scholarly journals Hydrogen Production from Ethanol by Equilibrium Shifting Using Lithium Silicate Pellet as CO2 Absorbent

2008 ◽  
Vol 87 (1) ◽  
pp. 72-75 ◽  
Author(s):  
Kenji ESSAKI ◽  
Takehiko MURAMATSU ◽  
Masahiro KATO
2013 ◽  
Vol 16 (3) ◽  
pp. 229-237 ◽  
Author(s):  
Virginia Collins-Martínez ◽  
Miguel A. Escobedo Bretado ◽  
Jesús Salinas Gutiérrez ◽  
Miguel Meléndez Zaragoza ◽  
Vanessa. G. Guzmán ◽  
...  

Thermodynamic analysis of the absorption enhanced autothermal reforming of ethanol using CaO as CO2 absorbent and O2 in the feed was performed to determine favorable operating conditions to produce a high hydrogen ratio (HR, mols H2-produced/EtOH-feed) and hydrogen concentration in gas product. Steam/Ethanol (S/EtOH) and oxygen/ethanol (O2/EtOH) feed molar ratios were varied in order to find autothermal (?H ? 0) and carbon free operating conditions at 300-900°C and CaO as CO2 absorbent at 1 atm. Carbon formation analysis used S/EtOH = 1.75-2.8, while for hydrogen production varied from stoichiometric; 3:1 to 6.5:1, and O2/ETOH from 0 to 1.0. Results indicate no carbon formation at S/EtOH ? stoichiometric. The absorption enhanced autothermal reforming of ethanol using CaO, O2/EtOH = 0.33, S/EtOH = 6.5 and 600°C, produced an autothermal system with 98% H2 and only a reduction of 9.8% in HR and with respect to the CO2 absorption reforming without O2 feed.


1982 ◽  
Vol 43 (C9) ◽  
pp. C9-143-C9-147 ◽  
Author(s):  
P. Heitjans ◽  
B. Bader ◽  
K. Dörr ◽  
H. J. Stöckman ◽  
G. Kiese ◽  
...  

2020 ◽  
pp. 124-135
Author(s):  
I. N. G. Wardana ◽  
N. Willy Satrio

Tofu is main food in Indonesia and its waste generally pollutes the waters. This study aims to change the waste into energy by utilizing the electric charge in the pores of tofu waste to produce hydrogen in water. The tofu pore is negatively charged and the surface surrounding the pore has a positive charge. The positive and negative electric charges stretch water molecules that have a partial charge. With the addition of a 12V electrical energy during electrolysis, water breaks down into hydrogen. The test was conducted on pre-treated tofu waste suspension using oxalic acid. The hydrogen concentration was measured by a MQ-8 hydrogen sensor. The result shows that the addition of turmeric together with sodium bicarbonate to tofu waste in water, hydrogen production increased more than four times. This is due to the fact that magnetic field generated by delocalized electron in aromatic ring in turmeric energizes all electrons in the pores of tofu waste, in the sodium bicarbonate, and in water that boosts hydrogen production. At the same time the stronger partial charge in natrium bicarbonate shields the hydrogen proton from strong attraction of tofu pores. These two combined effect are very powerful for larger hydrogen production in water by tofu waste.


Author(s):  
A. Iulianelli ◽  
◽  
G. Bagnato ◽  
A. Iulianelli ◽  
A. Vita Vita ◽  
...  

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