scholarly journals Application of novel synthesized nanocomposites containing κ-carrageenan/PVA/eggshell in cement mortars

2020 ◽  
Vol 70 (340) ◽  
pp. 235
Author(s):  
I. Sanrı-Karapınar ◽  
A. O. Pehlivan ◽  
S. Karakuş ◽  
A. E. Özsoy-Özbay ◽  
A. U. Yazgan ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Cement Mortar ◽  
Cement Matrix ◽  
Cementitious Composites ◽  
Triple Combination ◽  
Strain Capacity ◽  
Preliminary Attempt ◽  
Cement Mortars ◽  
Compressive And Flexural Strengths ◽  
First Time

This study is a preliminary attempt to present the preparation and the first time a κ-carrageenan/PVA/eggshell nanostructure is used as a novel biodegradable and homogeneous nanostructure in cement composition. In order to clearly understand the effects these additives have on the mechanical properties of cementitious composites, they were synthesized in double and triple combinations and added into mortar mixtures. Three different cement mortar specimens were prepared by integrating the additives in ratios of 0, 0.1, 0.5 and 1% by cement weight and flexural and compressive strengths of the specimens were determined at the ages of 7 and 28 days. The flowability of the presented nanostructures was also discussed. The results revealed a 10–11% increase in both compressive and flexural strengths for the specimens prepared with the triple combination of the proposed additives. Moreover, strain capacity was enhanced as a result of the efficient dispersion of additives in the cement matrix.

scholarly journals Mechanical Properties and Microstructure of Polyvinyl Alcohol (PVA) Modified Cement Mortar

2019 ◽  
Vol 9 (11) ◽  
pp. 2178 ◽  
Author(s):  
Jie Fan ◽  
Gengying Li ◽  
Sijie Deng ◽  
Zhongkun Wang
Keyword(s):  
Mechanical Properties ◽  
Polyvinyl Alcohol ◽  
Cement Mortar ◽  
Cement Matrix ◽  
Hydration Products ◽  
Scanning Calorimetry ◽  
Large Piece ◽  
Cement Mortars ◽  
Compressive And Flexural Strengths ◽  
Scanning Electron

The mechanical properties of cement mortars with 0~2.0% (by mass) polyvinyl alcohol (PVA) were experimentally studied, and the effects of PVA incorporation on the hydration products and microstructure of the cement mortar were determined with differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The results show that the rational content of PVA formed evenly dispersed network-like thin films within the cement matrix, and these network-like films can bridge cracks in the cement matrix and improve the mechanical properties of the cement mortar. Over- incorporation of PVA may result in the formation of large piece polymer films that coat the cement particles, delay the hydration of the cement mortar and adversely affect its performance. The mechanical properties of the cement mortar show a significant increase and then decrease with a change in the PVA incorporation. When the PVA content was 0.6% and 1.0%, the mortar had the best compressive and flexural strengths, respectively. The compressive strength of the cement mortar increased by 12.15% for a PVA content of 0.6%, and the flexural strength of the cement mortar increased by 24.83% for a PVA content of 1.0%.

Fluid Transport Mechanisms in Portland Cement Mortar Modified with PVA and Nano Montmorillonite

2013 ◽  
Vol 687 ◽  
pp. 311-315 ◽  
Author(s):  
Teresa María Piqué ◽  
Luis Fernandez Luco ◽  
Analía Vázquez
Keyword(s):  
Tensile Strength ◽  
Portland Cement ◽  
Construction Industry ◽  
Fluid Transport ◽  
Cement Mortar ◽  
Drying Shrinkage ◽  
Cement Matrix ◽  
Poly Vinyl Alcohol ◽  
Cement Mortars ◽  
Compressive And Flexural Strengths

The development of new materials for specific applications is an increasing field in the construction industry, so is the employment of nanotechnology for this goal. When poly(vinyl alcohol) (PVA) is added to a Portland cement mortar, a film is formed in between the hydration products. This film has low elasticity modulus and high tensile strength and it enhances the mortar’s mechanical properties in the fresh and hardened states. The addition of nano montmorillonites (MMT) gives the polymer a better compatibility with the cement matrix. In this work, the changes in the microstructure of Portland cement mortars modified with PVA and PVA with MMT are assessed by means of transport of fluids capacity as an indicator. The reference is a standard mortar according to EN 196-1. The parameters measured are: weight loss under drying and air permeability. Complementary measures, such as compressive and flexural strengths and drying shrinkage have also been performed. From the obtained results, it can be concluded that the inclusion PVA + MMT to Portland cement mortar doesn’t affect the microstructure, when compared with Portland cement mortar with PVA, and even increase its tensile strength.

Influence of Crystallization Admixture on Mechanical Parameters and Microstructure of Polymer-Cement Mortars with Waste Limestone

2019 ◽  
Vol 296 ◽  
pp. 27-34
Author(s):  
Jakub Hodul ◽  
Nikol Žižková ◽  
Rostislav Drochytka ◽  
Ruben Paul Borg
Keyword(s):  
Mechanical Properties ◽  
Cement Mortar ◽  
Cement Content ◽  
Climatic Chamber ◽  
The Czech Republic ◽  
Ca Addition ◽  
Cement Mortars ◽  
The World ◽  
Influence Of Crystallization ◽  
Compressive And Flexural Strengths

Many years of experience in practice not only in the Czech Republic but also around the world have shown that crystallising waterproofing technology (mortars, coatings) improves the water and water-vapor impermeability of the treated structures and thus positively affects the durability of concrete. The sealing of pores, capillaries and cracks also prevents degradation due to physical and mechanical structural actions (e.g. the effects of ice and salts in pores, etc.). In the presented research, the influence of different crystallization admixture (CA) contents on the mechanical properties of polymer-cement mortar with 24% cement substitution by waste limestone was investigated. The crystallization admixture (CA) was added in different amounts at 0.8, 1.6 and 2.4% of the cement content in the mix. It was determined that the mechanical properties, namely the compressive and flexural strengths were not significantly influenced by the CA addition, with the highest difference recorded in the compressive strength (7%). The cohesion with the base concrete containing different amounts of limestone was sufficient, and the bond of the mortar to concrete was also closely examined using scanning electron microscopy (SEM). Through the SEM investigation it was determined that the presence of waste limestone of particle size below 250 μm did not affect the formation of crystals during the proper hydration process, in a climatic chamber at a high relative humidity (99%).

Incorporation of Iraqi Rocks in the Production of Eco-Friendly Cement Mortar

2020 ◽  
Vol 38 (10A) ◽  
pp. 1522-1530
Author(s):  
Rawnaq S. Mahdi ◽  
Aseel B. AL-Zubidi ◽  
Hassan N. Hashim
Keyword(s):  
Mechanical Properties ◽  
Thermal Conductivity ◽  
Compressive Strength ◽  
Water Absorption ◽  
Structural Properties ◽  
Mechanical Milling ◽  
Cement Mortar ◽  
Cement Mortars

This work reports on the incorporation of Flint and Kaolin rocks powders in the cement mortar in an attempt to improve its mechanical properties and produce an eco-friendly mortar. Flint and Kaolin powders are prepared by dry mechanical milling. The two powders are added separately to the mortars substituting cement partially. The two powders are found to improve the mechanical properties of the mortars. Hardness and compressive strength are found to increase with the increase of powders constituents in the cement mortars. In addition, the two powders affect water absorption and thermal conductivity of the mortar specimens which are desirable for construction applications. Kaolin is found to have a greater effect on the mechanical properties, water absorption, and thermal conductivity of the mortars than Flint. This behavior is discussed and analyzed based on the compositional and structural properties of the rocks powders.

scholarly journals Preparation and Mechanical Properties of Graphene Oxide: Cement Nanocomposites

2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Fakhim Babak ◽  
Hassani Abolfazl ◽  
Rashidi Alimorad ◽  
Ghodousi Parviz
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Graphene Oxide ◽  
Cement Mortar ◽  
Cement Matrix ◽  
Cement Composites ◽  
Xrd Diffraction ◽  
Calcium Silicate Hydrates ◽  
The Matrix ◽  
Scanning Electron

We investigate the performance of graphene oxide (GO) in improving mechanical properties of cement composites. A polycarboxylate superplasticizer was used to improve the dispersion of GO flakes in the cement. The mechanical strength of graphene-cement nanocomposites containing 0.1–2 wt% GO and 0.5 wt% superplasticizer was measured and compared with that of cement prepared without GO. We found that the tensile strength of the cement mortar increased with GO content, reaching 1.5%, a 48% increase in tensile strength. Ultra high-resolution field emission scanning electron microscopy (FE-SEM) used to observe the fracture surface of samples containing 1.5 wt% GO indicated that the nano-GO flakes were well dispersed in the matrix, and no aggregates were observed. FE-SEM observation also revealed good bonding between the GO surfaces and the surrounding cement matrix. In addition, XRD diffraction data showed growth of the calcium silicate hydrates (C-S-H) gels in GO cement mortar compared with the normal cement mortar.

scholarly journals Efecto del dióxido de titanio en las propiedades mecánicas y autolimpiantes del mortero

2021 ◽  
Vol 25 (109) ◽  
pp. 88-97
Author(s):  
Carlos Magno Chavarry Vallejos ◽  
Liliana Janet Chavarría Reyes ◽  
Xavier Antonio Laos Laura ◽  
Andrés Avelino Valencia Gutiérrez ◽  
Enriqueta Pereyra Salardi ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tio2 Nanoparticles ◽  
Low Temperatures ◽  
Mechanical Performance ◽  
Cement Mortar ◽  
Physical And Mechanical Properties ◽  
Cementitious Composites ◽  
Palabras Clave ◽  
Self Cleaning

El presente artículo tiene como objetivo determinar la influencia de la adición del dióxido de titanio (TiO2) en el mortero de cemento Pórtland Tipo I. La investigación es descriptiva, correlacional, explicativo, con diseño experimental, longitudinal, prospectivo y estudio de cohorte. Se elaboró una mezcla patrón y tres mezclas de mortero con 5%, 7.5% y 10% de contenido de TiO2 como reemplazo del volumen de cemento para las propiedades autolimpiantes se realizó el ensayo de rodamina e intemperismo. La incorporación de dióxido de titanio disminuyó la resistencia a la compresión, incrementó la fluidez y tasa de absorción de agua; la prueba de rodamina dio que el mortero sin actividad fotocatalítico no contenía TiO2 porque no cumple con los factores de fotodegradación R4 y R26. Mediante la exposición de paneles al intemperismo favoreciendo la propiedad autolimpiante de los morteros con adición de TiO2 (5%). Palabras Clave: Actividad foto catalítico, dióxido de titanio, factores de fotodegradación, propiedades mecánicas y autolimpiante. Referencias [1]E. Medina and H. Pérez, “Influencia del fotocatalizador dióxido de titanio en las propiedades autolimpiables y mecánicas del mortero de cemento - arena 1:4 - Cajamarca,” Universidad Nacional de Cajamarca, 2017. [2]G. Abella, “Mejora de las propiedades de materiales a base de cemento que contienen TiO 2 : propiedades autolimpiantes,” Universidad Politécnica de Madrid, 2015. [3]J. Gonzalez, “El Dióxido de titanio como material fotocatalitico y su influencia en la resistencia a la compresión en Morteros,” Universidad de San Buenaaventura Seccional Bello, 2015. [4]D. Jimenez and J. Moreno, “Efecto del reemplazo de cemento portland por el dioido de titanio en las propiedades mecanicas del mortero,” Pontificia Universidad Javeriana, 2016. [5]L. Wang, H. Zhang, and Y. Gao, “Effect of TiO2 nanoparticles on physical and mechanical properties of cement at low temperatures,” Adv. Mater. Sci. Eng., 2018, doi: 10.1155/2018/8934689. [6]Comisión de Normalización y de Fiscalización de Barreras Comerciales no Arancelares, Norma Técnica Peruana. Perú, 2013, p. 29. [7]ASTM Internacional, “ASTM C150,” 2021. https://www.astm.org/Database.Cart/Historical/C150-07-SP.htm. [8]M. Issa, “( current astm c150 / aashto m85 ) with limestone and process addition ( ASTM C465 / AASHTO M327 ) on the performance of concrete for pavement and Prepared By,” 2014. [9]S. Zailan, N. Mahmed, M. Abdullah, A. Sandu, and N. Shahedan, “Review on characterization and mechanical performance of self-cleaning concrete,” MATEC Web Conf., vol. 97, pp. 1–7, 2017, doi: 10.1051/matecconf/20179701022. [10]C. Chavarry, L. Chavarría, A. Valencia, E. Pereyra, J. Arieta, and C. Rengifo, “Hormigón reforzado con vidrio molido para controlar grietas y fisuras por contracción plástica,” Pro Sci., vol. 4, no. 31, pp. 31–41, 2020, doi: 10.29018/issn.2588-1000vol4iss31.2020pp31-41. [11]D. Tobaldi, “Materiali ceramici per edilizia con funzionalità fotocatalitica,” Università di Bologna, 2009. [12]Norme UNI, “Norma Italiana UNI 11259,” 2016. http://store.uni.com/catalogo/uni-11259-2008?josso_back_to=http://store.uni.com/josso-security-check.php&josso_cmd=login_optional&josso_partnerapp_host=store.uni.com. [13]E. Grebenisan, H. Szilagyi, A. Hegyi, C. Mircea, and C. Baera, “Directory lines regarding the desing and production of self-cleaning cementitious composites,” Sect. Green Build. Technol. Mater., vol. 19, no. 6, 2019. [14]M. Kaszynska, “The influence of TIO2 nanoparticles on the properties of self-cleaning cement mortar,” Int. Multidiscip. Sci. GeoConference SGEM, pp. 333–341, 2018.

scholarly journals Zastosowanie popiołu lotnego i szkła kineskopowego w zaprawach cementowych

2018 ◽  
Vol 27 (3) ◽  
pp. 348-354 ◽  
Author(s):  
Jakub Jura ◽  
Małgorzata Ulewicz
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Cement Mortar ◽  
Physical And Mechanical Properties ◽  
Waste Materials ◽  
Glass Cullet ◽  
Glass Waste ◽  
Cement Mortars ◽  
Resistance Tests ◽  
Made In

The article presents the results of research aimed at using glass waste and ash from biomass. The tests were carried out for cement mortars samples with using glass cullet, ash from biomass and using both wastes in 50/50 proportions. The physical and mechanical properties of the standard mortar and modified mortars were tested. Standard mortar and cement mortar samples were made in which 10, 20 and 30% of the cement mass was used as part of the standard sand. The samples were made of CEM I 42.5R. Mortars containing fly ash addition had an increased compressive strength and a smaller drop in compressive strength after frost resistance tests than standard mortar. The use of glass cullet in the amount of up to 20% did not reveal any changes in the mechanical properties of mortars, but using them in a larger amount resulted in unfavorable results. The use of a mixture of these two waste materials did not improve the results. The research has shown the possibility of using this waste to modify cement mortars.

scholarly journals Effect of Graphene Oxide/Graphene Hybrid on Mechanical Properties of Cement Mortar and Mechanism Investigation

Nanomaterials ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 113 ◽  
Author(s):  
Hongfang Sun ◽  
Li Ling ◽  
Zhili Ren ◽  
Shazim Ali Memon ◽  
Feng Xing
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Graphene Oxide ◽  
Flexural Strength ◽  
Pore Size Distribution ◽  
Cement Mortar ◽  
Underlying Mechanism ◽  
Mortar Specimen ◽  
Degree Of Hydration ◽  
Cement Mortars

This paper evaluated the effect of graphene oxide/graphene (GO/GR) hybrid on mechanical properties of cement mortar. The underlying mechanism was also investigated. In the GO/GR hybrid, GO was expected to act as a dispersant for GR while GR was used as reinforcement in mortar due to its excellent mechanical properties. For the mortar specimen, flexural and compressive strength were measured at varied GO to GR ratios of 1:0, 3:1, 1:1, 1:3, and 0:1 by keeping the total amount of GO and GR constant. The underlying mechanism was investigated through the dispersibility of GR, heat releasing characteristics during hydration, and porosity of mortar. The results showed that GO/GR hybrid significantly enhanced the flexural and compressive strength of cement mortars. The flexural strength reached maximum at GO:GR = 1:1, where the enhancement level was up to 23.04% (28 days) when compared to mortar prepared with only GO, and up to 15.63% (7 days) when compared to mortar prepared with only GR. In terms of compressive strength, the enhancement level for GO:GR = 3:1 was up to 21.10% (3 days) when compared with that of mortar incorporating GO only. The enhancement in compressive strength with mortar at GO:GR = 1:1 was up to 14.69% (7-day) when compared with mortar incorporating GR only. In addition to dispersibility, the compressive strength was also influenced by other factors, such as the degree of hydration, porosity, and pore size distribution of mortar, which made the mortars perform best at different ages.

Use of Spongilites as Pozzolanic Additives in Cement Mortars

2021 ◽  
Vol 325 ◽  
pp. 65-70
Author(s):  
Martin Vyšvařil ◽  
Patrik Bayer ◽  
Tomáš Žižlavský
Keyword(s):  
Mechanical Properties ◽  
Bulk Density ◽  
Frost Resistance ◽  
Water Retention ◽  
Cement Mortar ◽  
Partial Replacement ◽  
Fine Grained ◽  
Natural Pozzolans ◽  
Cement Mortars ◽  
Pozzolanic Additives

In this study, the utilization of two types of spongilites in various addition in cement mortars has been investigated with the purpose of exploring a new application of this natural pozzolans as cement mortar additives. The influence of the addition of spongilites on the physico-mechanical properties, frost-resistance, and microstructure of cement mortars as a function of time was studied. The results revealed that the rising proportion of spongilites in cement mortars causes increase in water retention of mortars, reduction of their bulk density, increase in porosity of mortars due to the growing predominance of capillary pores maintaining sufficient mortars strengths, and slightly increase in the frost-resistance of mortars. After initial tests, partial replacement of cement in fine-grained cement mortars with hitherto unexploited spongilites seems to be very promising. Based on the achieved results, a 20% cement replacement can be recommended as optimal.

Mechanical strength and self-sensing capacity of smart cementitious composite containing conductive rubber crumbs

2020 ◽  
Vol 31 (10) ◽  
pp. 1325-1340 ◽  
Author(s):  
Wenkui Dong ◽  
Wengui Li ◽  
Kejin Wang ◽  
Kirk Vessalas ◽  
Shishun Zhang
Keyword(s):  
Cement Mortar ◽  
Dominant Role ◽  
Cement Matrix ◽  
Cementitious Composites ◽  
Fine Aggregate ◽  
Contact State ◽  
Cyclic Compression ◽  
Conductive Rubber ◽  
Binder Ratio ◽  
Water To Binder Ratio

The effects of conductive rubber crumbs on the mechanical properties and self-sensing capacities of cementitious composites are investigated in this study. The rubberized cementitious composites with five different contents of conductive rubber crumbs are incorporated, ranging from 0%, 10%, 20%, 30% and 40% by mass of fine aggregate. Under the uniaxial cyclic compression, all the conductive rubber crumbs–filled cement composites exhibit excellent repeatability of piezoresistivity. The mortar with 20% conductive rubber crumbs at a water-to-binder ratio of 0.42 displayed the best piezoresistive sensitivity. Based on the relative positions of conductive rubber crumbs in the rubberized cement mortar, three conductive mechanisms were proposed for the conductive rubber crumbs, including complete isolation state, neighbouring state and the contact state. The isolation state plays a dominant role when the content of the conductive rubber crumbs is low, in which the piezoresistive behaviour is mainly controlled by the resistivity changes in cement matrix. In the neighbouring state, pores or voids in the gaps between nearby conductive rubber crumbs make the conductive rubber crumbs easier to connect, thus decreasing the resistivity under uniaxial compression. As for the contact state, the decreased contact resistance and the absence of sand between conductive rubber crumbs lead to higher resistivity changes under cyclic compression. The related results indicate that conductive rubber crumbs in cement mortar have application potentials for structural health monitoring.

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