scholarly journals Application of microscale combustion calorimeter to characterize protective properties of bovine leather

2020 ◽  
Vol 68 (4) ◽  
pp. 14-17
Author(s):  
Franka Žuvela Bošnjak ◽  
Sandra Flinčec Grgac ◽  
Suzana Mihanović
Keyword(s):  
Fire Resistance ◽  
Test Procedure ◽  
Rate Capability ◽  
Protective Role ◽  
Resistance Test ◽  
Heating Rates ◽  
Technical Standards ◽  
Two Samples ◽  
Microscale Combustion Calorimeter ◽  
Combustion Calorimeter

The quality and properties of fire resistance are crucial to the selection of leather for the production of protective fire fighting boots, which has a primarily protective role. During fire extinguishing it is exposed to extremely high and low temperatures, chemicals (acids and alkalis), mechanical loads, etc. The properties of fire resistance were tested on two samples of bovine leather (BL1, BL2). Burn resistance test has been carried out in accordance with the requirements of the technical standards for the burn resistance test: HRN EN ISO 15090: 2012, t, 7.3 - Firefighters and rescue services. The mentioned two samples were individually tested according to HRN EN ISO 15025: 2003. The test procedure was carried out by the "Flame Expansion Testing Method". Moreover, in this research used Microscale Combustion Calorimeter (MCC) Govmark, UK because that was designed for produce the maximum heating rate capability similarly the heating rates in fires and give as a lot of flammability parameters. The analysis of physicochemical properties of samples was performed using Fourier transform infrared (FTIR) spectroscopy. The surface morphology of the samples was studied using a Field Emission Scanning Electron Microscopy (FE-SEM). The measurement of the above samples on MCC was performed according to ASTM D7309. From the obtained HRR results, it is evident that BL1 sample has a better thermal stability than the BL2 sample.

scholarly journals Experimental Study on Delaying the Failure Time of In-Service Cables in Trays by Using Fire-Retardant Coatings

2021 ◽  
Vol 11 (6) ◽  
pp. 2521
Author(s):  
Feng Jiang ◽  
Jianyong Liu ◽  
Wei Yuan ◽  
Jianbo Yan ◽  
Lin Wang ◽  
...  
Keyword(s):  
Fire Resistance ◽  
Failure Time ◽  
Fire Retardant ◽  
Resistance Test ◽  
Control Group ◽  
Engineering Practice ◽  
Standard Fire ◽  
Oil Storage ◽  
Fire Resistance Test ◽  
Test Furnace

Improving the fire resistance of the key cables connected to firefighting and safety equipment is of great importance. Based on the engineering practice of an oil storage company, this study proposes a modification scheme that entails spraying fire-retardant coatings on the outer surface of a cable tray to delay the failure times of the cables in the tray. To verify the effect, 12 specimens were processed using five kinds of fire-retardant coatings and two kinds of fire-resistant cotton to coat the cable tray. The specimens were installed in the vertical fire resistance test furnace. For the ISO 834 standard fire condition, a fire resistance test was carried out on the specimens. The data for the surface temperature and the insulation resistance of the cables in trays were collected, and the fireproof effect was analyzed. The results showed that compared with the control group, the failure time of the cable could be delayed by 1.57–14.86 times, and the thicker the fire-retardant coatings were, the better the fireproof effect was. In general, the fire protection effect of the fire-retardant coating was better than that of the fire-resistant cotton.

Flammability and Thermal Degradation of Polystyrene/Cadmium Sulfate Nanocomposites

2013 ◽  
Vol 820 ◽  
pp. 84-87
Author(s):  
Zheng Zhou Wang ◽  
Charles A. Wilkie
Keyword(s):  
Thermal Stability ◽  
Thermal Degradation ◽  
Cone Calorimeter ◽  
Cds Nanoparticles ◽  
Solvothermal Process ◽  
Cadmium Sulfate ◽  
Peak Heat Release Rate ◽  
Microscale Combustion Calorimeter ◽  
Combustion Calorimeter ◽  
Thermal Stability Of

Cadmin sulfate nanoparticles, hollow sphere (CdS-HS) and rode (CdS-NR) were synthesized by ultrasonic and solvothermal process, respectively. The effect of the two kinds of nanoparticles on flammability of polystyrene was investigated using cone calorimeter (Cone) and microscale combustion calorimeter (MCC). Cone data indicate that the incorporation of 1% CdS nanoparticles leads to a about 20% reduction in the peak heat release rate (PHRR) compared to the pure PS; CdS-NR is more efficient in reducing the PHRR proved by both Cone and MCC results. The TG results show that the addition of the nanoparticles mainly increases thermal stability of PS at high temepratures.

A microscale combustion calorimeter study of gas phase combustion of polymers

2015 ◽  
Vol 162 (3) ◽  
pp. 855-863 ◽  
Author(s):  
Richard N. Walters ◽  
Natallia Safronava ◽  
Richard E. Lyon
Keyword(s):  
Gas Phase ◽  
Microscale Combustion Calorimeter ◽  
Combustion Calorimeter

scholarly journals Flammability and Thermal Kinetic Analysis of UiO-66-Based PMMA Polymer Composites

Polymers ◽  
2021 ◽  
Vol 13 (23) ◽  
pp. 4113
Author(s):  
Ruiqing Shen ◽  
Tian-Hao Yan ◽  
Rong Ma ◽  
Elizabeth Joseph ◽  
Yufeng Quan ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Mass Loss ◽  
Polymer Composites ◽  
Flame Retardants ◽  
Loss Rate ◽  
Mass Loss Rate ◽  
Protective Layer ◽  
Average Mass ◽  
Microscale Combustion Calorimeter ◽  
Combustion Calorimeter

Metal–organic frameworks (MOFs) are emerging as novel flame retardants for polymers, which, typically, can improve their thermal stability and flame retardancy. However, there is a lack of specific studies on the thermal decomposition kinetics of MOF-based polymer composites, although it is known that they are important for the modeling of flaming ignition, burning, and flame spread over them. The thermal decomposition mechanisms of poly (methyl methacrylate) (PMMA) have been well investigated, which makes PMMA an ideal polymer to evaluate how fillers affect its decomposition process and kinetics. Thus, in this study, UiO-66, a common type of MOF, was embedded into PMMA to form a composite. Based on the results from the microscale combustion calorimeter, the values of the apparent activation energy of PMMA/UiO-66 composites were calculated and compared against those of neat PMMA. Furthermore, under cone calorimeter tests, UiO-66, at only 1.5 wt%, can reduce the maximum burning intensity and average mass loss rate of PMMA by 14.3% and 12.4%, respectively. By combining UiO-66 and SiO2 to form a composite, it can contribute to forming a more compact protective layer, which shows a synergistic effect on reducing the maximum burning intensity and average mass loss rate of PMMA by 22.0% and 14.7%, respectively.

scholarly journals Fire resistance test of transformers filled with natural ester insulating liquid

2019 ◽  
Vol 2019 (16) ◽  
pp. 1560-1564 ◽  
Author(s):  
Shengwei Cai ◽  
Cheng Chen ◽  
Huihao Guo ◽  
Shaobing Chen ◽  
Zandong Zhou ◽  
...  
Keyword(s):  
Fire Resistance ◽  
Resistance Test ◽  
Fire Resistance Test ◽  
Insulating Liquid ◽  
Natural Ester

scholarly journals Some Key Factors Influencing the Flame Retardancy of EDA-DOPO Containing Flexible Polyurethane Foams

Polymers ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1115 ◽  
Author(s):  
Agnieszka Przystas ◽  
Milijana Jovic ◽  
Khalifah Salmeia ◽  
Daniel Rentsch ◽  
Laurent Ferry ◽  
...  
Keyword(s):  
Flame Retardancy ◽  
High Speed ◽  
Combustion Efficiency ◽  
Polyurethane Foams ◽  
Key Factors ◽  
Ul 94 ◽  
Microscale Combustion Calorimeter ◽  
Flexible Polyurethane ◽  
Combustion Calorimeter ◽  
Pu Foams

The role of various additives (emulsifier, anti-dripping agent) and formulation procedures (pre-dispersion of solid additives in polyol via milling) which influence the flame retardancy of 6,6′-[ethan-1,2-diylbis(azandiyl)]bis(6H-dibenzo[c,e][1,2]oxaphosphin-6-oxid) (EDA-DOPO) containing flexible polyurethane foams has been investigated in this work. For comparison, the flame retardancy of two additional structurally-analogous bridged 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO)-based compounds, i.e., ethanolamine-DOPO (ETA-DOPO) and ethylene glycol-DOPO (EG-DOPO) were also evaluated together with EDA-DOPO in flexible PU foams of various formulations. The flame retardancy of these three bridged-DOPO compounds depends on the type of PU formulation. For certain PU formulations containing EDA-DOPO, lower fire performance was observed. Addition of emulsifier and polytetrafluoroethylene (PTFE) to these PU formulations influenced positively the flame retardancy of EDA-DOPO/PU foams. In addition, dispersion of EDA-DOPO and PTFE via milling in polyol improved the flame retardancy of the PU foams. Mechanistic studies performed using a microscale combustion calorimeter (MCC) and its coupling to FTIR showed no difference in the combustion efficiency of the bridged-DOPO compounds in PU foams. From MCC experiments it can be concluded that these bridged-DOPO compounds and their decomposition products may work primarily in the gas phase as flame inhibitors. The physiochemical behavior of additives in PU formulation responsible for the improvement in the flame retardancy of PU foams was further investigated by studying the dripping behavior of the PU foams in the UL 94 HB test. A high-speed camera was used to study the dripping behavior in the UL 94 HB test and results indicate a considerable reduction of the total number of melt drips and flaming drips for the flame retardant formulations. This reduction in melt drips and flaming drips during the UL 94 HB tests help PU foams achieve higher fire classification.

Flammability testing of wool/cellulosic and wool/synthetic fiber blends: Vertical flame spread and heat release results

2020 ◽  
Vol 38 (6) ◽  
pp. 522-551
Author(s):  
Alexander B Morgan ◽  
Mary L Galaska
Keyword(s):  
Heat Release ◽  
Flame Spread ◽  
Natural Fiber ◽  
Woven Fabric ◽  
Synthetic Fiber ◽  
Cone Calorimetry ◽  
Lower Heat ◽  
Microscale Combustion Calorimeter ◽  
Microscale Combustion Calorimetry ◽  
Combustion Calorimeter

Wool is a natural fiber with lower heat release/flammability than some synthetic fabrics, but it has not been well studied for its heat release when other fibers such as cotton, linen, and nylon are present in the woven fabric. In this article, the heat release and vertical flame spread of six commercially available natural color fabrics is reported. This includes 100% wool, 80% wool/20% nylon, 70% wool/30% linen, 45% wool/55% cotton, and 40% wool/38% cotton/12% nylon/10% metallic thread fabric. Heat release was measured through cone calorimetry (ASTM E1354) as a function of the sample mounting method, through microscale combustion calorimetry (ASTM D7309), and flame spread was measured by ASTM D6413. The type of insulated backing used greatly affected the cone calorimeter results, and fabric types did show some effects in vertical flame spread and microscale combustion calorimeter testing.

scholarly journals Numerical Modeling of Fire Resistance Test as a Tool to Design Lightweight Marine Fire Doors: A Preliminary Study

2020 ◽  
Vol 8 (7) ◽  
pp. 520 ◽  
Author(s):  
Giada Kyaw Oo D’Amore ◽  
Alberto Marinò ◽  
Jan Kašpar
Keyword(s):  
Fire Resistance ◽  
Resistance Test ◽  
Critical Parameters ◽  
Test Procedures ◽  
Element Analysis ◽  
Thermal Bridge ◽  
Fire Resistance Test ◽  
Marine Applications ◽  
In Fire

Finite element analysis (FEA) is employed to simulate the thermo-resistance of a marine fire-proof door in the fire-resistance test defined by the International Code for the Application of Fire Test Procedures (2010 FTP Code) and required by the International Maritime Organization (IMO) for marine applications. The appropriate type of simulation adopted (i.e., steady or unsteady) is discriminated on the basis of a comparison between the numerical results and the experimental data. This appropriate model is used to evaluate the critical parameters affecting fire-proof door performance. A remarkable role of the thermal bridge at the door edges in fire resistance is assessed, along with the parameters that allow its reduction. These findings provide insight into how to design a thinner and lighter fire door.

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