scholarly journals N-Alkylated dinitrones from isosorbide as cross-linkers for unsaturated bio-based polyesters

2014 ◽  
Vol 10 ◽  
pp. 902-909 ◽  
Author(s):  
Oliver Goerz ◽  
Helmut Ritter
Keyword(s):  
Mechanical Properties ◽  
Methyl Acrylate ◽  
Unsaturated Polyester ◽  
Model Systems ◽  
Crotonic Acid ◽  
Dipolar Cycloaddition ◽  
Acryloyl Chloride ◽  
Rheological Measurements ◽  
Strong Change ◽  
Dimethyl Itaconate

Isosorbide was esterified with acryloyl chloride and crotonic acid yielding isosorbide diacrylate (9a) and isosorbide dicrotonate (9b), which were reacted with benzaldehyde oxime in the presence of zinc(II) iodide and boron triflouride etherate as catalysts to obtain N-alkylated dinitrones 10a/b. Poly(isosorbide itaconite -co- succinate) 13 as a bio-based unsaturated polyester was cross-linked by a 1,3-dipolar cycloaddition with the received dinitrones 10a/b. The 1,3-dipolar cycloaddition led to a strong change of the mechanical properties which were investigated by rheological measurements. Nitrones derived from methyl acrylate (3a) and methyl crotonate (3b) were used as model systems and reacted with dimethyl itaconate to further characterize the 1,3-dipolaric cycloaddition.

A Study of Some Mechanical and Physical Properties for Palm Fiber/Polyester Composite

2020 ◽  
Vol 38 (3B) ◽  
pp. 104-114
Author(s):  
Samah M. Hussein
Keyword(s):  
Mechanical Properties ◽  
Thermal Conductivity ◽  
Dielectric Constant ◽  
Date Palm ◽  
Volume Fraction ◽  
Unsaturated Polyester ◽  
Dielectric Strength ◽  
Palm Fiber ◽  
Mechanical And Physical Properties ◽  
Polyester Composite

This research has been done by reinforcing the matrix (unsaturated polyester) resin with natural material (date palm fiber (DPF)). The fibers were exposure to alkali treatment before reinforcement. The samples have been prepared by using hand lay-up technique with fiber volume fraction of (10%, 20% and 30%). After preparation of the mechanical and physical properties have been studied such as, compression, flexural, impact strength, thermal conductivity, Dielectric constant and dielectric strength. The polyester composite reinforced with date palm fiber at volume fraction (10% and 20%) has good mechanical properties rather than pure unsaturated polyester material, while the composite reinforced with 30% Vf present poor mechanical properties. Thermal conductivity results indicated insulator composite behavior. The effect of present fiber polar group induces of decreasing in dielectric strength, and increasing dielectric constant. The reinforcement composite 20% Vf showed the best results in mechanical, thermal and electrical properties.

Physical and mechanical properties of unsaturated polyester resin matrix from recycled PET (based PG ) with corn straw fiber

2021 ◽  
pp. 51305
Author(s):  
Nora Abigail Wilson García ◽  
Jorge Luis Almaral Sánchez ◽  
Ramón Álvaro Vargas Ortiz ◽  
Abel Hurtado Macías ◽  
Nelly Flores Ramírez ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Polyester Resin ◽  
Unsaturated Polyester ◽  
Physical And Mechanical Properties ◽  
Unsaturated Polyester Resin ◽  
Resin Matrix ◽  
Corn Straw ◽  
Recycled Pet

Reuse potential of functionalized thermoplastic waste as reinforcement for thermoset polymers: Mechanical properties and erosion resistance

2021 ◽  
pp. 002199832110370
Author(s):  
Tihomir Kovačević ◽  
Saša Brzić ◽  
Melina Kalagasidis Krušić ◽  
Jovica Nešić ◽  
Ljubica Radović ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Activation Energy ◽  
Erosion Resistance ◽  
Unsaturated Polyester ◽  
Chemical Activation ◽  
Mining Industry ◽  
Dynamic Mechanical Properties ◽  
Variable Loading ◽  
Polymer Waste ◽  
Dynamic Mechanical

Two types of polymer waste materials, poly(ethylene terephthalate) (PET) and polycarbonate based Colombian Resin (CR-39), were used for the designing of fully recycled composite materials. Waste PET was employed for the synthesis of thermoset unsaturated polyester resin (UPR), while CR-39 was used as reinforcement in the UPR matrix. Prior to mixing, CR-39 particles were subjected to oxidation and chemical activation using acids/base and ethanol amine, respectively. The effect of the modifier type and variable loading of the activated CR-39 particles on mechanical and dynamic-mechanical properties of the corresponding composites was investigated. The greatest improvement in the tensile and flexural strength of UPR resin was achieved with the composite containing 0.5 wt% of amine activated filler particles, 96.0% and 62.2%, respectively. The Arrhenius equation was used to calculate the activation energy for glass transition from dynamic mechanical properties measured at various frequencies. The activation energy of the main transition for UPR resin and composites were calculated to be 173 and 350 kJ·mol−1 indicating that reinforcement results in an increase in the energy barrier to macromolecules viscoelastic relaxation. In addition, erosion resistance was studied during exposure of samples to cavitation tests. According to the obtained results, these materials can be applied in construction and mining industry.

Shrinkage and mechanical properties of unsaturated polyester reinforced with clay and core–shell rubber

2012 ◽  
Vol 21 (12) ◽  
pp. 855-868 ◽  
Author(s):  
Morteza Ahmadi ◽  
Mohammad Reza Moghbeli ◽  
Mahmood M. Shokrieh
Keyword(s):  
Mechanical Properties ◽  
Unsaturated Polyester ◽  
Core Shell
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