scholarly journals Recent Progress on Metal-Enhanced Photocatalysis: A Review on the Mechanism

Research ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-16
Author(s):  
Ming Fang ◽  
Xiaoli Tan ◽  
Zhixin Liu ◽  
Baowei Hu ◽  
Xiangke Wang

Metal-enhanced photocatalysis has recently received increasing interest, mainly due to the ability of metal to directly or indirectly degrade pollutants. In this review, we briefly review the recent breakthroughs in metal-enhanced photocatalysis. We discussed the recent progress of surface plasmon resonance (SPR) effect and small size effect of metal nanoparticles on photocatalysis; in particular, we focus on elucidating the mechanism of energy transfer and hot electron injection/transfer effect of metal nanoparticles and clusters while as photocatalysts or as cophotocatalysts. Finally, we discuss the potential applications of metal-enhanced photocatalysis, and we also offer some perspectives for further investigations.

2021 ◽  
Author(s):  
Weixue Yang ◽  
Fei Li ◽  
Huali Liu ◽  
Zhen Li ◽  
Jiaqi Zhao ◽  
...  

A photo-assisted Li−Oxygen (Li−O2) battery with Au/SnO2 (ASO) hybrid nanotubes as cathode and photocatalyst has been prepared. The localized surface plasmon resonance (LSPR) excitation of gold nanoparticles (Au NPs) can...


Author(s):  
Yongming Fu ◽  
Zeqian Ren ◽  
Lixia Guo ◽  
Xiu Li ◽  
Yuqing Li ◽  
...  

Metal-semiconductor piezo-photocatalysts are generally investigated due to their high photocatalytic performances by coupling effect of piezotronics and localized surface plasmon resonance (LSPR). However, the mechanism is still indistinct, even the...


Symmetry ◽  
2020 ◽  
Vol 12 (8) ◽  
pp. 1365
Author(s):  
Pritam Khan ◽  
Grace Brennan ◽  
James Lillis ◽  
Syed A. M. Tofail ◽  
Ning Liu ◽  
...  

Optical properties of metal nanostructures, governed by the so-called localised surface plasmon resonance (LSPR) effects, have invoked intensive investigations in recent times owing to their fundamental nature and potential applications. LSPR scattering from metal nanostructures is expected to show the symmetry of the oscillation mode and the particle shape. Therefore, information on the polarisation properties of the LSPR scattering is crucial for identifying different oscillation modes within one particle and to distinguish differently shaped particles within one sample. On the contrary, the polarisation state of light itself can be arbitrarily manipulated by the inverse designed sample, known as metamaterials. Apart from polarisation state, external stimulus, e.g., magnetic field also controls the LSPR scattering from plasmonic nanostructures, giving rise to a new field of magneto-plasmonics. In this review, we pay special attention to polarisation and its effect in three contrasting aspects. First, tailoring between LSPR scattering and symmetry of plasmonic nanostructures, secondly, manipulating polarisation state through metamaterials and lastly, polarisation modulation in magneto-plasmonics. Finally, we will review recent progress in applications of plasmonic and magneto-plasmonic nanostructures and metamaterials in various fields.


Sensors ◽  
2020 ◽  
Vol 20 (18) ◽  
pp. 5119 ◽  
Author(s):  
Michal Gryga ◽  
Dalibor Ciprian ◽  
Petr Hlubina

We report on a highly sensitive measurement of the relative humidity (RH) of moist air using both the surface plasmon resonance (SPR) and Bloch surface wave resonance (BSWR). Both resonances are resolved in the Kretschmann configuration when the wavelength interrogation method is utilized. The SPR is revealed for a multilayer plasmonic structure of SF10/Cr/Au, while the BSWR is resolved for a multilayer dielectric structure (MDS) comprising four bilayers of TiO2/SiO2 with a rough termination layer of TiO2. The SPR effect is manifested by a dip in the reflectance of a p-polarized wave, and a shift of the dip with the change in the RH, or equivalently with the change in the refractive index of moist air is revealed, giving a sensitivity in a range of 0.042–0.072 nm/%RH. The BSWR effect is manifested by a dip in the reflectance of the spectral interference of s- and p-polarized waves, which represents an effective approach in resolving the resonance with maximum depth. For the MDS under study, the BSWRs were resolved within two band gaps, and for moist air we obtained sensitivities of 0.021–0.038 nm/%RH and 0.046–0.065 nm/%RH, respectively. We also revealed that the SPR based RH measurement is with the figure of merit (FOM) up to 4.7 × 10−4 %RH−1, while BSWR based measurements have FOMs as high as 3.0 × 10−3 %RH−1 and 1.1 × 10−3 %RH−1, respectively. The obtained spectral interferometry based results demonstrate that the BSWR based sensor employing the available MDS has a similar sensitivity as the SPR based sensor, but outperforms it in the FOM. BSW based sensors employing dielectrics thus represent an effective alternative with a number of advantages, including better mechanical and chemical stability than metal films used in SPR sensing.


Sign in / Sign up

Export Citation Format

Share Document