MINERAL ASSEMBLAGES, COMPOSITIONAL VARIATION, AND CRYSTAL STRUCTURE OF FERUVITIC TOURMALINE FROM A CONTAMINATED ANATECTIC PEGMATITE AT MIROŠOV NEAR STRÁŽEK, MOLDANUBIAN ZONE, CZECH REPUBLIC

2014 ◽  
Vol 52 (2) ◽  
pp. 285-301 ◽  
Author(s):  
Petr Gadas ◽  
Milan Novák ◽  
Jan Cempírek ◽  
Jan Filip ◽  
Michaela Vašinová Galiová ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Czech Republic ◽  
Compositional Variation ◽  
Moldanubian Zone ◽  
Mineral Assemblages

Secondary Beryl in Cordierite/Sekaninaite Pseudomorphs from Granitic Pegmatites – A Monitor of Elevated Content of Beryllium in the Precursor

2020 ◽  
Author(s):  
Petr Gadas ◽  
Milan Novák ◽  
Michaela Vašinová Galiová ◽  
Adam Szuszkiewicz ◽  
Adam Pieczka ◽  
...  
Keyword(s):  
Czech Republic ◽  
Chemical Composition ◽  
Limit Of Detection ◽  
Coarse Grained ◽  
Secondary Minerals ◽  
Moldanubian Zone ◽  
Granitic Pegmatites ◽  
Icp Ms ◽  
Mineral Assemblages ◽  
Host Rocks

Abstract Cordierite-group minerals (cordierite and sekaninaite) from granitic pegmatites are often strongly to completely altered to a fine- or coarse-grained mixture of muscovite, chlorite and/or, biotite, along with several less common secondary minerals, including mainly paragonite, tourmaline, and secondary beryl. The mixture is a common product of early subsolidus hydrothermal alteration at the examined pegmatites of the beryl-columbite subtype – Věžná I and Drahonín (Moldanubian Zone, Czech Republic) and Mount Begbie (Shuswap Complex, Canada); of the beryl-columbite-phosphate subtype – Szklary (Góry Sowie Block, Poland); and of miarolitic intragranitic pegmatites – Zimnik (Massif Strzegom-Sobótka, Poland). We studied in detail (EPMA, LA-ICP-MS) relics of primary cordierite/sekaninaite: Věžná I (Crd77–72Sek27–22MnCrd2–1, Be = 0.39–0.25 apfu, Li = 0.06–0.04 apfu), Drahonín (Crd13–9Sek74–71MnCrd17–16, Be = 0.24–0.18 apfu, Li = 0.07–0.05 apfu), Szklary (Crd50–49Sek30–26MnCrd25–21, Be = 0.45–0.41 apfu, Li ≤ 0.02 apfu), Mount Begbie (Crd34–33Sek53–43MnCrd24–14, Be = 0.33–0.29 apfu, Li = 0.26–0.23 apfu), and Zimnik (Crd2–1Sek75–71MnCrd28–23, Be = 0.25–0.15 apfu, Li = 0.18–0.12 apfu). Secondary beryl has a similar Mg/(Mg+Fe) ratio to its cordierite/sekaninaite precursor but is Mn depleted. The mineral assemblages and textures of the pseudomorphs were examined with a focus on secondary beryl, which forms anhedral grains to subhedral elongated crystals, up to 0.3 mm in size, or aggregates of these in textural equilibrium with associated phyllosilicates and tourmaline. Tourmaline is known from Věžná I, Drahonín, Mount Begbie, and Zimnik, the last also with topaz and “zinnwaldite” (a mineral with chemical composition between siderophyllite and polylithionite). Secondary beryl in pseudomorphs after cordierite/sekaninaite from granitic pegmatites and more evolved granites may have been often overlooked; hence, we present its textures and morphology so that it can be recognized during routine EPMA study and to study the source of elevated concentrations of Be in primary cordierite/sekaninaite. The empirical limit of detection of secondary beryl in pseudomorphs is ∼500–1000 ppm Be, which corresponds to ∼1–2 vol.% of secondary beryl. The chemical composition of the secondary beryl and other minerals indicate that the fluids responsible for the alteration were exsolved from the residual pegmatite melt and were not contaminated by fluids from the host rocks.

The crystal chemistry of the uranyl carbonate mineral grimselite, (K, Na)3Na[(UO2)(CO3)3](H2O), from Jáchymov, Czech Republic

2012 ◽  
Vol 76 (3) ◽  
pp. 443-453 ◽  
Author(s):  
J. Plášil ◽  
K. Fejfarová ◽  
R. Skála ◽  
R. Škoda ◽  
N. Meisser ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Czech Republic ◽  
Structure Refinement ◽  
Unit Cell ◽  
Carbonate Mineral ◽  
X Ray Diffraction ◽  
The Czech Republic ◽  
Cell Parameters ◽  
Uranyl Carbonate ◽  
Diffraction Peaks

AbstractTwo crystals of the uranyl carbonate mineral grimselite, ideally K3Na[(UO2)(CO3)3](H2O), from Jáchymov in the Czech Republic were studied by single-crystal X-ray diffraction and electron-probe microanalysis. One crystal has considerably more Na than the ideal chemical composition due to substitution of Na into KO8 polyhedra; the composition of the other crystal is nearer to ideal, and similar to synthetic grimselite. The presence of Na atoms in KO8 polyhedra, which are located in channels in the crystal structure, reduces their volume, and as a result the unit-cell volume also decreases. Structure refinement shows that the formula for the sample with the anomalously high Na content is (K2.43Na0.57)Σ3.00Na[(UO2)(CO3)3](H2O). The unit-cell parameters, refined in space group P2c, are a = 9.2507(1), c = 8.1788(1) Å, V = 606.14(3) Å3 and Z = 2. The crystal structure was refined to R1 = 0.0082 and wR1 = 0.0185 with a GOF = 1.33, based on 626 observed diffraction peaks [Iobs>3σ(I)].

Apatite with lamellae of sulfide and other phases in ultrahigh-pressure eclogites from Nové Dvory, Moldanubian Zone, Czech Republic

2018 ◽  
Vol 83 (1) ◽  
pp. 95-105
Author(s):  
Shah Wali Faryad ◽  
Radim Jedlicka ◽  
Maria Perraki
Keyword(s):  
Czech Republic ◽  
Surface Charge ◽  
Closed System ◽  
Ultrahigh Pressure ◽  
Temperature Decrease ◽  
Moldanubian Zone ◽  
Sector Zoning ◽  
Growth Plane ◽  
Close Relationship ◽  
Preferential Uptake

AbstractExsolution lamellae of baryte, Fe sulfides, Cu sulfides and Fe oxides were observed in apatite enclosed in garnet and omphacite and their intergranular spaces in ultrahigh-pressure eclogite in the Moldanubian Zone, Czech Republic. Micro-textural relations and compositional mapping of the apatite indicates a close relationship between the density of the exsolution lamellae and compositional domains that are rich in sulfur and iron. No relation between compositional domains and fluorine or chlorine content or any evidence of apatite metasomatisation was observed. On the basis of cathodoluminescence images, the compositional domains reflect sector zoning in apatite crystals by preferential uptake of elements due to differences in surface charge and morphology on the growth plane. It is concluded that the lamellae are products of exsolution in a closed system resulting from temperature decrease during metamorphism.

Compositional variation in högbomites from north Connemara, Ireland

1985 ◽  
Vol 49 (354) ◽  
pp. 649-654 ◽  
Author(s):  
N. S. Angus ◽  
R. Middleton
Keyword(s):  
Chemical Composition ◽  
Regional Metamorphism ◽  
The Other ◽  
Partial Substitution ◽  
Compositional Variation ◽  
Physical Parameters ◽  
Chemical Heterogeneity ◽  
High Grade ◽  
Thermal Metamorphism ◽  
Mineral Assemblages

AbstractHögbomite occurs in two contrasting mineral assemblages within the Currywongaun-Dough-ruagh intrusion of north Connemara: a cordierite-rich pelitic xenolith and an orthopyroxenite. In the latter, högbomite and green spinel form blebs within magnetite-ilmenite grains. The högbomite displays significant compositional variation from grain to grain: TiO2 (3.0–6.3%), FeO (21.6–21.3%), MgO (10.0–7.5%), ZnO (3.6–2.4%). This chemical heterogeneity appears to represent variable degrees of partial substitution of Mg and Zn by Ti, in the replacement of spinel by högbomite. By contrast, in the cordierite-hornfels, the högbomite compositions are more notably enriched in iron: TiO2 (4.7–7.0%), FeO (29.6–24.3%), MgO (4.2–6.2%), ZnO (2.7–2.1%). This iron-rich högbomite appears to have formed primarily by interaction between opaque ore and adjacent cordierite, rather than by replacement of spinel.Two high-grade metamorphic episodes appear to be necessary for högbomite growth, one determining chemical composition and the other appropriate physical parameters. In the Connemara occurrences thermal metamorphism and partial melting, coupled with contamination of the surrounding magma, controlled the formation of mineral assemblages rich in Fe, Mg, Al, Ti, and Zn. Emplacement of the intrusion was accompanied by amphibolite facies regional metamorphism and it is to this metamorphic event that the growth of högbomite may be attributed.

Two Paragenetic Types of Cookeite From the Dolní Bory-Hatě Pegmatites, Moldanubian Zone, Czech Republic: Proximal and Distal Alteration Products of Li-Bearing Sekaninaite

2015 ◽  
Vol 53 (6) ◽  
pp. 1035-1048
Author(s):  
Milan Novák ◽  
Renata Čopjaková ◽  
Marek Dosbaba ◽  
Michaela VAŠINOVÁ Galiová ◽  
Dalibor Všianský ◽  
...  
Keyword(s):  
Czech Republic ◽  
Moldanubian Zone

Refikite from Krásno, Czech Republic: a crystal-and molecular-structure study

2015 ◽  
Vol 79 (1) ◽  
pp. 59-70 ◽  
Author(s):  
Richard Pažout ◽  
Jiři´ Sejkora ◽  
Jaroslav Maixner ◽  
Michal Dušek ◽  
Jaromír Tvrdý
Keyword(s):  
Crystal Structure ◽  
Czech Republic ◽  
Abietic Acid ◽  
Minor Component ◽  
Structure Study ◽  
Methyl Groups ◽  
Orthorhombic Space Group ◽  
Fine Crystal ◽  
Light Yellow ◽  
Pine Trees

AbstractThe crystal structure of the organic mineral refikite has been determined. The mineral was found in joints in bark and wood from pine trees in the 'V Borkách' peat deposit near the town of Krásno, Slavkovský les Mountains, western Bohemia, Czech Republic. It forms white to light-yellow polycrystalline crusts or randomly intergrown, transparent, colourless, very thin, acicular crystals up to 0.2–0.5 mm long. Sometimes, colourless-to-white elongated prismatic crystals up to 1–1.5 mm in size were encountered. The mineral is soft (Mohs hardness ∼1) and very brittle, with an uneven fracture. No visible cleavage was discerned. Crystals have a greasy-to-glassy lustre; fine crystal aggregates have a pearly lustre. Refikite, empirical formula C20H34O2 or C19H33COOH, is a derivative of abietic acid. It is orthorhombic, space group P21212, with a = 22.6520(7), b = 10.3328(3), c = 7.6711(2) Å, V = 1795.49(9) Å3, Z = 4. Refikite comprises two closely related compounds based on perhydrophenanthrene. The major component has two axial methyl groups, one terminal carboxylic group and one terminal propan-2-yl (isopropyl) group joined to the three fused rings in the same fashion as in abietic acid. However, the fused ring system is fully reduced (contains single bonds only). In the minor component, the terminal propan-2-yl group is replaced by a propen-2-yl (methylvinyl) group. The crystal structure is stabilized by strong O···H–O hydrogen bonds. High-resolution mass spectroscopy (HRMS) confirmed a molecular mass of 306 and the formula C20H34O2. Hydrogen-1 and carbon-13 nuclear magnetic resonance (NMR) spectroscopy showed the presence of four methyl groups in the major component; infrared (IR), Raman and NMR spectra are consistent with the structure. The HRMS, IR and Raman spectroscopy methods confirmed the presence of a minor component containing the propen-2-yl group replacing the propan-2-yl group. This is also reflected in a shortened C15–C17 single bond metric of 1.468(6) Å shown by single-crystal X-ray analysis. The trivial name of the major component of refikite is tetrahydroabietic acid or abietan-18-oic acid. This work represents the first proof of the existence of abietic acid derivatives as naturally occurring species.

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