Method for determination of mercaptan sulphur content of light hydrocarbon products (silver nitrate method)

2015 ◽  
Keyword(s):  
Silver Nitrate ◽  
Light Hydrocarbon ◽  
Sulphur Content

Conductometric determination of trospium chloride by silver nitrate and phosphomolybidic acid

2020 ◽  
Vol 78 (5) ◽  
pp. 408-414
Author(s):  
E.M. Meselhy ◽  
A.A. Aboul Kheir ◽  
M.M. El Henawee ◽  
M.S. Elmasry
Keyword(s):  
Silver Nitrate ◽  
Trospium Chloride

scholarly journals Field test of available methods to measure remotely SO<sub>x</sub> and NO<sub>x</sub> emissions from ships

2014 ◽  
Vol 7 (8) ◽  
pp. 2597-2613 ◽  
Author(s):  
J. M. Balzani Lööv ◽  
B. Alfoldy ◽  
L. F. L. Gast ◽  
J. Hjorth ◽  
F. Lagler ◽  
...  
Keyword(s):  
Field Studies ◽  
Emission Factors ◽  
Sulphur Content ◽  
Nox Emission ◽  
Optical Methods ◽  
Optical Absorption Spectroscopy ◽  
Open Sea ◽  
Remote Measurements ◽  
Convenient Technique

Abstract. Methods for the determination of ship fuel sulphur content and NOx emission factors based on remote measurements have been compared in the harbour of Rotterdam and compared to direct stack emission measurements on the ferry Stena Hollandica. The methods were selected based on a review of the available literature on ship emission measurements. They were either optical (LIDAR, Differential Optical Absorption Spectroscopy (DOAS), UV camera), combined with model-based estimates of fuel consumption, or based on the so called "sniffer" principle, where SO2 or NOx emission factors are determined from simultaneous measurement of the increase of CO2 and SO2 or NOx concentrations in the plume of the ship compared to the background. The measurements were performed from stations at land, from a boat and from a helicopter. Mobile measurement platforms were found to have important advantages compared to the land-based ones because they allow optimizing the sampling conditions and sampling from ships on the open sea. Although optical methods can provide reliable results it was found that at the state of the art level, the "sniffer" approach is the most convenient technique for determining both SO2 and NOx emission factors remotely. The average random error on the determination of SO2 emission factors comparing two identical instrumental set-ups was 6%. However, it was found that apparently minor differences in the instrumental characteristics, such as response time, could cause significant differences between the emission factors determined. Direct stack measurements showed that about 14% of the fuel sulphur content was not emitted as SO2. This was supported by the remote measurements and is in agreement with the results of other field studies.

Colorimetric Determination of Oxyphenisatin and Oxyphenisatin Diacetate in Pharmaceutical Preparations

1964 ◽  
Vol 47 (4) ◽  
pp. 688-692
Author(s):  
Antoine Major
Keyword(s):  
Aqueous Solution ◽  
Organic Solvent ◽  
Silver Nitrate ◽  
Sodium Hydroxide ◽  
Column Chromatography ◽  
Sodium Hydroxide Solution ◽  
Pharmaceutical Preparations ◽  
Colorimetric Determination ◽  
Hydroxide Solution

Abstract A method is described which will quantitatively determine 0.1 mg oxyphenisatin or the diacetate in various pharmaceutical preparations. After removal of interferences by organic solvent extractions from aqueous solution and partition column chromatography, the reaction of oxyphenisatin (diacetate) with silver nitrate in alcoholic sodium hydroxide solution produces a violet solution, which follows Beer’s law (1—15 μg per ml). The method was satisfactorily applied to the assay of commercial tablets, liquids, and powders with recoveries, as per cent found of declared, in the range 95—101%.

Potentiometric Determination of Chlorides in Wine, Distilled Spirits, and Wine Vinegar

1966 ◽  
Vol 49 (3) ◽  
pp. 498-501
Author(s):  
Clifford E Hubach
Keyword(s):  
Silver Nitrate ◽  
Collaborative Study ◽  
Potentiometric Determination ◽  
End Point ◽  
Direct Titration ◽  
Distilled Spirits ◽  
Wine Vinegar ◽  
High Degree

Abstract Collaborative study of the Pro method for determining chlorides in wines and distilled spirits by direct titration with silver nitrate followed by potentiometric reading of the end point gave accurate and reproducible results. The procedure is suitable for repetitious analyses in control laboratories, and it is also adaptable to determinations requiring a high degree of precision. Recoveries of chloride added to samples averaged 99.7%. The method is recommended for adoption as official, first action.

Modified Method for the Determination of Mycotoxins in Cocoa Beans

1973 ◽  
Vol 56 (4) ◽  
pp. 1028-1030 ◽  
Author(s):  
Peter M Scott
Keyword(s):  
Silver Nitrate ◽  
Ochratoxin A ◽  
Nitrate Solution ◽  
Silver Nitrate Solution ◽  
Solvent Mixture ◽  
Cocoa Beans ◽  
Extraction Solvent ◽  
Modified Method

Abstract Method 26.026–26.030 was modified for the analysis of cocoa beans for aflatoxins by inclusion of 3% silver nitrate solution in the extraction solvent mixture. Recoveries of aflatoxins and ochratoxin A added at levels of 5–45 and 20–300 μg/kg, respectively, were satisfactory.

Volumetric Determination of Malathion, Using Dichlorofluorescein as Indicator

1976 ◽  
Vol 59 (1) ◽  
pp. 216-218
Author(s):  
Miguel Siquiroff ◽  
Ricardo Pollero ◽  
Rodolfo Goyena
Keyword(s):  
Standard Deviation ◽  
Petroleum Ether ◽  
Silver Nitrate ◽  
Ethyl Ether ◽  
Colorimetric Method ◽  
Florisil Column ◽  
Average Recovery ◽  
Florisil Column Chromatography ◽  
Volumetric Determination

Abstract A method has been developed which is based on alkali cleavage of malathion and volumetric determination of the resulting dimethylphosphorodithioate with silver nitrate, using dichlorofluorescein as the indicator. Pure malathion standards were analyzed by the proposed method, yielding a standard deviation of 0.27. Four typical malathion formulations containing talc, wheat flour, and anionic and nonionic emulsifiers were analyzed by both the proposed method and the former official first action colorimetric method with comparable results. Potential interferences from surfactants currently employed in liquid formulations are avoided by the use of Florisil column chromatography. Malathion is eluted from the column with petroleum ether-ethyl ether with an average recovery of 92.5%.

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