Ecological Composites Materials for Brake Pads Using Shells as Filler Material

2019 ◽  
Vol 56 (3) ◽  
pp. 588-591
Author(s):  
Camelia Pinca Bretotean ◽  
Ludovic Dan Lemle ◽  
Alexandru Szabo
Keyword(s):  
Chemical Composition ◽  
Ultrafine Particles ◽  
Scientific Literature ◽  
Filler Material ◽  
New Materials ◽  
Brake Pads ◽  
Composites Materials ◽  
Similar Materials ◽  
Mechanical And Tribological Characteristics

The brake pads are one of the basic components for the development an ecological transport. The main objective of the paper is to produce green brake pads used shells as filler material capable to reducing the emission of fine and ultrafine particles resulting from vehicle braking systems. The stages in the development of this goal were: establishing the chemical composition of shells, formulating the recipes of composite materials, selecting parameters of technology, obtaining in laboratory and characterization of new materials in terms of physico-mechanical and tribological characteristics, evaluating their performance compared to similar materials presented in the scientific literature.

Qualitative and Quantitative Characterization of Airport-related Ultrafine Particles using Liquid Chromatography – High-Resolution Mass Spectrometry (UHPLC/HRMS)

2021 ◽  
Author(s):  
Florian Ungeheuer ◽  
Diana Rose ◽  
Dominik van Pinxteren ◽  
Florian Ditas ◽  
Stefan Jacobi ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Ultrafine Particles ◽  
Chemical Characterization ◽  
Engine Oil ◽  
Aircraft Emissions ◽  
Jet Engine ◽  
Qualitative And Quantitative ◽  
Ionization Mode ◽  
Lubrication Oils

<p>We present the results from a chemical characterization study of ultrafine particles (UFP), collected nearby Frankfurt International Airport where particle size distribution measurements showed high number concentrations for particles with a diameter <50 nm. Aluminium filter samples were collected at an air quality monitoring station in a distance of 4 km to Frankfurt airport, using the 13-stage cascade impactor Nano-MOUDI (MSP Model-115). The chemical characterization of the ultrafine particles in the size range of 0.010-0.018 μm, 0.018-0.032 μm and 0.032-0.056 μm was accomplished by the development of an optimized filter extraction method. An UHPLC method for chromatographic separation of homologous series of hydrophobic and high molecular weight organic compounds, followed by heated electrospray ionization (ESI) and mass analysis using an Orbitrap high-resolution mass spectrometer was developed. Using a non-target screening, ~200 compounds were detected in the positive ionization mode after filtering, in order to ensure high quality of the obtained data. We determined the molecular formula of positively charged adducts ([M+H]<sup>+</sup>; [M+Na]<sup>+</sup>), and for each impaction stage we present molecular fingerprints (Molecular weight vs Retention time, Kroll-diagram, Van-Krevelen-diagram, Kendrick mass defect plot) in order to visualize the complex chemical composition. The negative ionization mode led only to the detection of a few compounds (<20) for which reason the particle characterization focuses on the positive ionization mode. We found that the majority of detected compounds belong to homologous series of two different kinds of organic esters, which are base stocks of aircraft lubrication oils. In reference to five different jet engine lubrication oils of various manufacturers, we identified the corresponding lubricant base stocks and their additives in the ultrafine particles by the use of matching retention time, exact mass and MS/MS fragmentation pattern of single organic molecules. As the relevance of the chemical composition of UFP regarding human health is depending on the mass contribution of each compound we strived for quantification of the jet engine oil compounds. This was achieved by standard addition of purchased original standards to the native sample extracts. Two amines serving as stabilizers, one organophosphate used as an anti-wear agent/metal deactivator and two ester base stocks were quantified. Quantification of the two homologous ester series was carried out using one ester compound and cross-calibration. The quantitative determination is burdened by the uncertainty regarding sampling artefacts in the Nano-MOUDI. Therefore we characterized the cascade impactor in a lab experiment using the ester standard. Particle size distribution measurements conducted parallel to the filter sampling enables the determination of jet engine oil contribution to the UFP mass. Results indicate that aircraft emissions strongly influence the mass balance of 0.010-0.018 μm particles. This contribution decreases for bigger sized particles (0.018-0.056 μm) as presumably more sources get involved. The hereby-introduced method allows the qualitative and quantitative assignment of aircraft emissions towards the chemical composition and total mass of airport related ultrafine particles.</p>

scholarly journals Experimental Characterization Protocols for Wear Products from Disc Brake Materials

Atmosphere ◽  
2020 ◽  
Vol 11 (10) ◽  
pp. 1102 ◽  
Author(s):  
Ankur Sinha ◽  
Gloria Ischia ◽  
Cinzia Menapace ◽  
Stefano Gialanella
Keyword(s):  
Ultrafine Particles ◽  
Disc Brake ◽  
Brake Pads ◽  
Brake Wear Particles ◽  
General Improvement ◽  
Emission Behavior ◽  
Brake Wear ◽  
Wear Products ◽  
Main Material

The increasing interest in the emission from the disc brake system poses new challenges for the characterization approaches used to investigate the particles emitted from the wearing out of the relevant tribological systems. This interest stems from different factors. In the first place, a thorough characterization of brake wear particles is important for a complete understanding of the active tribological mechanisms, under different testing and servicing conditions. This information is an important prerequisite not only for the general improvement of brake systems, but also to guide the development of new materials for discs and brake pads, responding better to the specific requirements, including not only performance, but also the emission behavior. In this review paper, the main material characterization protocols used for the analyses of the brake wear products, with particular regard for the airborne fraction, are presented. Reliable results require investigating the fine and ultrafine particles as concerns their composition together with their structural and microstructural aspects. For this reason, in general, multi-analytical protocols are very much recommended.

Production of Asbestos-free Brake Pad Using Groundnut Shell as Filler Material

2018 ◽  
Vol 4 (12) ◽  
Author(s):  
W. C. Solomon ◽  
M. T. Lilly ◽  
J. I. Sodiki
Keyword(s):  
Phenolic Resin ◽  
Cost Effective ◽  
Filler Material ◽  
Particle Sizes ◽  
Brake Pad ◽  
Brake Pads ◽  
Environmental Friendly ◽  
Sieve Size ◽  
Groundnut Shell ◽  
The Cost

The development and evaluation of brake pads using groundnut shell (GS) particles as substitute material for asbestos were carried out in this study. This was with a view to harnessing the properties of GS, which is largely deposited as waste, and in replacing asbestos which is carcinogenic in nature despite its good tribological and mechanical properties. Two sets of composite material were developed using varying particle sizes of GS as filler material, with phenolic resin as binder with percentage compositions of 45% and 50% respectively. Results obtained indicate that the compressive strength and density increase as the sieve size of the filler material decreases, while water and oil absorption rates increase with an increase in sieve size of GS particle. This study also indicates that the cost of producing brake pad can be reduced by 19.14 percent if GS is use as filler material in producing brake pad. The results when compared with those of asbestos and industrial waste showed that GS particle can be used as an effective replacement for asbestos in producing automobile brake pad. Unlike asbestos, GS-based brake pads are environmental friendly, biodegradable and cost effective.

scholarly journals Synthesis and Characterization of a Bioconjugate Based on Oleic Acid and L-Cysteine

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1791
Author(s):  
Marco Vizcarra-Pacheco ◽  
María Ley-Flores ◽  
Ana Mizrahim Matrecitos-Burruel ◽  
Ricardo López-Esparza ◽  
Daniel Fernández-Quiroz ◽  
...  
Keyword(s):  
Oleic Acid ◽  
Materials Science ◽  
Critical Micellar Concentration ◽  
Synthesis And Characterization ◽  
New Materials ◽  
Visible Spectroscopy ◽  
Amide Bonds ◽  
Transmission Electron ◽  
Self Assembled

One of the main challenges facing materials science today is the synthesis of new biodegradable and biocompatible materials capable of improving existing ones. This work focused on the synthesis of new biomaterials from the bioconjugation of oleic acid with L-cysteine using carbodiimide. The resulting reaction leads to amide bonds between the carboxylic acid of oleic acid and the primary amine of L-cysteine. The formation of the bioconjugate was corroborated by Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, and nuclear magnetic resonance (NMR). In these techniques, the development of new materials with marked differences with the precursors was confirmed. Furthermore, NMR has elucidated a surfactant structure, with a hydrophilic part and a hydrophobic section. Ultraviolet-visible spectroscopy (UV-Vis) was used to determine the critical micellar concentration (CMC) of the bioconjugate. Subsequently, light diffraction (DLS) was used to analyze the size of the resulting self-assembled structures. Finally, transmission electron microscopy (TEM) was obtained, where the shape and size of the self-assembled structures were appreciated.

scholarly journals Structural Factors Inducing Cracking of Brass Fittings

Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3255
Author(s):  
Lenka Kunčická ◽  
Michal Jambor ◽  
Adam Weiser ◽  
Jiří Dvořák
Keyword(s):  
Chemical Composition ◽  
Plastic Flow ◽  
Beta Phase ◽  
Alpha Phase ◽  
Structural Factors ◽  
Transmission Electron ◽  
Medical Gas ◽  
Hot Die Forging ◽  
Multiple Step

Cu–Zn–Pb brasses are popular materials, from which numerous industrially and commercially used components are fabricated. These alloys are typically subjected to multiple-step processing—involving casting, extrusion, hot forming, and machining—which can introduce various defects to the final product. The present study focuses on the detailed characterization of the structure of a brass fitting—i.e., a pre-shaped medical gas valve, produced by hot die forging—and attempts to assess the factors beyond local cracking occurring during processing. The analyses involved characterization of plastic flow via optical microscopy, and investigations of the phenomena in the vicinity of the crack, for which we used scanning and transmission electron microscopy. Numerical simulation was implemented not only to characterize the plastic flow more in detail, but primarily to investigate the probability of the occurrence of cracking based on the presence of stress. Last, but not least, microhardness in specific locations of the fitting were examined. The results reveal that the cracking occurring in the location with the highest probability of the occurrence of defects was most likely induced by differences in the chemical composition; the location the crack in which developed exhibited local changes not only in chemical composition—which manifested as the presence of brittle precipitates—but also in beta phase depletion. Moreover, as a result of the presence of oxidic precipitates and the hard and brittle alpha phase, the vicinity of the crack exhibited an increase in microhardness, which contributed to local brittleness.

Synthesis and structural and electrical characterization of new materials Bi3R2FeTi3O15

2012 ◽  
Vol 407 (16) ◽  
pp. 3099-3101 ◽  
Author(s):  
O.D. Gil Novoa ◽  
D.A. Landínez Téllez ◽  
J. Roa-Rojas
Keyword(s):  
Electrical Characterization ◽  
New Materials

The Growth and Characterization of Germanium-Carbon Alloy Thin Films

1992 ◽  
Vol 270 ◽  
Author(s):  
Haojie Yuan ◽  
R. Stanley Williams
Keyword(s):  
Thin Films ◽  
Photoelectron Spectroscopy ◽  
Vacuum Chamber ◽  
Optical Band Gap ◽  
High Vacuum ◽  
Optical Absorption Spectroscopy ◽  
Alloy Thin Film ◽  
New Materials ◽  
X Ray

ABSTRACTThin films of pure germanium-carbon alloys (GexC1−x with x ≈ 0.0, 0.2, 0.4, 0.5, 0.6, 0.8, 1.0) have been grown on Si(100) and A12O3 (0001) substrates by pulsed laser ablation in a high vacuum chamber. The films were analyzed by x-ray θ-2θ diffraction (XRD), x-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES), conductivity measurements and optical absorption spectroscopy. The analyses of these new materials showed that films of all compositions were amorphous, free of contamination and uniform in composition. By changing the film composition, the optical band gap of these semiconducting films was varied from 0.00eV to 0.85eV for x = 0.0 to 1.0 respectively. According to the AES results, the carbon atoms in the Ge-C alloy thin film samples has a bonding configuration that is a mixture of sp2 and sp3 hybridizations.

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