços e indústrias.AbstractQuality of forest biomass pellets produced in State of Santa Catarina for power generation. This study aimed to determine the physical, chemical and energetic properties of pellets of residual forest biomass of Pinus spp. production chain from the state of Santa Catarina, and compare them to the parameters set by existing international standards. Nine samples were collected, in which the properties were determined: size of pellets; bulk density and unity density; moisture content; immediate analysis; calorific value; mechanical durability and fines content. Compared to literature and quality standards parameters: the pellets showed high apparent density (663.46 kg / m³), unit density (1711 kg / m³), mechanical durability (99.07%) and gross calorific value (20.21 MJ / kg); low moisture content (7.89%) and ash (0.38%), indicating good quality pellets. The pellets had a high fines content (1.05%), as a negative characteristic. They had diameter of 6.58 mm; length 17.31 mm; volatiles content of 81.29% and 18.33% fixed carbon. The average values of properties of the pellets fully met the German standards (DIN Plus) and Austria (ÖNORM M7135) and G2 and G3 classes of Swedish (SS 187 120), and the classes I1, I2 and I3 ISO (17225-2), and can be used in the service and industry sectors.Keywords: Pinus waste; densified; pellet quality standards. 

scholarly journals Exploring the possibilities of infrared spectroscopy for urine sediment examination and detection of pathogenic bacteria in urinary tract infections

2020 ◽  
Vol 58 (10) ◽  
pp. 1759-1767
Author(s):  
Mieke Steenbeke ◽  
Sander De Bruyne ◽  
Jerina Boelens ◽  
Matthijs Oyaert ◽  
Griet Glorieux ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Urinary Tract ◽  
Urinary Tract Infections ◽  
Pathogenic Bacteria ◽  
Agar Plate ◽  
Principal Component ◽  
Blood Agar Plate ◽  
Urine Sediment ◽  
Flight Mass Spectrometry ◽  
Tract Infections

AbstractObjectivesIn this study, the possibilities of Fourier-transformed infrared spectroscopy (FTIR) for analysis of urine sediments and for detection of bacteria causing urinary tract infections (UTIs) were investigated.MethodsDried urine specimens of control subjects and patients presenting with various nephrological and urological conditions were analysed using mid-infrared spectroscopy (4,000–400 cm−1). Urine samples from patients with a UTI were inoculated on a blood agar plate. After drying of the pure bacterial colonies, FTIR was applied and compared with the results obtained by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS). Chemometric data analysis was used to classify the different species.ResultsDue to the typical molecular assignments of lipids, proteins, nucleic acids and carbohydrates, FTIR was able to identify bacteria and showed promising results in the detection of proteins, lipids, white and red blood cells, as well as in the identification of crystals. Principal component analysis (PCA) allowed to differentiate between Gram-negative and Gram-positive species and soft independent modelling of class analogy (SIMCA) revealed promising classification ratios between the different pathogens.ConclusionsFTIR can be considered as a supplementary method for urine sediment examination and for detection of pathogenic bacteria in UTI.

Simultaneous implementation of sludge dewatering and solid biofuel production by microwave torrefaction

2021 ◽  
Vol 195 ◽  
pp. 110775
Author(s):  
Congyu Zhang ◽  
Shih-Hsin Ho ◽  
Wei-Hsin Chen ◽  
Chun Fong Eng ◽  
Chin-Tsan Wang
Keyword(s):  
Biofuel Production ◽  
Sludge Dewatering ◽  
Solid Biofuel ◽  
Simultaneous Implementation

scholarly journals Electrical Capacitance Characteristics of Wood Chips at Low Frequency Ranges: A Cheap Tool for Quality Assessment

Sensors ◽  
2021 ◽  
Vol 21 (10) ◽  
pp. 3494
Author(s):  
Jakub Lev ◽  
Václav Křepčík ◽  
Egidijus Šarauskis ◽  
František Kumhála
Keyword(s):  
Moisture Content ◽  
Linear Models ◽  
Economic Value ◽  
Wood Chip ◽  
Principal Component ◽  
Dissipation Factor ◽  
Industrial Applications ◽  
Wood Chips ◽  
Electrical Capacitance ◽  
Low Frequencies

Moisture content is one of the most important parameters related to the quality of wood chips that affects both the calorific and economic value of fuel chips. For industrial applications, moisture content needs to be detected quickly. For this purpose, various indirect moisture content measurement methods (e.g., capacitance, NIR, microwave, ECT, X-ray CT, and nuclear MR) have been investigated with different results in the past. Nevertheless, determining wood chip moisture content in real time is still a challenge. The main aim of this article was therefore to analyze the dielectric properties of wood chips at low frequencies (10 kHz–5 MHz) and to examine the possibility of using these properties to predict wood chip moisture content and porosity. A container-type probe was developed for this purpose. The electrical capacitance and dissipation factor of wood chips with different moisture content was measured by an LCR meter at 10 kHz, 50 kHz, 100 kHz, 500 kHz, 1 MHz, and 5 MHz frequencies. Wood chip porosity was also measured using a gas displacement method. Linear models for moisture content and porosity prediction were determined by backward stepwise linear regression. Mathematical model was developed to better understand the physical relationships between moisture content, porosity, and electrical capacitance. These models were able to predict the moisture content of observed quantities of wood chips with the required accuracy (R2 = 0.9−0.99). This finding opens another path to measuring the moisture content and porosity of wood chips in a relatively cheap and fast way and with adequate precision. In addition, principal component analysis showed that it is also possible to distinguish between individual wood chip fraction sizes from the information obtained.

PHARMACEUTICAL FORMULATION MANUFACTURER DISCRIMINATION BY INFRARED SPECTROSCOPY AND PRINCIPAL COMPONENT ANALYSIS

2019 ◽  
pp. 7-15
Author(s):  
E.M. Basova ◽  
Yu.N. Litvinenko ◽  
N.А. Polotnyanko
Keyword(s):  
Principal Component Analysis ◽  
Infrared Spectroscopy ◽  
Ir Spectroscopy ◽  
Principal Component ◽  
Component Analysis ◽  
Active Pharmaceutical Ingredients ◽  
Pharmaceutical Ingredients ◽  
The Third ◽  
Chemometric Technique ◽  
Tablet Formulations

In the present work Fournier transform infrared (IR) spectroscopy in association with chemometric technique was employed to identify kind of tablet formulations containing paracetamol and/or caffeine as active pharmaceutical ingredients. 13 samples of 5 commercially available brand tablets of different manufacturers and batches were bayed in local pharmacies. IR spectra of samples were recorded in the range 600—4000 cm-1 and subjected to and principal component analysis (PCA) which allowed to clearly identify 5 clusters in the scores plot using the third and the second principal components, corresponding to the brands of tablets. For Paracetamol and Caffeine-sodium benzoate tablets the combination of IR spectroscopy and PCA was able to recognize the manufacturer on the basis of distance between samples in clusters in the PCA scores plot.

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