scholarly journals Biomass Conversion into Soluble Carbohydrates and Catalytic Hydrogenation for Polyols Production

2021 ◽  
Author(s):  
Jornandes Dias Silva
Keyword(s):  
Catalytic Hydrogenation ◽  
Biomass Conversion ◽  
Soluble Carbohydrates

scholarly journals Catalytic Hydrogenation and Hydrodeoxygenation of Furfural over Pt(111): A Model System for the Rational Design and Operation of Practical Biomass Conversion Catalysts

2017 ◽  
Vol 121 (15) ◽  
pp. 8490-8497 ◽  
Author(s):  
Martin J. Taylor ◽  
Li Jiang ◽  
Joachim Reichert ◽  
Anthoula C. Papageorgiou ◽  
Simon K. Beaumont ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Rational Design ◽  
Biomass Conversion ◽  
Model System

Efficient catalytic hydrogenation of levulinic acid: a key step in biomass conversion

2012 ◽  
Vol 14 (7) ◽  
pp. 2057 ◽  
Author(s):  
József M. Tukacs ◽  
Dávid Király ◽  
Andrea Strádi ◽  
Gyula Novodarszki ◽  
Zsuzsanna Eke ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Levulinic Acid ◽  
Biomass Conversion

Technologies for Biomass Conversion

2006 ◽  
Author(s):  
Felicia Bucura ◽  
Violeta Niculescu ◽  
Elena David ◽  
Claudia Sisu ◽  
Marius Constantinescum
Keyword(s):  
Biomass Conversion

Nanometer Scale Spectroscopic Visualization of Catalytic Sites During a Hydrogenation Reaction on a Pd/Au Bimetallic Catalyst

2020 ◽  
Author(s):  
hao yin ◽  
Liqing Zheng ◽  
Wei Fang ◽  
Yin-Hung Lai ◽  
Nikolaus Porenta ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Density Functional ◽  
Hydrogen Transfer ◽  
Bimetallic Catalyst ◽  
Local Environment ◽  
Hydrogenation Reaction ◽  
Boundary Density ◽  
Catalytic Sites ◽  
Powerful Analytical Tool ◽  
Tip Enhanced Raman Spectroscopy

<p>Understanding the mechanism of catalytic hydrogenation at the local environment requires chemical and topographic information involving catalytic sites, active hydrogen species and their spatial distribution. Here, tip-enhanced Raman spectroscopy (TERS) was employed to study the catalytic hydrogenation of chloro-nitrobenzenethiol on a well-defined Pd(sub-monolayer)/Au(111) bimetallic catalyst (<i>p</i><sub>H2</sub>=1.5 bar, 298 K), where the surface topography and chemical fingerprint information were simultaneously mapped with nanoscale resolution (≈10 nm). TERS imaging of the surface after catalytic hydrogenation confirms that the reaction occurs beyond the location of Pd sites. The results demonstrate that hydrogen spillover accelerates hydrogenation at the Au sites within 20 nm from the bimetallic Pd/Au boundary. Density functional theory was used to elucidate the thermodynamics of interfacial hydrogen transfer. We demonstrate that TERS as a powerful analytical tool provides a unique approach to spatially investigate the local structure-reactivity relationship in catalysis.</p>

Nanometer Scale Spectroscopic Visualization of Catalytic Sites During a Hydrogenation Reaction on a Pd/Au Bimetallic Catalyst

2020 ◽  
Author(s):  
Hao Yin ◽  
Liqing Zheng ◽  
Wei Fang ◽  
Yin-Hung Lai ◽  
Nikolaus Porenta ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Density Functional ◽  
Hydrogen Transfer ◽  
Bimetallic Catalyst ◽  
Local Environment ◽  
Hydrogenation Reaction ◽  
Boundary Density ◽  
Catalytic Sites ◽  
Powerful Analytical Tool ◽  
Tip Enhanced Raman Spectroscopy

<p>Understanding the mechanism of catalytic hydrogenation at the local environment requires chemical and topographic information involving catalytic sites, active hydrogen species and their spatial distribution. Here, tip-enhanced Raman spectroscopy (TERS) was employed to study the catalytic hydrogenation of chloro-nitrobenzenethiol on a well-defined Pd(sub-monolayer)/Au(111) bimetallic catalyst (<i>p</i><sub>H2</sub>=1.5 bar, 298 K), where the surface topography and chemical fingerprint information were simultaneously mapped with nanoscale resolution (≈10 nm). TERS imaging of the surface after catalytic hydrogenation confirms that the reaction occurs beyond the location of Pd sites. The results demonstrate that hydrogen spillover accelerates hydrogenation at the Au sites within 20 nm from the bimetallic Pd/Au boundary. Density functional theory was used to elucidate the thermodynamics of interfacial hydrogen transfer. We demonstrate that TERS as a powerful analytical tool provides a unique approach to spatially investigate the local structure-reactivity relationship in catalysis.</p>

Herbicidal potential of Aerva javanica to control wild oat in wheat crop

2020 ◽  
Vol 51 (2) ◽  
pp. 177-194
Author(s):  
Al-Ghamdi A.M. ◽  
El-Zohri M
Keyword(s):  
Dry Weight ◽  
Soluble Carbohydrates ◽  
Wheat Crop ◽  
Aqueous Extracts ◽  
Wild Oat ◽  
Culture Experiment ◽  
Allelopathic Potential ◽  
Root Extracts ◽  
Wheat Germination ◽  
Radical Length

We investigated the phytotoxicity of desert cotton (Aerva javanica) extracts on wild oat and wheat. Aqueous extracts from A. javanica roots, leaves and inflorescences collected from Jeddah and Al-Baha regions, Saudi Arabia were used. Generally, the allelopathic potential of water extracts of A. javanica collected from Jeddah were more in inhibitory to wild oat germination and seedlings growth than those from Al-Baha. In both regions, root extracts were inhibitory to wild oat followed by leaves and inflorescences extracts. All test aqueous extracts of both regions did not inhibit the wheat germination or seedlings growth.Whreas, the wild oat germination was reduced by root extracts 58.62 %, 28.62 % leaves extracts : 32.72 %, 17.72 % and inflorescences extract 28.11 %, 12.13 % by in plants samples collected from Jeddah and Al-Baha, respectively. Wild oat radical length was inhibited by root extracts 53.27 %, 32.84 % leaves 42.35 %, 9.63 % and inflorescences extracts 22.64 %, 16.75 % in case of Jeddah and Al-Baha plants, respectively. In pot culture experiment, all treatments markedly reduced the plant dry weight and soluble carbohydrates, proteins and free amino acids contents in wild oat. The differences in the allelopathic potentials of studied A. javanica extracts were related to the qualitative variations in their phytochemicals constituents. Our results showed that A. javanica extracts could be safely used to control wild oat growth in wheat fields after more detsaled research..

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