scholarly journals Experimental Study of the Relationship Between Particle Size and Methane Sorption Capacity in Shale

10.3791/57705 ◽  
2018 ◽  
Author(s):  
Li Gao ◽  
Zongxiu Wang ◽  
Mingliang Liang ◽  
Yuxi Yu ◽  
Lei Zhou
Keyword(s):  
Experimental Study ◽  
Particle Size ◽  
Sorption Capacity ◽  
Methane Sorption ◽  
The Relationship

scholarly journals Experimental Investigation of the Dependence of Accessible Porosity and Methane Sorption Capacity of Carbonaceous Shales on Particle Size

Geofluids ◽  
2020 ◽  
Vol 2020 ◽  
pp. 1-13 ◽  
Author(s):  
Garri Gaus ◽  
Anton Kalmykov ◽  
Bernhard M. Krooss ◽  
Reinhard Fink
Keyword(s):  
Particle Size ◽  
Sorption Capacity ◽  
Storage Capacity ◽  
Particle Sizes ◽  
Eagle Ford Shale ◽  
Eagle Ford ◽  
Rock Fabric ◽  
Alum Shale ◽  
Carbonaceous Shales ◽  
Methane Sorption

Crushing and grinding of carbonaceous shale samples is likely to enhance the accessibility of pores and embedded organic matter as compared to the intact rock. This may lead to an overestimation of the total (volume and sorptive) gas storage capacity. In order to investigate the importance of these effects we have measured unconfined apparent grain densities (helium pycnometry) and methane sorption capacities (high-pressure methane excess sorption) of four carbonaceous shales (Cambro-Ordovician Alum Shale, Jurassic Kimmeridge Clay, Jurassic/Cretaceous Bazhenov Shale, and Late Cretaceous Eagle Ford Shale) as a function of particle size. Measurements were first conducted on 38 mm diameter core plugs, which then were crushed and milled to successively smaller particle sizes (<10 mm, <2 mm, <64 μm, and <1 μm). Apparent grain densities of the smallest particle fractions of the Alum, Bazhenov and Kimmeridge samples were consistently higher by 0.5 to 1% than apparent grain densities of the original sample plugs. Methane excess sorption capacity increased significantly for particle sizes <64 μm for the Alum and <1 μm for the Bazhenov and Kimmeridge samples while no significant changes upon grinding were observed for the Eagle Ford Shale. For the Bazhenov Shale, the apparent grain density increased slightly from 2.446 g/cm3 to 2.450 g/cm3 upon particle size reduction from <64 μm to <1 μm while the maximum sorption capacity (“Langmuir volume”) increased substantially from 0.11 mmol/g to 0.19 mmol/g. Similarly, for the Kimmeridge Clay and Alum Shale, a slight increase of the apparent grain density from 1.546 g/cm3 to 1.552 g/cm3 and from 2.362 g/cm3 to 2.385 g/cm3, respectively, was accompanied by increases in sorption capacity from 0.37 mmol/g to 0.45 mmol/g and from 0.14 mmol/g to 0.185 mmol/g, respectively. The increase in sorption capacity indicates an opening of a considerable amount of micropores with large internal surface area upon physical disruption of the rock fabric and/or removal of included fluids. It may also be due to increased swelling abilities of clay minerals and organic matter upon destruction of the stabilizing rock fabric with decreasing particle size. Grain density and sorption isotherms measured on small particle sizes are likely to overestimate the gas storage capacities and the amounts of producible gas-in-place since under field conditions (largely undisrupted rock fabric), significant portions of this storage capacity are essentially inaccessible. Poor interconnectivity of the pore system and slow, diffusion-controlled transport will massively retard gas production. Based on these findings, particle sizes >64 μm should be used for porosity and sorption measurements because they are more likely to retain the properties of the rock fabric in terms of accessible pore volume and sorptive storage capacity.

Experimental Study on the Influence of Ceramist Properties Compressive Strength of Shale Ceramist Concrete

2012 ◽  
Vol 204-208 ◽  
pp. 4093-4096
Author(s):  
Wei Jun Yang ◽  
Zhi Gang He ◽  
Yi Yong
Keyword(s):  
Experimental Study ◽  
Particle Size ◽  
Compressive Strength ◽  
Concrete Strength ◽  
Aggregate Size ◽  
Strength Development ◽  
Concrete Compressive Strength ◽  
Absorption Time ◽  
The Relationship ◽  
Ceramic Cylinder

There are 6 group of experimental research to explore the relationship between shale ceramist concrete compressive strength and ceramic cylinder compressive strength, particle size, absorption time. The result shows that the strength of shale ceramist concrete is not only relevant with the ceramic cylinder compressive strength, but also relevant with the aggregate size, absorption time. For single graded particle size concrete, the strength of concrete decreased with grain size increasing. The longer time of ceramic absorption, the more sufficient the ceramist concrete strength development.

Experimental Study of Particle Size, Sound Velocity, and Resonance Phenomena in a Two-Phase Foam Flow

2001 ◽  
Vol 32 (4-6) ◽  
pp. 5
Author(s):  
A. P. Sevast'yanov ◽  
I. V. An ◽  
S. I. Vainshtein ◽  
Yu. A. Sevast'yanov ◽  
A. V. Sidnev ◽  
...  
Keyword(s):  
Experimental Study ◽  
Particle Size ◽  
Sound Velocity ◽  
Two Phase ◽  
Foam Flow ◽  
Resonance Phenomena

The Influences of the Rank of Coal on Methane Sorption Capacity in Coals/Wpływ Rzędu Węgla Na Pojemność Sorpcyjną Metanu W Węglach

2014 ◽  
Vol 59 (2) ◽  
pp. 509-516
Author(s):  
Andrzej Olajossy
Keyword(s):  
Sorption Capacity ◽  
Coalbed Methane ◽  
Vitrinite Reflectance ◽  
Sorption Isotherms ◽  
Volatile Matter ◽  
Low Rank ◽  
Hard Coal ◽  
Petrographic Composition ◽  
Methane Sorption ◽  
Indian Coals

Abstract Methane sorption capacity is of significance in the issues of coalbed methane (CBM) and depends on various parameters, including mainly, on rank of coal and the maceral content in coals. However, in some of the World coals basins the influences of those parameters on methane sorption capacity is various and sometimes complicated. Usually the rank of coal is expressed by its vitrinite reflectance Ro. Moreover, in coals for which there is a high correlation between vitrinite reflectance and volatile matter Vdaf the rank of coal may also be represented by Vdaf. The influence of the rank of coal on methane sorption capacity for Polish coals is not well understood, hence the examination in the presented paper was undertaken. For the purpose of analysis there were chosen fourteen samples of hard coal originating from the Upper Silesian Basin and Lower Silesian Basin. The scope of the sorption capacity is: 15-42 cm3/g and the scope of vitrinite reflectance: 0,6-2,2%. Majority of those coals were of low rank, high volatile matter (HV), some were of middle rank, middle volatile matter (MV) and among them there was a small number of high rank, low volatile matter (LV) coals. The analysis was conducted on the basis of available from the literature results of research of petrographic composition and methane sorption isotherms. Some of those samples were in the form (shape) of grains and others - as cut out plates of coal. The high pressure isotherms previously obtained in the cited studies were analyzed here for the purpose of establishing their sorption capacity on the basis of Langmuire equation. As a result of this paper, it turned out that for low rank, HV coals the Langmuire volume VL slightly decreases with the increase of rank, reaching its minimum for the middle rank (MV) coal and then increases with the rise of the rank (LV). From the graphic illustrations presented with respect to this relation follows the similarity to the Indian coals and partially to the Australian coals.

Quantity judgment and the mass-count distinction across languages: Advances, problems, and future directions for research

2018 ◽  
Author(s):  
David Barner ◽  
Alan Bale
Keyword(s):  
Experimental Study ◽  
Judgment Task ◽  
Scientific Enterprise ◽  
Future Directions ◽  
Quantity Judgment ◽  
The Relationship ◽  
Linguistic Cognition

We review advances in the experimental study of the mass-count distinction and highlight problems that have emerged. First, we lay out what we see to be the scientific enterprise of studying the syntax and semantics of mass-count distinction, and the assumptions we believe must be made if additional progress is to occur, especially as the empirical facts continue to grow in number and complexity. Second, we discuss the new landscape of cross-linguistic results that has been created by widespread use of the quantity judgment task, and what these results tell us about the nature of the mass-count distinction. Finally, we discuss the relationship between the mass-count distinction and non-linguistic cognition, and in particular the object-substance distinction.

External Investigators' Follow-Up Intentions When Whistleblowers Report Healthcare Fraud: The Effects of Report Anonymity and Previous Confrontation

2020 ◽  
Vol 32 (2) ◽  
pp. 91-101
Author(s):  
Steven E. Kaplan ◽  
Danny Lanier ◽  
Kelly R. Pope ◽  
Janet A. Samuels
Keyword(s):  
Experimental Study ◽  
Early Detection ◽  
Data Availability ◽  
Medical Provider ◽  
Perceived Credibility ◽  
The Relationship ◽  
Critical Investigation

ABSTRACT Whistleblowing reports, if properly investigated, facilitate the early detection of fraud. Although critical, investigation-related decisions represent a relatively underexplored component of the whistleblowing process. Investigators are responsible for initially deciding whether to follow-up on reports alleging fraud. We report the results of an experimental study examining the follow-up intentions of highly experienced healthcare investigators. Participants, in the role of an insurance investigator, are asked to review a whistleblowing report alleging billing fraud occurring at a medical provider. Thus, participants are serving as external investigators. In a between-participant design, we manipulate the report type and whether the caller previously confronted the wrongdoer. We find that compared to an anonymous report, a non-anonymous report is perceived as more credible and follow-up intentions stronger. We also find that perceived credibility fully mediates the relationship between report type and follow-up intentions. Previous confrontation is not significantly associated with either perceived credibility or follow-up intentions. Data Availability: Data are available upon request.

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