Trisubstituted Double Bond in the Cyclooctene Ring. Preparation Using the RCM Reaction

Heterocycles ◽  
2009 ◽  
Vol 78 (9) ◽  
pp. 2295 ◽  
Author(s):  
Motoo Tori ◽  
Reiko Mizutani ◽  
Takuo Miki ◽  
Katsuyuki Nakashima ◽  
Masakazu Sono
Keyword(s):  
Double Bond ◽  
Trisubstituted Double Bond

scholarly journals Iodine(III)-mediated halogenations of acyclic monoterpenoids

2018 ◽  
Vol 14 ◽  
pp. 1103-1111 ◽  
Author(s):  
Laure Peilleron ◽  
Tatyana D Grayfer ◽  
Joëlle Dubois ◽  
Robert H Dodd ◽  
Kevin Cariou
Keyword(s):  
Double Bond ◽  
Hypervalent Iodine ◽  
Halide Salt ◽  
Trisubstituted Double Bond ◽  
Excellent Selectivity

Five different halofunctionalizations of acyclic monoterpenoids were performed using a combination of a hypervalent iodine(III) reagent and a halide salt. In this manner, the dibromination, the bromo(trifluoro)acetoxylation, the bromohydroxylation, the iodo(trifluoro)acetoxylation or the ene-type chlorination of the distal trisubstituted double bond occurred with excellent selectivity and moderate to good yields.

Total Synthesis of Amphidinolide X and Its 12Z-Isomer by Formation of the C12-C13 Trisubstituted Double Bond via Ring-Closing Metathesis

Synlett ◽  
2008 ◽  
Vol 2008 (11) ◽  
pp. 1737-1741 ◽  
Author(s):  
Wei-Min Dai ◽  
Jinlong Wu ◽  
Yile Chen ◽  
Jian Jin ◽  
Jianshu Lou ◽  
...  
Keyword(s):  
Double Bond ◽  
Total Synthesis ◽  
Ring Closing Metathesis ◽  
Trisubstituted Double Bond

Selective Formation of a Z-Trisubstituted Double Bond Using a 1-(tert-Butyl)tetrazolyl Sulfone

2014 ◽  
Vol 79 (21) ◽  
pp. 10648-10654 ◽  
Author(s):  
Adriana Lorente ◽  
Fernando Albericio ◽  
Mercedes Álvarez
Keyword(s):  
Double Bond ◽  
Trisubstituted Double Bond ◽  
Tert Butyl ◽  
Selective Formation

ChemInform Abstract: CONJUGATE ACYLATION OF ALKYNES, A METHOD FOR THE SYNTHESIS OF α,β-UNSATURATED KETONES WITH A TRISUBSTITUTED DOUBLE BOND

1977 ◽  
Vol 8 (35) ◽  
pp. no-no
Author(s):  
A. A. SCHEGOLEV ◽  
W. A. SMIT ◽  
S. A. KHURSHUDYAN ◽  
V. A. CHERTKOV ◽  
V. F. KUCHEROV
Keyword(s):  
Double Bond ◽  
Unsaturated Ketones ◽  
Trisubstituted Double Bond

ChemInform Abstract: Trisubstituted Double Bond in the Cyclooctene Ring. Preparation Using the RCM Reaction.

ChemInform ◽  
2010 ◽  
Vol 41 (3) ◽  
Author(s):  
Reiko Mizutani ◽  
Takuo Miki ◽  
Katsuyuki Nakashima ◽  
Masakazu Sono ◽  
Motoo Tori
Keyword(s):  
Double Bond ◽  
Trisubstituted Double Bond
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