scholarly journals An expedient synthesis of 5-n-alkylresorcinols and novel 5-n-alkylresorcinol haptens

2009 ◽  
Vol 5 ◽  
Author(s):  
Kirsti Parikka ◽  
Kristiina Wähälä
Keyword(s):  
Wittig Reaction ◽  
Alkyl Chain ◽  
Open Systems ◽  
Aqueous Media ◽  
Whole Grain ◽  
Detection Techniques ◽  
Immunochemical Detection ◽  
Grain Products ◽  
Derivatives Of ◽  
Long Alkyl Chain

The first synthesis of bioactive long alkyl chain 5-n-alkylresorcinols, present in whole grain products, by a novel modification of the Wittig reaction is described. All the main long chain 5-n-alkylresorcinols present in rye and wheat, including C23 and C25 analogues and haptens, which have not been previously prepared, were synthesised. Microwave-promoted reactions of a semi-stabilized ylid and alkanals in water gave good yields in both pressurized and open systems. An alternative microwave-promoted synthesis starting from non-stabilized alkyltriphenylphosphonium salts and 3,5-dimethoxybenzaldehyde worked as well. Aqueous media were suitable for the reactions even if the starting materials were not soluble in water. The 5-n-alkylresorcinols are potential biomarkers of whole grain intake, and the new hapten derivatives of 5-n-alkylresorcinols will open the way for the immunochemical detection techniques of alkylresorcinols.

Long alkyl chain bearing derivatives of poly(3,4-ethylenedioxythiophene) studied by in situ EPR spectroelectrochemistry

2009 ◽  
Vol 159 (21-22) ◽  
pp. 2240-2244 ◽  
Author(s):  
P. Berdyczko ◽  
W. Domagala ◽  
A. Czardybon ◽  
M. Lapkowski
Keyword(s):  
Alkyl Chain ◽  
Derivatives Of ◽  
Long Alkyl Chain

Template mediated crystal engineering

1994 ◽  
Vol 52 ◽  
pp. 480-481
Author(s):  
Brigid R. Heywood ◽  
S. Champ
Keyword(s):  
Crystal Engineering ◽  
Electrostatic Interactions ◽  
Alkyl Chain ◽  
Crystallographic Axis ◽  
Two Dimensional ◽  
Engineering Process ◽  
Solution Interface ◽  
Extensive Program ◽  
Geometric Homology ◽  
Long Alkyl Chain

Recent work on the crystallisation of inorganic crystals under compressed monomolecular surfactant films has shown that two dimensional templates can be used to promote the oriented nucleation of solids. When a suitable long alkyl chain surfactant is cast on the crystallisation media a monodispersied population of crystals forms exclusively at the monolayer/solution interface. Each crystal is aligned with a specific crystallographic axis perpendicular to the plane of the monolayer suggesting that nucleation is facilitated by recognition events between the nascent inorganic solid and the organic template.For example, monolayers of the long alkyl chain surfactant, stearic acid will promote the oriented nucleation of the calcium carbonate polymorph, calcite, on the (100) face, whereas compressed monolayers of n-eicosyl sulphate will induce calcite nucleation on the (001) face, (Figure 1 & 2). An extensive program of research has confirmed the general principle that molecular recognition events at the interface (including electrostatic interactions, geometric homology, stereochemical complementarity) can be used to promote the crystal engineering process.

X-ray Crystallographic Study of Alkylammonium Anthracene-9-carboxylates as a Model for Fibrous Structure of Binary Anthracene Salt Gels

2004 ◽  
Vol 69 (6) ◽  
pp. 1292-1300 ◽  
Author(s):  
Tahahiro Tani ◽  
Kazuki Sada ◽  
Masatsugu Ayabe ◽  
Yuya Iwashita ◽  
Takanori Kishida ◽  
...  
Keyword(s):  
Alkyl Chain ◽  
Columnar Structure ◽  
Hydrogen Bond Network ◽  
One Dimensional ◽  
X Ray ◽  
Crystallographic Study ◽  
Alkylammonium Salts ◽  
Bond Network ◽  
Fibrous Assemblies ◽  
Long Alkyl Chain

Crystal structure of hexylammonium anthracene-9-carboxylate was investigated. The salt was arranged by a one-dimensional hydrogen bond network to form a columnar structure in the crystalline state. This columnar structure should be the model of fibrous assemblies in the organogels of anthracene-9-carboxylate alkylammonium salts having a long alkyl chain.

Relationship between mesoscale dynamics and shear relaxation of ionic liquids with long alkyl chain

2012 ◽  
Vol 137 (10) ◽  
pp. 104511 ◽  
Author(s):  
Tsuyoshi Yamaguchi ◽  
Ken-ichi Mikawa ◽  
Shinobu Koda ◽  
Kenta Fujii ◽  
Hitoshi Endo ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Alkyl Chain ◽  
Mesoscale Dynamics ◽  
Shear Relaxation ◽  
Long Alkyl Chain

Long alkyl chain quaternary ammonium-based ionic liquids and potential applications

2006 ◽  
Vol 8 (9) ◽  
pp. 798 ◽  
Author(s):  
Juliusz Pernak ◽  
Marcin Smiglak ◽  
Scott T. Griffin ◽  
Whitney L. Hough ◽  
Timothy B. Wilson ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Quaternary Ammonium ◽  
Alkyl Chain ◽  
Potential Applications ◽  
Long Alkyl Chain

Lipophilicity of tetraarylporphyrins. Part 1. Tetra-(hydroxyphenyl)porphyrins with long alkyl chain in the molecule

2011 ◽  
Vol 24 (3) ◽  
pp. 201-205 ◽  
Author(s):  
Marcin Rojkiewicz ◽  
Grzegorz Zięba ◽  
Anna Jarczyk ◽  
Piotr Kuś
Keyword(s):  
Alkyl Chain ◽  
Long Alkyl Chain
Sign in / Sign up

Export Citation Format

Share Document