A model for fluids in metamorphosed ultramafic rocks III. Mass transfer under amphibolite facies conditions in olivine˗enstatite rocks of the Central Alps, Switzerland

1981 ◽  
Vol 104 (6) ◽  
pp. 834-847
Author(s):  
Hans-Rudolf Pfeifer
Keyword(s):  
Mass Transfer ◽  
Amphibolite Facies ◽  
Ultramafic Rocks ◽  
Central Alps

How to disclose local equilibrium in subducted metapelites from the Cima Lunga Unit (Central Alps)

2020 ◽  
Author(s):  
Francesca Piccoli ◽  
Pierre Lanari ◽  
Jörg Hermann ◽  
Thomas Pettke
Keyword(s):  
High Pressure ◽  
Early Stage ◽  
Local Equilibrium ◽  
White Mica ◽  
Geochemical Data ◽  
Ultramafic Rocks ◽  
Central Alps ◽  
Large White ◽  
Icp Ms ◽  
Polyphase Inclusions

<p>Subducted metapelites are more prone to re-equilibrate during exhumation than mafic or ultramafic rocks to the point that recognizing high-pressure (HP) relicts is often very challenging. Geologic evidence from the Cima Lunga Unit (Central Alps) show this apparent discrepancy between high to ultra-high pressure metamorphism (28 kbar and 780 °C) recorded in mafic/ultramafic lenses, and Barrovian metamorphism (<10 kbar, 650°C) in the adjacent metapelitic rocks. We collected a white mica – garnet – biotite – plagioclase – kyanite (+ quartz, + zircon, + rutile) bearing metapelite adjacent to the garnet metaperidotite lens that displays an apparently well equilibrated Barrovian mineral assemblage (garnet + plagioclase + biotite), with no macroscopic or microtextural indication of a HP and/or HT metamorphic event (e.g. omphacite crystals; migmatitic texture; polyphase inclusions). Nevertheless, microstructures like atoll-like garnet or large white mica flakes surrounded by biotite and ilmenite replacing rutile suggest incomplete re-equilibration. We investigated garnet and phengite crystals by electron probe and laser ablation-ICP-MS mapping. Major and trace element mapping reveals very complex mineral zoning in both minerals. In particular, high Ti content in phengite and increasing P and Zr contents in pyrope-rich garnet indicate that the studied rock underwent a HP-HT event. This is also supported by Zr in rutile thermometry that indicates temperatures well above the Barrovian metamorphism (T > 700 °C). We combined detailed textural analysis with petrological-geochemical data and thermodynamic modelling to reconstruct the metamorphic evolution of the studied rock. We show that, thank to incomplete re-equilibration, the rock documents an evolution from prograde to UHP-HT peak (27 kbar and 800 °C) to retrograde (Barrovian) conditions (10 kbar and 620 °C). Noteworthy, peak metamorphic conditions of metapelite coincide with peak metamorphic conditions of the garnet metaperidotite. Lastly, geochemical evidence for minor wet melting of the studied metapelite at HP-HT conditions was recognized and is likely linked to the dehydration of chlorite to form garnet peridotite in the adjacent ultramafic body. We propose that metapelites and ultramafic rocks were coupled before subduction or at least in its early stage. This finding opens new scenarios for the geodynamic interpretation of the Cima Lunga unit. We propose that the ultramafic lenses at Cima di Gagnone were parts of the exhumed and serpentinised mantle emplaced at the hyper-extended European continental margin of the Piemont-Ligurian ocean. Slices of the margin were detached and tectonically mixed in the subduction channel. These new constraints call for re-evaluation of the paleogeographic position of the Adula-Cima Lunga nappe.</p>

scholarly journals Early (3700 Ma) Archaean rocks of the Isua supracrustal belt and adjacent gneisses

1983 ◽  
Vol 112 ◽  
pp. 5-22
Author(s):  
A.P Nutman ◽  
D Bridgwater ◽  
E Dimroth ◽  
R.C.O Gill ◽  
M Rosing
Keyword(s):  
Amphibolite Facies ◽  
Iron Formation ◽  
Ultramafic Rocks ◽  
Banded Iron Formation ◽  
Sedimentary Structures ◽  
The North ◽  
Gneiss Complex ◽  
Supracrustal Belt ◽  
Silicate Rocks

A coherent stratigraphy is recognised in the highly deformed, amphibolite facies early Archaean Isua supracrustal belt. The supracrustal belt consists of layered rocks (in which sedimentary structures are locally preserved), ultramafic rocks and units of garbenschiefer (a massive Mg-Al rich, leucoamphibolite). The layered supracrustal rocks form two sequences, which are separated from each other tectonically. When folding is taken into account, these sequences are now less than 200 m thick. Sequence A forms most of the belt. In it there is a transition upwards from predominantly layered amphibolites with banded iron formation horizons to calc-silicate rocks, carbonates and layered felsic metasediments. Sequence B is restricted to the western edge of the eastern part of the supracrustal belt. It changes upwards from predominantly layered felsic metasediments to ferromagnesian mica schists. The supracrustal belt is regarded as a thin fragment from a thicker, more extensive volcanosedimentary pile. The early Archaean gneisses adjacent to the supracrustal belt consist of early multiphase tonalites which were first intruded by mafic dioritic dykes and then by granitic sheets. The granitic sheets were originaIly horizontal to gently inciined and form up to 40 per cent of the gneiss complex. Interdigitation of supracrustal rocks and gneisses in the Isukasia area is due to both the style of intrusion ofthe gneisses and to tectonic intercalation. Archaean basic dykes that cut the supracrustal belt and adjacent gneisses are ofseveral generations. Within and south of the supracrustal belt they are generally strongly deformed and have been recrystallised under amphibolite facies conditions; but in the north of the area they are generally better preserved. The dykes cut across several generations of structures in the supracrustal belt and the adjacent gneisses.

scholarly journals Metamorphic Differentiation via Enhanced Dissolution along High Permeability Zones

2020 ◽  
Author(s):  
Jo Moore ◽  
Andreas Beinlich ◽  
Sandra Piazolo ◽  
Håkon Austrheim ◽  
Andrew Putnis
Keyword(s):  
Mass Transfer ◽  
Shear Zone ◽  
Mineral Chemistry ◽  
Amphibolite Facies ◽  
Metamorphic Rocks ◽  
High Permeability ◽  
Enhanced Dissolution ◽  
Fluid Infiltration ◽  
Mass Redistribution ◽  
Compositional Variations

Abstract Metamorphic differentiation, resulting in segregated mineral bands, is commonly recorded in metamorphic rocks. Despite the ubiquitous nature of compositionally layered metamorphic rocks, the processes that are responsible for metamorphic differentiation receive very little attention. Here, detailed petrography, quantitative mineral chemistry and bulk rock analyses are applied to investigate compositional variations and assemblage microstructure. Furthermore, thermodynamic modelling is applied to provide additional constraints on the P–T–XH2O conditions of assemblage formation and mass transfer. The studied outcrop, located within the Bergen arcs of southwestern Norway, preserves the hydration of anorthositic granulite at amphibolite-facies conditions. The amphibolite-facies hydration is expressed as both a statically hydrated amphibolite and a shear zone lithology, defined by the interlayering of amphibolite with leucocratic domains. Within the granulite, quartz-lined fractures surrounded by amphibolite-facies alteration haloes represent relics of initial fluid infiltration associated with brittle failure. The fracture assemblage (quartz + plagioclase + zoisite + kyanite ± muscovite ± biotite) is identical to that occurring within leucocratic domains of the shear zone. Consequently, the compositional layering of the shear zone lithology is linked to fluid infiltration along localized zones of high permeability that result from fracturing. Mass-balance calculations indicate that quartz-lined fractures and compositional differentiation of the shear zone resulted from mass redistribution internal to the shear zone rather than partial melting or precipitation of minerals from externally derived fluid. The process of internal fractionation within the shear zone is driven by enhanced dissolution along highly permeable fracture planes resulting in the loss of MgO, Fetot and K2O from the leucocratic domains. Elements dissolved in the fluid are then transported and ultimately either precipitated in comparatively impermeable amphibolite domains or removed from the system resulting in an overall mass loss. The mass transfer causing metamorphic differentiation of the shear zone is the result of coupled reaction and diffusion under differential stress. The mechanisms of mass redistribution observed within this shear zone provides further insight into the processes that facilitate mass transfer in the Earth’s crust.

From granulite hydration to metamorphic differentiation: Evolution of a shear zone.

2020 ◽  
Author(s):  
Andrew Putnis ◽  
Jo Moore ◽  
Andreas Beinlich ◽  
Sandra Piazolo ◽  
Håkon Austrheim
Keyword(s):  
Mass Transfer ◽  
Partial Melting ◽  
Shear Zone ◽  
Strain Distribution ◽  
Amphibolite Facies ◽  
Fluid Flux ◽  
Transfer Processes ◽  
Fluid Infiltration ◽  
Mass Transfer Processes ◽  
Local Dissolution

<p><span>The studied outcrop, located within the Bergen arcs of southwestern Norway, preserves the hydration of an anorthositic granulite at amphibolite-facies conditions. The amphibolite-facies hydration is expressed as both a statically hydrated amphibolite and a shear zone rock, defined by the interlayering of amphibolite with leucocratic domains. Within the outcrop, quartz-filled fractures and their associated amphibolite alteration haloes crosscut the granulite. These fractures are relicts of the initial fluid infiltration event. The fracture assemblage (quartz + plagioclase + zoisite + kyanite ± muscovite ± biotite) is equivalent to that occurring locally within leucocratic domains of the shear zone. Due to the textural and compositional similarities between quartz-filled fractures and leucocratic domains, the compositional layering of the shear zone rock may be directly linked to fracturing during initial fluid infiltration. Mass-balance calculations indicate quartz-filled fractures and compositional differentiation of the shear zone form by internal fractionation rather than partial melting or precipitation of minerals from an eternally derived fluid. This inferred fluid connectivity combined with the enhanced local dissolution indicates the presence of a continuously replenished fluid along fracture pathways. The overall conclusion is that the mass transfer processes that result in metamorphic differentiation of the shear zone lithologies are dependent on both continuous fluid flux and heterogeneous strain distribution. </span></p>

scholarly journals GEOLOGIA DA REGIÃO DE JEQUERI-VIÇOSA (MG), ORÓGENO ARAÇUAÍ MERIDIONAL

2013 ◽  
Author(s):  
Daniel Tavares Gradim ◽  
Gláucia Nascimento Queiroga ◽  
Tiago Amâncio Novo ◽  
Carlos Maurício Noce ◽  
Antônio Carlos Pedrosa-Soares ◽  
...  
Keyword(s):  
Partial Melting ◽  
Shear Zone ◽  
Granulite Facies ◽  
Minas Gerais ◽  
Amphibolite Facies ◽  
Ultramafic Rocks ◽  
Metamorphic Rocks ◽  
The West ◽  
Minas Gerais State ◽  
Araçuaí Orogen

RESUMO: A característica fundamental da região de Jequeri-Viçosa, situada no extremo sul do Orógeno Araçuaí, é a abundância de rochas metamórficas, ortoderivadas e paraderivadas, de fácies anfibolito alto e granulito. O embasamento paleoproterozóico é representado, a oeste, por ortognaisses tonalíticos a graníticos do Complexo Mantiqueira e, a leste, por ortognaisses charno-enderbíticos do Complexo Juiz de Fora. Ambos os complexos incluem anfibolitos e exibem intensidades variáveis de migmatização. O contato entre eles é marcado pela zona de cisalhamento transpressiva destral de Abre Campo, interpretada como uma sutura paleoproterozóica reativada no Neoproterozóico. O Anfibolito Santo Antônio do Grama e rochas meta-ultramáficas associadas (Córrego do Pimenta) representam restos ofiolíticos ediacaranos, colocados ao longo da Zona de Cisalhamento de Abre Campo. Assentada sobre o embasamento, na parte oeste da área, ocorre uma associação metavulcano-sedimentar neoproterozóica do Grupo Dom Silvério, composta por xistos diversos e quartzito. Na porção leste da área mapeada, a cobertura metassedimentar neoproterozóica é atribuída ao Grupo Andrelândia que inclui paragnaisse migmatítico e raro quartzito. Corpos de hidrotermalito quartzoso, indiscriminadamente associados às unidades do embasamento e da cobertura neoproterozóica, ocorrem ao longo de zonas de cisalhamento. Hidrotermalitos ferruginosos associam-se ao Complexo Mantiqueira na Zona de Cisalhamento de Ponte Nova. O granito foliado a milonitizado da Serra dos Vieiras parece ser um produto de fusão parcial do paragnaisse Andrelândia. Completam o quadro geológico os pegmatitos da Suíte Paula Cândico e diques de diabásio mesozóicos.Palavras-chave: Paleoproterozóico, Neoproterozóico, Orógeno AraçuaíABSTRACT: GEOLOGY OF THE JEQUERI-VIÇOSA REGION, MINAS GERAIS STATE, SOUTHERN ARAÇUAÍ OROGEN. This paper focuses on the southwestern sector of the Araçuaí orogen in a region located close to the boundary with the northern Ribeira orogen. This region is rich in ortho- and para-derived metamorphic rocks of the high amphibolite and granulite facies. The Paleoproterozoic basement includes, to the west, tonalitic to granitic orthogneisses of the Mantiqueira Complex and, to the east, enderbitic to charnockitic orthogneisses of the Juiz de Fora Complex. Both complexes also include amphibolite enclaves and show several rates of partial melting. The contact between them is marked by the dextral transpressional Abre Campo shear zone, considered to be a Paleoproterozoic suture reactivated during the Neoproterozoic Era. The Santo Antônio do Grama Amphibolite and associated meta-ultramafic rocks (Córrego do Pimenta) are Ediacaran ophiolite slivers emplaced along the Abre Campo shear zone. In the western part of the region, the Paleoproterozoic basement is locally covered by a metavolcano-sedimentary assemblage composed of amphibolite facies schist and quartzite of the Neoproterozoic Dom Silvério Group. To the east, the Neoproterozoic cover comprises the migmatized paragneiss and rare quartzite of the Andrelândia Group. The Serra dos Vieiras foliated to mylonitic granite seems to be formed from the partial melting of the Andrelândia paragneiss. Pegmatites of the Paula Cândido Suite and Mesosozic diabase dikes complete the geologic framework of the mapped area.Keywords: Paleoproterozoic, Neoproterozoic, Araçuaí Orogen

HP melting of eclogites and metasomatism of garnet peridotites in the Monte Duria area (Central Alps, N Italy): a proxy for the mafic crust-to-mantle mass transfer at subduction zones

2020 ◽  
Author(s):  
Luca Pellegrino ◽  
Nadia Malaspina ◽  
Stefano Zanchetta ◽  
Antonio Langone ◽  
Simone Tumiati
Keyword(s):  
Mass Transfer ◽  
Direct Contact ◽  
Subduction Zones ◽  
Chemical Interaction ◽  
Granulite Facies ◽  
Garnet Peridotite ◽  
Stability Field ◽  
Central Alps ◽  
Selective Enrichment ◽  
Garnet Stability Field

<p>In the Monte Duria area (Adula-Cima Lunga unit, Central Alps, N Italy) Grt-peridotites occur in direct contact with migmatised orthogneiss (Mt. Duria) and eclogites (Borgo). Both mafic and ultramafic rocks share a common HP peak at 2.8 GPa and 750 °C and post-peak static equilibration at 1.2 GPa and 850 °C (Tumiati et al., 2018).</p><p>Grt-peridotites show abundant amphibole, dolomite, phlogopite and orthopyroxene after olivine, suggesting that they experienced metasomatism by crust-derived agents enriched in SiO<sub>2</sub>, K<sub>2</sub>O, CO<sub>2</sub> and H<sub>2</sub>O. Peridotites also display LREE fractionation (La/Nd = 2.4) related to LREE-rich amphibole and clinopyroxene grown in equilibrium with garnet, indicating that metasomatism occurred at HP conditions. At Borgo, retrogressed Grt-peridotites show low strain domains characterised by garnet compositional layering, cut by a subsequent low-pressure chlorite foliation, in direct contact with migmatised eclogites. Kfs+Pl+Qz+Cpx interstitial pocket aggregates and Cpx+Kfs thin films around symplectites after omphacite parallel to the Zo+Omp+Grt foliation in the eclogites suggest that they underwent partial melting at HP.</p><p>The contact between garnet peridotites and associated eclogites is marked by a tremolitite layer. Tremolitites also occur as variably stretched layers within the peridotite lens, showing a boudinage parallel to the garnet layering of peridotites, indicating that the tremolitite boudins formed when peridotites were in the garnet stability field. Tremolitites also show Phl+Tc+Chl+Tr pseudomorphs after garnet, both crystallized in a static regime postdating the boudins formation, suggesting that they derive from a Grt-bearing precursor. Tremolitites have Mg#>0.90 and Al<sub>2</sub>O<sub>3</sub>=2.75 wt.% pointing to ultramafic compositions but also show enrichments in SiO<sub>2</sub>, CaO, and LREE suggesting that they formed after the reaction between the eclogite-derived melt and the garnet peridotite at HP. To test this hypothesis, we calculated a log aH<sub>2</sub>O-X pseudosection at fixed P=3GPa and T=750°C to model the chemical interaction between the garnet peridotite and the eclogite-derived melt. Our results show that the interaction produces a Opx+Cpx+Grt assemblage + Amp+Phl, depending on the water activity in the melt, suggesting that tremolitites likely derive from a previous Grt-websterite with amphibole and phlogopite. Both peridotites and tremolitites also show a selective enrichment in LILE recorded by amphiboles in the spinel stability field, indicating that a fluid-assisted metasomatic event occurred at LP conditions, leading to the formation of a Chl-foliation post-dating the garnet layering in peridotites, and the retrogression of Grt-websterites in tremolitites.</p><p>The Monte Duria area is a unique case study where we can observe eclogite-derived melt interacting with peridotite at HP and relatively HT, and could thus represents a proxy for the crust-to mantle mass transfer at great depths in subduction zones.</p><p> </p><p>Tumiati, S., Zanchetta, S., Pellegrino, L., Ferrario, C., Casartelli, S., Malaspina, N., 2018. Granulite-facies overprint in garnet peridotites and kyanite eclogites of Monte Duria (Central Alps, Italy): Clues from srilankite- and sapphirine-bearing symplectites. J. Petrol. 59.</p>

scholarly journals Fe-Ti Oxide Assemblages from the Contact-Metamorphosed Mafic-Ultramafic Rocks of the Sedova Zaimka Intrusion (Western Siberia, Russia): The Tracking of Metamorphic Transformations

Minerals ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 253 ◽  
Author(s):  
Tatyana V. Svetlitskaya ◽  
Peter A. Nevolko ◽  
Pavel A. Fominykh
Keyword(s):  
Western Siberia ◽  
Amphibolite Facies ◽  
Contact Metamorphism ◽  
Ultramafic Rocks ◽  
Granite Pluton ◽  
Silicate Minerals ◽  
Elevated Content ◽  
Unstable Phase ◽  
Metamorphic Fluids ◽  
Oxide Minerals

Studies that track and compiled transformations of ilmenite and magnetite under conditions of different metamorphic grades are still very limited. The Sedova Zaimka intrusion in Western Siberia (Russia) is a good example to examine the effect of contact metamorphism from greenschist to low-amphibolite facies on magmatic Fe-Ti oxide minerals, as this small mafic-ultramafic body is located within contact metamorphic aureole of a large granite pluton. In the Sedova Zaimka, ilmenite with little to no magnetite is present as an accessory dissemination throughout metamorphosed rocks. Ilmenite is variably enriched in MnO (1 to 13.3 wt%) and depleted in MgO (less than 0.3 wt%), suggesting that its primary magmatic composition has been unevenly modified by diffusion re-equilibrium with coexisting metamorphic silicates. The elevated content of ZnO (up to 0.5 wt%) and NiO (up to 0.4 wt%) in ilmenite suggests that both ZnO and NiO, like MnO, must be strongly partitioned into ilmenite relatively to silicate minerals under the reducing contact metamorphic conditions, if chromite is absent. The textural observations of ilmenite–sulfide and ilmenite–titanite–sulfide relationships indicate that Ti-magnetite, in contrast to ilmenite, is an unstable phase in the presence of sulfur-rich reduced metamorphic fluids and is completely replaced by sulfides, with the development of specific “octahedral meshes” of ilmenite in sulfides.

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