A Convenient Synthesis od Substituted Heteroaromatic Compounds via the Palladium-Catalyzed Cross-Coupling Reaction od Organosilicon Compounds

Heterocycles ◽  
1990 ◽  
Vol 30 (1) ◽  
pp. 303 ◽  
Author(s):  
Tamejiro Hiyama ◽  
Yasuo Hatanaka ◽  
Satoshi Fukushima
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Organosilicon Compounds ◽  
Heteroaromatic Compounds ◽  
Cross Coupling Reaction ◽  
Convenient Synthesis ◽  
Palladium Catalyzed

ChemInform Abstract: Palladium-Catalyzed Cross-Coupling Reaction of Organosilicon Compounds with Allylic Carbonates or Diene Monoxides.

ChemInform ◽  
2010 ◽  
Vol 28 (49) ◽  
pp. no-no
Author(s):  
H. MATSUHASHI ◽  
S. ASAI ◽  
K. HIRABAYASHI ◽  
Y. HATANAKA ◽  
A. MORI ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Organosilicon Compounds ◽  
Cross Coupling Reaction ◽  
Palladium Catalyzed

The Palladium-Catalyzed Cross-Coupling Reaction of Organosilicon Compounds with Allylic Carbonates or Diene Monoxides

1997 ◽  
Vol 70 (8) ◽  
pp. 1943-1952 ◽  
Author(s):  
Hayao Matsuhashi ◽  
Satoshi Asai ◽  
Kazunori Hirabayashi ◽  
Yasuo Hatanaka ◽  
Atsunori Mori ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Organosilicon Compounds ◽  
Cross Coupling Reaction ◽  
Palladium Catalyzed

Ferromagnetic Chain Based on Verdazyl-Nitroxide Diradical

2020 ◽  
Author(s):  
Evgeny Tretyakov ◽  
Svetlana Zhivetyeva ◽  
Pavel Petunin ◽  
Dmitry Gorbunov ◽  
Nina Gritsan ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Ferromagnetic Coupling ◽  
Nitronyl Nitroxide ◽  
Triplet Ground State ◽  
One Dimensional ◽  
Cross Coupling Reaction ◽  
Palladium Catalyzed ◽  
Ferromagnetic Chain ◽  
High Yields

<p>Verdazyl-nitroxide diradicals were synthesized using the palladium-catalyzed cross-coupling reaction of the corresponding iodoverdazyls with a nitronyl nitroxide-2-ide gold(I) complex with high yields (up to 82%). The synthesized diradicals were found to be highly thermally stable and have a singlet (D<i>E</i><sub>ST</sub> » -64 cm<sup>–1</sup>) or triplet ground state (D<i>E</i><sub>ST</sub> ³ 25 and 100 cm<sup>–1</sup>), depending on which canonical hydrocarbon diradical type they belong to. Upon crystallization, triplet diradicals form unique one-dimensional (1D) spin <i>S</i> = 1 chains of organic diradicals with intrachain ferromagnetic coupling of <i>J</i>′/<i>k</i><sub>B</sub> from 3 to 6 K.</p>

scholarly journals Fluorinated Iron(ii) clathrochelate units in metalorganic based copolymers: improved porosity, iodine uptake, and dye adsorption properties

RSC Advances ◽  
2021 ◽  
Vol 11 (25) ◽  
pp. 14986-14995
Author(s):  
Suchetha Shetty ◽  
Noorullah Baig ◽  
Atikur Hassan ◽  
Saleh Al-Mousawi ◽  
Neeladri Das ◽  
...  
Keyword(s):  
Dye Adsorption ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Building Blocks ◽  
Adsorption Properties ◽  
Iodine Uptake ◽  
Cross Coupling Reaction ◽  
Palladium Catalyzed

We report the synthesis of metalorganic copolymers made from the palladium catalyzed Sonogashira cross-coupling reaction between various iron(ii) clathrochelate building blocks with diethynyl–triptycene and fluorene derivatives.

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