scholarly journals Studies on the interaction of isocyanides with imines: reaction scope and mechanistic variations

2014 ◽  
Vol 10 ◽  
pp. 12-17 ◽  
Author(s):  
Ouldouz Ghashghaei ◽  
Consiglia Annamaria Manna ◽  
Esther Vicente-García ◽  
Marc Revés ◽  
Rodolfo Lavilla
Keyword(s):  
Double Bond ◽  
Lewis Acid ◽  
Acid Catalysis ◽  
Main Product ◽  
Structural Features ◽  
Ring System ◽  
Membered Ring ◽  
Sequential Process ◽  
Lewis Acid Catalysis ◽  
Nitrogen Double Bond

The interaction of imines with isocyanides has been studied. The main product results from a sequential process involving the attack of two units of isocyanide, under Lewis acid catalysis, upon the carbon–nitrogen double bond of the imine to form the 4-membered ring system. The scope of the reaction regarding the imine and isocyanide ranges has been determined, and also some mechanistic variations and structural features have been described.

scholarly journals Combining Bidentate Lewis Acid Catalysis and Photochemistry: Formal Insertion of o-Xylene into an Enamine Double Bond

2019 ◽  
Vol 21 (11) ◽  
pp. 3927-3930 ◽  
Author(s):  
Sebastian Ahles ◽  
Julia Ruhl ◽  
Marcel A. Strauss ◽  
Hermann A. Wegner
Keyword(s):  
Double Bond ◽  
Lewis Acid ◽  
Acid Catalysis ◽  
Lewis Acid Catalysis

Chiral Lewis Acid Catalysis in Nitrile Oxide Cycloadditions

2004 ◽  
Vol 126 (17) ◽  
pp. 5366-5367 ◽  
Author(s):  
Mukund P. Sibi ◽  
Kennosuke Itoh ◽  
Craig P. Jasperse
Keyword(s):  
Lewis Acid ◽  
Acid Catalysis ◽  
Nitrile Oxide ◽  
Lewis Acid Catalysis ◽  
Chiral Lewis Acid

Lewis Acid Catalysis with Cationic Dinuclear Gold(II,II) and Gold(III,III) Phosphorus Ylide Complexes

2016 ◽  
Vol 35 (17) ◽  
pp. 2830-2835 ◽  
Author(s):  
Benjamin R. Reiner ◽  
Mark W. Bezpalko ◽  
Bruce M. Foxman ◽  
Casey R. Wade
Keyword(s):  
Lewis Acid ◽  
Acid Catalysis ◽  
Lewis Acid Catalysis ◽  
Phosphorus Ylide ◽  
Ylide Complexes

Radical Changes in Lewis Acid Catalysis: Matching Metal and Substrate

2016 ◽  
Vol 55 (27) ◽  
pp. 7852-7856 ◽  
Author(s):  
Tim Bleith ◽  
Qing-Hai Deng ◽  
Hubert Wadepohl ◽  
Lutz H. Gade
Keyword(s):  
Lewis Acid ◽  
Acid Catalysis ◽  
Lewis Acid Catalysis

Boosting Lewis Acid Catalysis in Water-in-Oil Metallomicroemulsions

ChemCatChem ◽  
2012 ◽  
Vol 4 (12) ◽  
pp. 1979-1986 ◽  
Author(s):  
María Méndez-Pérez ◽  
Luis García-Río ◽  
Moisés Pérez-Lorenzo
Keyword(s):  
Lewis Acid ◽  
Acid Catalysis ◽  
Lewis Acid Catalysis
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