scholarly journals Photoinduced 1,2,3,4-tetrahydropyridine ring conversions

2015 ◽  
Vol 11 ◽  
pp. 2166-2170
Author(s):  
Baiba Turovska ◽  
Henning Lund ◽  
Viesturs Lūsis ◽  
Anna Lielpētere ◽  
Edvards Liepiņš ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Solid State ◽  
Light Intensity ◽  
Photoinduced Electron Transfer ◽  
Driving Force ◽  
Spectroscopic Data

Stable heterocyclic hydroperoxide can be easily prepared as a product of fast oxidation of a 1,2,3,4-tetrahydropyridine by 3O2 if the solution is exposed to sunlight. The driving force for the photoinduced electron transfer is calculated from electrochemical and spectroscopic data. The outcome of the reaction depends on the light intensity and the concentration of O2. In the solid state the heterocyclic hydroperoxide is stable; in solution it is involved in further reactions.

Driving Force Dependence of Photoinduced Electron Transfer Dynamics of Intercalated Molecules in DNA

2003 ◽  
Vol 107 (45) ◽  
pp. 12511-12518 ◽  
Author(s):  
Shunichi Fukuzumi ◽  
Mari Nishimine ◽  
Kei Ohkubo ◽  
Nikolai V. Tkachenko ◽  
Helge Lemmetyinen
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Driving Force

Effects of Distance and Driving Force on Photoinduced Electron Transfer between Photosynthetic Reaction Centers and Gold Electrodes

2007 ◽  
Vol 111 (45) ◽  
pp. 17122-17130 ◽  
Author(s):  
Scott A. Trammell ◽  
Igor Griva ◽  
Anthony Spano ◽  
Stanislav Tsoi ◽  
Leonard M. Tender ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Driving Force ◽  
Reaction Centers ◽  
Gold Electrodes ◽  
Photosynthetic Reaction Centers

Photoinduced electron transfer in the solid state: rate vs. free energy dependence in fixed-distance porphyrin-acceptor molecules

1991 ◽  
Vol 113 (2) ◽  
pp. 719-721 ◽  
Author(s):  
George L. Gaines ◽  
Michael P. O'Neil ◽  
Walter A. Svec ◽  
Mark P. Niemczyk ◽  
Michael R. Wasielewski
Keyword(s):  
Electron Transfer ◽  
Free Energy ◽  
Solid State ◽  
Energy Dependence ◽  
Photoinduced Electron Transfer ◽  
Fixed Distance ◽  
State Rate ◽  
Acceptor Molecules

Tuning the Photoinduced Electron Transfer in a Zr-MOF: Toward Solid-State Fluorescent Molecular Switch and Turn-On Sensor

2018 ◽  
Vol 30 (34) ◽  
pp. 1802329 ◽  
Author(s):  
Bo Gui ◽  
Yi Meng ◽  
Yang Xie ◽  
Jianwu Tian ◽  
Ge Yu ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Solid State ◽  
Photoinduced Electron Transfer ◽  
Molecular Switch ◽  
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