The Zebra Granitic Pegmatite, San Luis, Argentina

Author(s):  
Miguel Ángel Galliski ◽  
Robert F. Martin ◽  
María Florencia Márquez-Zavalía

Abstract We describe an unusual example of rhythmically layered peraluminous granitic pegmatite locally developed in the intragranitic Potrerillos NYF pegmatites derived from the A-type host granites of the Las Chacras–Potrerillos batholith, Sierra de San Luis, Argentina. The strikingly rhythmic layers in the Zebra pegmatite consist of units of albite–K-feldspar–quartz–K-feldspar–albite, with accessory tourmaline and minor muscovite. The layers crystallized from a boron-bearing melt ponded and thermally insulated in the intermediate zone. A layer of low albite 1–2 cm thick was followed by coarser-grained K-feldspar, then well-ordered microcline, which gives way to quartz grains, also coarser-grained, in optical continuity. Zoned prismatic crystals of schorl nucleated in the feldspathic layer in random orientation. Muscovite is scarce. The rock has a granitic composition enriched in Rb, Cs, and B, and is depleted in the rare-earth elements compared to its precursor. We contend that the normative composition, 35.3% Or, 38.1% Ab, and 21.3% Q, was close to the eutectic in the granite system modified by dissolved H2O, F, and B, at a P(H2O) close to 3.5 kbar and a temperature in the range 575–600 °C. Repeated incursions from the field of Ab + Or to the field of quartz and back again as the melt was producing bubbles of H2O can account for the rhythmic crystallization and the local truncation or merging of the feldspathic layers. Occasional larger crystals of K-feldspar may have become detached from the wall or roof of the chamber.

2005 ◽  
Vol 893 ◽  
Author(s):  
Sergey Stefanovsky ◽  
S.V. Yudintsev ◽  
B.S. Nikonov ◽  
O.I. Stefanovsky

AbstractPhase composition of the murataite-based ceramics containing 10 wt.% of mixed oxides simulating rare earth/actinide (REE/An) and actinide (An) fractions of high level waste (HLW) was studied. The ceramics were prepared by melting of oxide mixtures in Pt ampoules in air at ∼1500 °C. Ceramics with REE/An and An fractions surrogates are composed of predominant murataite-type phases and minor extra phases: perovskite and crichtonite. Three murataite-related phases with five- (5C), eight- (8C), and three-fold (3C) elementary fluorite unit cell are present in these ceramics. These phases form core, intermediate zone, and rim of the murataite grains, respectively. They are predominant host phases for the rare earth elements and uranium whose concentrations are reduced in a row: M-5C>M-8C>M-3C. Appreciate fraction of Ce, Nd, and Pu may enter the perovskite phase. In the An-Gd ceramic perovskite and murataite were found to be predominant and secondary in abundance phases respectively.


2006 ◽  
Vol 985 ◽  
Author(s):  
Sergey Stefanovsky ◽  
Sergey Yudintsev ◽  
Boris Nikonov ◽  
Olga Stefanovsky

AbstractPhase composition of the murataite-based ceramics containing 10 wt.% lanthanum, cerium, neodymium, europium, gadolinium, yttrium, zirconium oxides was studied. The ceramics were prepared by melting of oxide mixtures in glass-carbon ampoules in air at ∼1500° C. They are composed of predominant murataite-type phases and minor extra phases: rutile, crichtonite, perovskite, ilmenite/pyrophanite, and zirconolite (in the Zr-bearing sample only). Three murataite-related phases with five- (5C), eight- (8C), and three-fold (3C) elementary fluorite unit cell are normally present in all the ceramics. These phases form core, intermediate zone, and rim of the murataite grains, respectively. They are predominant host phases for the rare earth elements whose concentrations are reduced in a row: M-5C>M-8C>M-3C. Appreciate fraction of La and Ce may enter the perovskite phase.


1962 ◽  
Vol 18 (4) ◽  
pp. 1127-1153
Author(s):  
V FASSEL ◽  
R CURRY ◽  
R KNISELEY

2017 ◽  
Vol 8 (1) ◽  
Author(s):  
Takaaki Hatanaka ◽  
Akimasa Matsugami ◽  
Takamasa Nonaka ◽  
Hideki Takagi ◽  
Fumiaki Hayashi ◽  
...  

1967 ◽  
Vol 22 (4) ◽  
pp. 551-555 ◽  
Author(s):  
W. Jeitschko ◽  
E. Parthé

1962 ◽  
Vol 18 (9) ◽  
pp. 1127-1153 ◽  
Author(s):  
V.A. Fassel ◽  
R.H. Curry ◽  
R.N. Kniseley

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