Electrically conducting rubber flooring

1959 ◽  
1942 ◽  
Vol 15 (1) ◽  
pp. 146-157 ◽  
Author(s):  
B. J. Habgood ◽  
J. R. S. Waring

Abstract (1) The scattered references in the literature dealing with conducting rubber have been collected together. (2) A résumé of existing ideas on the mechanism of electrical conduction is given, from which certain lines of development work suggested themselves. (3) Electrically conducting Neoprene or rubber compounds based on acetylene black are anisotropic, an effect which is particularly pronounced after extrusion. (4) By the use of fine channel black, either alone or in addition to acetylene black, the transverse conductivity is improved, thus reducing the anisotropy. (5) A further improvement can be obtained by using highly plasticized Neoprene or rubber which reduces the shear during extrusion operations. In the case of Neoprene, zinc oxide is omitted from the mixings to prevent set-up. (6) Conducting tubes having a transverse volume resistivity of 300 ohms per cu. cm., and a longitudinal resistivity of 60 to 70 ohms per cu. cm. have been obtained, using a potential difference of 6 volts. (7) Provisional methods of testing conducting rubber are suggested.


1957 ◽  
Vol 30 (2) ◽  
pp. 572-583
Author(s):  
D. G. Marshall

Abstract Many workers have studied the changes in resistivity that occur on deforming rubbers loaded with carbon black. This paper describes three types of experimental investigation that do not seem to have received detailed study previously, and also a theory that explains the results qualitatively in terms of variations of contact resistances between carbon black particles. Firstly, the changes of resistance of vulcanized natural rubber, Butyl rubber, Neoprene, and Thiokol FA loaded with carbon black have been studied during cyclic deformations. Secondly, the initial increase of resistance during stretching testpieces of vulcanized natural rubber containing several loadings of different carbon blacks has been investigated. Finally, the changes of resistance with time that occur after stretching and releasing samples of electrically conducting rubber have been studied. The ingredients and preparation of the compounds used in experiments discussed in this paper are listed in the Appendix. The testpieces used in the following experiments were approximately 0.7 cm. wide, 0.1 cm. thick, and 7.0 cm. long. Electrical contact was established by means of brass strips bonded by molding into the ends of the samples, so that the direction of current flow was along the length of the pieces, and in the same direction as the extensions.


1949 ◽  
Vol 22 (2) ◽  
pp. 535-554
Author(s):  
K. A. Lane ◽  
E. R. Gardner

Abstract In recent years the dangers and inconveniences arising from the presence of static electrical charges on rubber conveyor belts, rubber flooring, rubber-tired vehicles and the like, have aroused interest in the use of electrically conducting rubber as a means of minimizing the accumulation of static electricity. Conventional rubber compounds, which have electrical resistivities normally above 107 ohm-cm, and as high as 1014–1016 ohm-cm. for nonblack compositions, favor the accumulation of static charges. By using high loadings of channel black, the resistivity can be reduced considerably. If special types of carbon black are employed the resistivity can be reduced to a very low value ; in fact, the development of a compound with a resistivity of 1 ohm-cm. has been reported. A compound with a resistivity of about 10 ohm-cm., processible on ordinary factory-size rubber machinery, is described later in this paper. Rubber compounds with resistivities less than 107 ohm-cm. are generally grouped under the generic title of “electrically conducting rubbers”. The conduction of electricity through rubber-carbon black compositions is attributed to the ability of the carbon black to form chains of particles through the rubber. The formation of these chains depends on the particle size, crystal structure, and degree of dispersion of the black. The special types of black referred to above, termed conducting blacks, possess this ability for chain formation to an advanced degree. The work described below deals with the compounding of conducting rubbers, their application, and the methods used for testing. It appears under three main headings: measurement of resistivity; development of highly conducting rubber ; and development and testing of antistatic tires.


2014 ◽  
Vol 8 (1) ◽  
pp. 1457-1463
Author(s):  
Salah Abdulla Hasoon

Novel electrically conducting polymeric materials are prepared in this work. Polythiophene (PT) and poly (3-Methelthiophene) (P3MT) films were prepared by electro-polymerization method using cyclic voltammetry in acetonitrile as a solvent and lithium tetrafluoroborate as the electrolyte on a gold electrode. Electrical properties of P3MT have been examined in different environments using UV-Vis absorption spectroscopy and quantum mechanical ab initio calculations, The observed absorption peaks at 314 and 415 nm, were attributed to the n-π* and π-π* transitions, respectively in the conjugated polymer chain, in contrast, the observed absorbance peak at 649 nm, is responsible for electric conduction. The temperature dependence of the conductivity can be fitted to the Arrhenius and the VTF equations in different temperature ranges.


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