scholarly journals Rhodium-catalyzed reductive carbonylation of aryl iodides to arylaldehydes with syngas

2020 ◽  
Vol 16 ◽  
pp. 645-656 ◽  
Author(s):  
Zhenghui Liu ◽  
Peng Wang ◽  
Zhenzhong Yan ◽  
Suqing Chen ◽  
Dongkun Yu ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Industrial Applications ◽  
Catalytic Method ◽  
Broad Application ◽  
Aryl Aldehydes ◽  
Mild Conditions ◽  
Aryl Iodides ◽  
Reductive Carbonylation ◽  
Experimental Parameters ◽  
Application Prospects

The reductive carbonylation of aryl iodides to aryl aldehydes possesses broad application prospects. We present an efficient and facile Rh-based catalytic system composed of the commercially available Rh salt RhCl3·3H2O, PPh3 as phosphine ligand, and Et3N as the base, for the synthesis of arylaldehydes via the reductive carbonylation of aryl iodides with CO and H2 under relatively mild conditions with a broad substrate range affording the products in good to excellent yields. Systematic investigations were carried out to study the experimental parameters. We explored the optimal ratio of Rh salt and PPh3 ligand, substrate scope, carbonyl source and hydrogen source, and the reaction mechanism. Particularly, a scaled-up experiment indicated that the catalytic method could find valuable applications in industrial productions. The low gas pressure, cheap ligand and low metal dosage could significantly improve the practicability in both chemical researches and industrial applications.

Nickel-Catalyzed Regioselective Hydroalkylation of 1,3-Dienes with Hydrazones

2019 ◽  
Author(s):  
Leiyang Lv ◽  
Dianhu Zhu ◽  
Zihang Qiu ◽  
Jianbin Li ◽  
Chao-Jun Li
Keyword(s):  
Catalytic Method ◽  
Unsaturated Hydrocarbons ◽  
Carbon Nucleophiles ◽  
Aryl Aldehydes ◽  
Aldehydes And Ketones ◽  
Sterically Hindered

Hydroalkylation of unsaturated hydrocarbons with unstablized carbon nucleophiles is difficult and remains a major challenge. The disclosed examples so far mainly focused on the involvement of heteroatom and/or stabilized carbon nucleophiles as efficient reaction partners. Reported here is an unprecedented regioselective nickel-catalyzed hydroalkylation of 1,3-dienes with hydrazones, generated in situ from abundant aryl aldehydes and ketones and acted as both the sources of unstabilized carbanions and hydride. With this strategy, both terminal and sterically hindered internal dienes are hydroalkylated efficiently in a highly selective manner, thus providing a novel and reliable catalytic method to construct challenging C(sp3)-C(sp3) bonds.

scholarly journals Nickel-Catalyzed Asymmetric Reductive Cross-Coupling of α-Chloroesters with (Hetero)Aryl Iodides

2021 ◽  
Author(s):  
Travis DeLano ◽  
Sara Dibrell ◽  
Caitlin R. Lacker ◽  
Adam Pancoast ◽  
Kelsey Poremba ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Mild Conditions ◽  
Aryl Iodides ◽  
Reaction Proceeds

An asymmetric reductive cross-coupling of α-chloroesters and (hetero)aryl iodides is reported. This nickel-catalyzed reaction proceeds with a chiral BiOX ligand under mild conditions, affording α-arylesters in good yields and enantioselectivities....

Compactability Analysis of Soil-Rock Mixture

2013 ◽  
Vol 423-426 ◽  
pp. 1001-1005
Author(s):  
Lin Ping Yu ◽  
Zhi Yun Wang
Keyword(s):  
Influencing Factors ◽  
Building Material ◽  
Engineering Properties ◽  
Broad Application ◽  
Compaction Test ◽  
Object Of Study ◽  
Application Prospects

With soil-rock mixture (SRM) as the object of study and compaction test as the means, the paper studies the compactability of the SRM and analyzes the compactability influencing factors and engineering properties after compaction. Studies show that the soil engineering properties of compacted SRM are greatly improved, so it is a building material with broad application prospects.

scholarly journals Enantioenriched Quaternary α-Pentafluoroethyl Derivatives of Alkyl 1-Indanone-2-Carboxylates

2020 ◽  
Author(s):  
Albert Granados ◽  
Anna Balleteros ◽  
Adelina Vallribera
Keyword(s):  
Hypervalent Iodine ◽  
Catalytic Method ◽  
Quaternary Centers ◽  
Mild Conditions ◽  
Reaction Proceeds ◽  
Mechanistic Investigations ◽  
Derivatives Of

An electrophilic enantioselective catalytic method for the a-pentafluoroethylation of alkyl 1-indanone-2-carboxylates is described. Under the use of La(OTf)<sub>3</sub> in combination with (<i>S,R</i>)-indanyl-<i>pybox</i> ligand good results in terms of yield and enantioselectivities were achieved (up to 89% <i>ee</i>). The reaction proceeds under mild conditions leading to the formation of enantioenriched quaternary centers. This methodology uses an hypervalent iodine(III)-CF<sub>2</sub>CF<sub>3</sub> reagent and mechanistic investigations are consistent with the involvement of a radical pathway.

scholarly journals Palladium-catalyzed difluoromethylthiolation of heteroaryl bromides, iodides, triflates and aryl iodides

2016 ◽  
Vol 7 (6) ◽  
pp. 3757-3762 ◽  
Author(s):  
Jiang Wu ◽  
Yafei Liu ◽  
Changhui Lu ◽  
Qilong Shen
Keyword(s):  
Mild Conditions ◽  
Aryl Iodides ◽  
Palladium Catalyzed

A palladium-catalyzed difluoromethylthiolation of heteroaryl halides and triflates under mild conditions was described.

Combustion synthesis of Si3N4 powder

1997 ◽  
Vol 12 (3) ◽  
pp. 805-811 ◽  
Author(s):  
Wei-Chang Lee ◽  
Shyan-Lung Chung
Keyword(s):  
Reaction Mechanism ◽  
Combustion Synthesis ◽  
Combustion Temperature ◽  
Fine Particles ◽  
Minor Amount ◽  
Synthesis Reaction ◽  
Experimental Parameters ◽  
Combustion Synthesis Reaction ◽  
A Minor ◽  
Low Nitrogen

A combustion synthesis (SHS) process has been developed for the synthesis of Si3N4 powder under low nitrogen pressures. Si and NaN3 powders were used as the reactants, and NH4Cl powder was added as a catalytic agent. These powders were mixed and pressed into a cylindrical compact. The compact was wrapped up with an igniting agent (i.e., Ti + C), and the synthesis reaction was triggered by the combustion of the igniting agent. Addition of NH4Cl was found necessary for the combustion synthesis reaction under low nitrogen pressures (< 1.2 MPa). The product as synthesized is mostly in the form of agglomerated fine particles (0.1–1 μm in diameter) and is composed mainly of α-phase and a minor amount of β-phase. Effects of various experimental parameters (N2 pressure, NaN3, NH4Cl, and Si3N4 contents) on the product conversion and the combustion temperature were investigated. A possible reaction mechanism was proposed that explains the effects of the experimental parameters on the synthesis reaction.

Quantum blockchain system

2021 ◽  
pp. 2150343
Author(s):  
Xiao-Jun Wen ◽  
Yong-Zhi Chen ◽  
Xin-Can Fan ◽  
Zheng-Zhong Yi ◽  
Zoe L. Jiang ◽  
...  
Keyword(s):  
Quantum Teleportation ◽  
Secure Communication ◽  
Quantum Computers ◽  
Computing Power ◽  
Broad Application ◽  
Digital Currency ◽  
Blockchain Technology ◽  
Quantum Secure Communication ◽  
Complexity Problem ◽  
Application Prospects

Blockchain technology represented by Bitcoin and Ethereum has been deeply developed and widely used due to its broad application prospects such as digital currency and IoT. However, the security of the existing blockchain technologies built on the classical cryptography depends on the computational complexity problem. With the enhancement of the attackers’ computing power, especially the upcoming quantum computers, this kind of security is seriously threatened. Based on quantum hash, quantum SWAP test and quantum teleportation, a quantum blockchain system is proposed with quantum secure communication. In classical cryptographic theory sense, the security of this system is unconditional since it has nothing to do with the attackers’ computing power and computing resources.

MoS2 nanosheets chemically modified with metal phthalocyanine via mussel-inspired chemistry for multifunctional memristive devices

2021 ◽  
Author(s):  
Qing Yan ◽  
Fei Fan ◽  
Chen Sun ◽  
Mohamed E. El-Khouly ◽  
Hongfei Liu ◽  
...  
Keyword(s):  
Artificial Intelligence ◽  
Metal Phthalocyanine ◽  
Mos2 Nanosheets ◽  
Broad Application ◽  
Chemically Modified ◽  
Application Prospects

Memristive devices with in-memory computing functions have broad application prospects in the field of artificial intelligence. The development of memristive devices that integrate multi-functions of nonvolatile rewritable memory and biomimicking...

Design for New Actuator Based on Electroactive Polymer

2013 ◽  
Vol 579-580 ◽  
pp. 804-807
Author(s):  
Zhong Yao Wu ◽  
Tian Feng Zhao ◽  
Jian Bo Cao ◽  
Shi Ju E ◽  
Chun Xiao Chen
Keyword(s):  
Polymer Material ◽  
Dielectric Elastomer ◽  
Optimal Performance ◽  
Electroactive Polymer ◽  
Good Prospect ◽  
Broad Application ◽  
Design Scheme ◽  
New Type ◽  
Simulation Results ◽  
Application Prospects

Dielectric elastomer is a kind of electroactive polymer material with optimal performance. As actuator material, dielectric elastomer has shown a good prospect. Based on studying the principle of electroactive polymer, a new type of cylindrical actuator was designed. Its 3-D figure and 2-D dimension drawing was finished by UG software. The animation simulation of the actuator was studied. The simulation results verified the feasibility of design scheme. Electroactive polymer will have broad application prospects in the field of actuator.

Sewage Treatment Performance of Biological Aerated Filters with Fe-Containing Compound Clinoptilolite Media

2015 ◽  
Vol 737 ◽  
pp. 579-583
Author(s):  
Hui Mu ◽  
Yu Xiao Zhao ◽  
Min Tian Gao ◽  
Xiao Dong Zhang ◽  
Jie Zhang ◽  
...  
Keyword(s):  
Phosphorus Removal ◽  
Sewage Treatment ◽  
Ammonia Nitrogen ◽  
Ferric Ions ◽  
Pore Connectivity ◽  
Adsorption Effect ◽  
Broad Application ◽  
Treatment Performance ◽  
Natural Clinoptilolite ◽  
Application Prospects

Fe-containing compound clinoptilolite media (Fe-M), prepared with natural clinoptilolite, was applied to be the filter media of BAF, and then the treating performance of sewage by BAFs with Fe-M and ceramsite were investigated. Because Fe-M had relatively larger surface area, better pore connectivity, higher biofilm microbial biomass, and the ion-exchanging and adsorption effect, a higher ammonia nitrogen removal efficiency was obtained in BAF with Fe-M than ceramsite; and higher phosphorus removal in BAF with Fe-M was also realized by the adsorption and precipitation effect of the leaching ferric ions. Fe-M is more suitable to be used as the filter of BAF to treat sewage wastewater than ceramsite, which has a high value of broad application prospects and engineering popularization value.

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