Plastics. Determination of average molecular mass and mixture ratio of poly(ethylene glycol) and its derivatives by MALDI-TOF-MS

2017 ◽  
Author(s):  
Nicolas Hans Völcker ◽  
Doris Klee ◽  
Martin Hanna ◽  
Hartwig Höcker ◽  
Jordi J. Bou ◽  
...  

Daxue Huaxue ◽  
2015 ◽  
Vol 30 (5) ◽  
pp. 39-44
Author(s):  
Yu Huijuan ◽  
◽  
◽  
Chu Yuehuan ◽  
Shao Guang ◽  
...  
Keyword(s):  

2010 ◽  
Vol 31 (23-24) ◽  
pp. 3850-3862 ◽  
Author(s):  
Roland Müller ◽  
Martina Marchetti-Deschmann ◽  
Helmut Elgass ◽  
Heimo Breiteneder ◽  
Martin Kratzmeier ◽  
...  

e-Polymers ◽  
2005 ◽  
Vol 5 (1) ◽  
Author(s):  
Slim Salhi ◽  
Martine Tessier ◽  
Jean-Claude Blais ◽  
Rachid El Gharbi ◽  
Alain Fradet

AbstractPoly(ethylene adipate) (PEA) and poly(ethylene dodecanedioate) (PED) with dicarboxy-, dihydroxy-, dimethyl ester- and hydroxy-carboxy end-groups were synthesized and characterized by 13C NMR and MALDI-TOF MS. Size-exclusion chromatography (SEC) fractions of these polyesters were analyzed by MALDI-TOF MS and used as standards to obtain SEC calibration curves leading to the absolute molar masses of the unfractionated polyesters. PEA and PED calibration curves were different from each other, but the same calibration curve was obtained for each type of polyester, irrespective of the nature of end-groups, showing the predominant role of the nature of repeating units on the hydrodynamic volume of oligoesters. The study also shows that the conventional SEC calibration method using polystyrene standards leads to a significant overestimation of polyester average molar masses.


2000 ◽  
Vol 48 (2) ◽  
pp. 150-154 ◽  
Author(s):  
Yoichiro NIHASHI ◽  
Mitsuhiro ISHIDA ◽  
Fumio SAKAMOTO ◽  
Yuichiro NAKADA
Keyword(s):  

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