Study of possible contamination of police officers and service vehicles with gunshot residues

2018 ◽  
Vol 302 ◽  
pp. 44-53
Author(s):  
Wiktor Dmitruk ◽  

The hereby article presents the analysis of data from literature of the subject, as well as of analyses of material recovered onto microscope stubs from hands of 59 police officers and traces collected from 38 police cars backseats onto ELEVAK instrument cartridges. The stubs were checked for presence of GSR particles and the filters of ELEVAK cartridges – for O-GSR and other substances. Traces were recovered at seven district police stations within Warsaw Municipal area. The analyses were performed with two analytical techniques: SEM/EDX and GC/MS. From 1 to 27 characteristic GSR particles were found on hands of 18% officers. Between 1 and 11 of such particles were detected on the surfaces of 24% car backseats. Traces of diphenylamine, a chemical substance used as a stabiliser in smokeless powders were detected in 13 vehicles, cocaine traces were found in 3 vehicles and THC was found in one vehicle.

1906 ◽  
Vol 25 (1) ◽  
pp. 51-60 ◽  
Author(s):  
Charles E. Fawsitt

Some time ago, while studying the chemical dynamics of the changes which occur in solutions of urea or carbamide, I came upon some rather unexpected results which led me to hope that investigations conducted on somewhat the same lines with other substances of the amide group might prove to yield results of some interest. The amides referred to are those derived from carboxylic acids. While proceeding to this investigation I noticed some measurements, obtained in connection with the viscosity of aqueous solutions of carbamide, which appeared of sufficient interest to demand an inquiry into the nature of solutions of this class of substances before proceeding further with the subject of inquiry in the manner at first intended.


1995 ◽  
Vol 23 (2) ◽  
pp. 103-111
Author(s):  
I. A. Craighead

The subject of condition monitoring is becoming increasingly popular on engineering courses. One of the principal techniques used to assess the condition of plant and machinery is vibration monitoring. Traditional teaching methods can adequately present the analytical techniques to students and case studies illustrate their application but the art of diagnosing faults in machinery is usually not addressed to any significant extent. To overcome this deficiency a ‘game’ has been devised which gives students the opportunity to apply aspects of vibration monitoring to a simulated piece of real plant.


Author(s):  
Muhammad R. Hajj ◽  
Ali H. Nayfeh ◽  
Pavol Popovic

Abstract Experimental and analytical techniques that characterize nonlinear modal interactions in structures are used to quantify parameters in representative nonlinear systems. The subject of the experimental study is a three-beam frame. Subharmonic resonances and interaction between widely spaced modes are exploited to determine nonlinear parameters in models that represent these interactions. The phases of the auto-bispectra of the response of this structure appear in the analytical solutions of the representative models. Values of these phases could thus aid in determining other unknown parameters of nonlinear systems.


1851 ◽  
Vol 141 ◽  
pp. 29-84 ◽  

2797. The remarkable results given in a former series of these researches (2757. &c.) respecting the powerful tendency of certain gaseous substances to proceed either to or from the central line of magnetic force, according to their relation to other substances present at the same time, and yet the absence of all condensation or expansion of these bodies (2756.) which might be supposed to be consequent on such an amount of attractive or repulsive force as would be thought needful to produce this tendency and determination to particular places, have, upon consideration, led me to the idea, that if bodies possess different degrees of conducting power for magnetism, that difference may account for all the phenomena; and, further, that if such an idea be considered, it may assist in developing the nature of magnetic force. I shall therefore venture to think and speak freely on this matter for a while, for the purpose of drawing others into a consideration of the subject; though I run the risk, in doing so, of falling into error through imperfect experiments and reasoning. As yet, however, I only state the case hypothetically, and use the phrase conducting power as a general expression of the capability which bodies may possess of affecting the transmission of magnetic force; implying nothing as to how the process of conduction is carried on. Thus limited in sense, the phrase may be very useful, enabling us to take, for a time, a connected, consistent and general view of a large class of phenomena; may serve as a standard of meaning amongst them, and yet need not necessarily involve any error, inasmuch as whatever may be the principles and condition of conduction, the phenomena dependent on it must consist among themselves. 2798. If a medium having a certain conducting power occupy the magnetic field, and then a portion of another medium or substance be placed in the field having a greater conducting power, the latter will tend to draw up towards the place of greatest force, displacing the former. Such at least is the case with bodies that are freely magnetic, as iron, nickel, cobalt and their combinations (2357. 2363. 2367. &c.), and such a result is in analogy with the phenomena produced by electric induction. If a portion of still higher conducting power be brought into play, it will approach the axial line and displace that which had just gone there; so that a body having a certain amount of conducting power, will appear as if attracted in a medium of weaker power, and as if repelled in a medium of stronger power by this differential kind of action (2367. 2414.).


1878 ◽  
Vol 26 (179-184) ◽  
pp. 384-386 ◽  

In the Proceedings of the Royal Society (vol. xxiv. p. 393) Dr Royston-Pigott described a new refractometer to determine the index of refraction of liquids and other substances by means of the displacement of the focal point of an object seen through them with a low magnifying-power. Another paper on the subject was communicated by him to the Royal Microscopical Society, and subsequently published its Journal. After the reading of this paper I said that it appeared me probable that the same principle might be applied with advantage the determination of the index of refraction of minerals. The chief question was how to make the requisite measurements by means of such a addition to an ordinary microscope as would not in any way interfere with its general use for other purposes. This I accomplished by fixing graduated scale to the body of the microscope and a vernier to the supporting arm, so that the position of the focal point can be read off to within about 1/2000 of an inch. I described this arrangement and pointed out its value in connexion with mineralogy at a meeting of the Mineralogical Society last March, and an account of it was published in the Journal of the Society. I have since learned that a very similar addition was made to a microscope in Professor Clifton’s laboratory at Oxford some eight years ago, and used for the measurement of the index of refraction of glass, but no account of it was ever published. When I came to study the index of refraction of doubly refracting minerals I was very soon struck with the fact that, instead of seeing at one focus the two systems of lines at right angles to each other, they were sometimes quite invisible, or one set was seen at one focus, and the whether at a very different, as though they had been ruled on the two opposite sides of a piece of glass. These curious phenomena were exhibited at the soirée of the Royal Society on the 25th of April last, and Processor Stokes immediately examined the question theoretically, and found that they could be explained by, and might have been predicted from, the known laws of double refraction, though apparently no one had ever studied them, either theoretically or practically. We therefore decided to investigate the problem independently. I was to make the practical observations, and he to give the theoretical explanations, the results being kept separate, but communicated conjointly to the Royal Society.


1833 ◽  
Vol 123 ◽  
pp. 95-142 ◽  

Mr. Faraday's highly interesting papers, entitled “Experimental Researches in Electricity,” having been referred to me, to report on, by the President and Council of this Society, I necessarily entered minutely into all the experiments and conclusions of the author, and the more so that I had had the advantage of witnessing many of the most important of these experiments. It is foreign to my present purpose to descant upon the value of Mr. Faraday’s discovery, or the merits of his communication ; the President and Council have marked their opinion of these by the award of the Copley Medal: but I may be permitted to state, that no one can concur more cordially than I do in the propriety of that award. Agreeing as I did generally with the author, both in the views which he took of the subject, and in the conclusions which he drew from his experiments, there was one, however, which I felt great difficulty in adopting, viz. “That when metals of different kinds are equally subject, in every circumstance, to magneto-electric induction, they exhibit exactly equal powers with respect to the currents which either are formed, or tend to form, in them :" and that “the same is probably the case in all other substances.” Although the experiments might appear to indicate that this was possibly the case, I did not consider them to be conclusive. The most conclusive experiment, that of two spirals, one of copper and the other of iron, transmitting opposite currents, was quite consistent with the absolute equality of the currents excited in copper and iron; but, at the same time, the apparent equality of the currents might be due to their inequality being counteracted by a corresponding inequality in the facility of transmission.


2017 ◽  
Vol 2017 ◽  
pp. 1-9 ◽  
Author(s):  
E. Manuela Garrido ◽  
Daniela Rodrigues ◽  
Nuno Milhazes ◽  
Fernanda Borges ◽  
Jorge Garrido

The herbicide terbuthylazine (TBA) is widely used for preemergence or postemergence control of many grass and broadleaf weeds and has, besides other issues, a poor aqueous solubility profile that results in reduced bioavailability. Cyclodextrins and modified cyclodextrins were considered, among other substances, appropriate agents for improving pesticide water solubility. Therefore, the inclusion complex formation of terbuthylazine withβ-cyclodextrin (β-CD) and hydroxypropyl-β-cyclodextrin (HP-β-CD) was studied to attain its aqueous solubility enhancement. Their characterization was accomplished with different analytical techniques, namely, by UV-Vis, DSC, FTIR, and1H NMR. From the analysis of the complexation performance of the herbicide it was concluded that the interaction of terbuthylazine with CDs leads to the formation of inclusion complexes with a stoichiometry of 1 : 1. The association constants of the TBA/β-CD and TBA/HP-β-CD complexes were determined by UV. The mean values obtained for the stability constants are 460.4 ± 26.5 and 532.1 ± 27.6 to TBA/β-CD and TBA/HP-β-CD, respectively.1H NMR data corroborate the formation of the TBA/β-CD and TBA/HP-β-CD complexes synthesized by the kneading method. A formulation incorporating TBA cyclodextrin complexes might lead to an improvement in terbuthylazine bioavailability. The development of TBA-CD formulations may be interesting since it would enable, through their inclusion into the hydrophobic cavity of CDs, enhancement of solubility, bioavailability, and stability of the herbicide.


2019 ◽  
Vol 10 (2) ◽  
pp. 19-29
Author(s):  
Marta Kowalczyk-Ludzia

Social judgments regarding the assessment of the work of the representatives of the preparatory proceedings organs are often formulated prematurely. Actions taken in favor of properly conducted proceedings often require commitment, which is difficult to qualify in specific assessment categories. Advances in technology mean that committing offences is often simpler, resulting in the possibility of committing more and more new crimes (including, among others, cybercrime). Such realities oblige the representatives of the procedural authorities to take effective remedial actions to combat criminogenic behavior, which sometimes correlates with taking actions that are on the fringes of the law or ethics (among others, Art. 168 a and 168 b of KPK (the Code of Criminal Procedure)). The effectiveness of the preparatory proceedings carried out is therefore dependent on many factors, the derivative of which is the decision of the trial resolution, which, in the theoretical assumption, should meet not only the statutory objectives of the proceedings, but also be a testimony to achieve a social sense of justice. The stereotypical verification of the work of prosecutors and the Police officers makes it difficult to make a proper assessment of the actions taken by them, thus distorting the actual image of the bodies of proceedings. The subject and purpose of this study is to emphasize the social perception of the representatives of the organs of preparatory proceedings. The theoretical reflections were formulated on the basis of the developed conclusions from the analysis of the court files examined.


2019 ◽  
Vol Special Issue ◽  
pp. 143-156
Author(s):  
Witold Apolinarski

Within the structure of the Polish Police, as a formation statutorily responsible for the protection of health, life and property of citizens, there are crowd and riot control squads (Pol. pododdziały zwarte). These are police organisational units , also referred to as riot police units (Pol. OPP - Oddziały Prewencji Policji) and independent riot police subunits (Pol. SPPP - Samodzielne Pododdziały Prewencji Policji). Their main advantage is the possibility of deploying several thousand police officers to respond to various events in a relatively short period of time and, if necessary, to broadly understood threats to the security of citizens. This is achieved by the use of appropriate mechanisms for maintaining readiness to act and achieving higher levels of readiness, as well as due to an organisational structure based on the military model, mobility based on available means of transport, a system of specialist trainings and modularity and compatibility with other police squads. Quite a wide range of opportunities to act in situations of existing threats to people and the environment raises the question of the quality and possibilities for the development of this structure, its strengths, as well as difficulties that emerge, both in terms of a direct involvement in various forms of police action, as well as those relating to the real condition of the structure, in the context of forces and measures available to the squads in question. At this point, it is necessary to mention other police structures referred to as police squads which include officers who daily perform different prevention activities (e.g. they occupy the posts of patrol and responding officers at county and municipal police headquarters). These are so-called irregular riot police units (Pol. NOP - Nieetatowe Oddziały Prewencji) and irregular riot police subunits (Pol. NPP - Nieetatowe Pododdziały Prewencji); however, their role and operational rules are not the subject matter, and the main issue under consideration is so-called regular units, whose officers remain in the structures of riot police units and independent riot police subunits.


2017 ◽  
Vol 72 (3-4) ◽  
pp. 171-183
Author(s):  
Filip Hradil ◽  
Vít Procházka ◽  
Lukáš Richtera

Unattractive stains on gold coins – sometimes wrongly described or mistakenly understood as gold corrosion – remained in focus of increased interest of scholars especially because of development of modern analytical techniques in the last decades. It is impossible to answer the primary questions about character and reasons of appearance of these stains without deep interdisciplinary knowledge. There is also another important question dealing with prevention of these stains and possibility of their gentle removal. The presented study tries to discover what caused appearance of the dark stains on the surface of the gold medal from Olomouc celebrating handover of the rule to Franz Joseph I and what is their chemical substance, and if it could be – in this case – a result and external effect of violation of the declared fineness.


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