Periodicals of reference value form and presentation.

1959 ◽  
Keyword(s):  
Reference Value

DFT Benchmark Study of the O--O Bond Dissociation Energy in Peroxides Validated with High-Level Ab-Initio Calculations

2019 ◽  
Author(s):  
Danilo Carmona ◽  
Pablo Jaque ◽  
Esteban Vöhringer-Martinez
Keyword(s):  
Reference Value ◽  
Basis Set ◽  
Basis Sets ◽  
Mean Deviation ◽  
Bond Dissociation ◽  
Dissociation Energies ◽  
The Mean ◽  
Experimental Values ◽  
High Level ◽  
Almost All

<div><div><div><p>Peroxides play a central role in many chemical and biological pro- cesses such as the Fenton reaction. The relevance of these compounds lies in the low stability of the O–O bond which upon dissociation results in radical species able to initiate various chemical or biological processes. In this work, a set of 64 DFT functional-basis set combinations has been validated in terms of their capability to describe bond dissociation energies (BDE) for the O–O bond in a database of 14 ROOH peroxides for which experimental values ofBDE are available. Moreover, the electronic contributions to the BDE were obtained for four of the peroxides and the anion H2O2− at the CBS limit at CCSD(T) level with Dunning’s basis sets up to triple–ζ quality provid- ing a reference value for the hydrogen peroxide anion as a model. Almost all the functionals considered here yielded mean absolute deviations around 5.0 kcal mol−1. The smallest values were observed for the ωB97 family and the Minnesota M11 functional with a marked basis set dependence. Despite the mean deviation, order relations among BDE experimental values of peroxides were also considered. The ωB97 family was able to reproduce the relations correctly whereas other functionals presented a marked dependence on the chemical nature of the R group. Interestingly, M11 functional did not show a very good agreement with the established order despite its good performance in the mean error. The obtained results support the use of similar validation strategies for proper prediction of BDE or other molecular properties by DF Tmethods in subsequent related studies.</p></div></div></div>

Das nachhaltig verfügbare Holznutzungspotenzial im Schweizer Wald

2016 ◽  
Vol 167 (3) ◽  
pp. 162-171 ◽  
Author(s):  
Ruedi Taverna ◽  
Michael Gautschi ◽  
Peter Hofer
Keyword(s):  
National Level ◽  
Reference Value ◽  
Forest Growth ◽  
Long Term Effects ◽  
Management Scenarios ◽  
Additional Time ◽  
Basic Scenario ◽  
Economic Framework ◽  
Forest Growth Model ◽  
New Findings

The sustainably available wood use potential in Swiss forests Based on the most recent simulations created using the Massimo forest growth model, the sustainably available wood use potential in Swiss forests was calculated for five management scenarios for the next three decades as well as for two additional time periods in the future (to monitor the long-term effects). The term “sustainably available wood use potential” covers those wood quantities that could be put on the market, taking into account socio-ecological and economic restrictions on use. The sustainably available wood use potential is provided for production regions, priority functions as well as the assortment and qualities of timber. The previously used factors of the applied “onion” model were checked and modified, if necessary, in order to take new findings and current cost developments into consideration. The calculations for all scenarios come up with a sustainably available wood use potential that is much lower than in earlier investigations. Depending on the scenario and decade, sustainably available wood use potential accounts for less than 50% of the total use potential. The biggest decrease in total use potential was due to economic framework conditions. Turning to Switzerland as a whole, towards the end of the investigation period (2106) those scenarios including a sharp increase in use in the first three decades result in a sustainably available wood use potential that is clearly lower than the reference value used at the beginning of the simulation. In the basic scenario (constant stock) and in the scenario in which the form of management used to date (increasing stock) was simulated, the sustainably available wood use potential at national level remained more or less the same throughout the simulation period, ranging from 5 to 6 million m3 per year.

Determination of Traces Heavy Metals from Solid Residues Formed by Combustion of Lignite in Relation to Degree of Accessibility in Soil and Plants

2017 ◽  
Vol 68 (10) ◽  
pp. 2363-2366
Author(s):  
Delia Nica Badea
Keyword(s):  
Heavy Metals ◽  
Power Plant ◽  
Thermal Power ◽  
Reference Value ◽  
Combustion Products ◽  
Toxic Heavy Metals ◽  
Area Of Influence ◽  
Risk Potential

The paper evaluates the presence and content of traces of heavy metals Hg, Pb, Ni, Cd (total forms) from coal and solid combustion products, the degree of transfer and accessibility in the area of influence of a lignite power plant. The content of toxic heavy metals in residues are characterized by RE Meiji [ 1 (Pb and Hg) and REMeij �1 (Ni and Cd) for the filter ash. Pb and Ni content in the soil exceeds normal values, and Pb exceeds and alert value for sensitive soils around the residue deposit (70.20 mg.Kg-1). The degree of accessibility of the metals in plants (TF), reported at the Khan reference value (0.5), indicates a significant bioaccumulation level for the metals: Cd (1.9) and Hg (0.6) inside the deposit; Cd (0.39) at the base of the deposit, Hg (0.8) in the area of the thermal power plant. The trace levels of heavy metals analyzed by GFAAS and CVAAS (Hg), indicates a moderate risk potential for food safety and quality of life in the studied area.

The design of modular oil tank: A new design process model

2020 ◽  
Vol 15 ◽  
Author(s):  
Jin Li ◽  
Xingsheng Jiang ◽  
Jingye Li ◽  
Yadong Zhao ◽  
Xuexing Li
Keyword(s):  
Product Design ◽  
Design Process ◽  
Process Model ◽  
Mechanical Design ◽  
Computer Software ◽  
Reference Value ◽  
Fuel Tank ◽  
Design Quality ◽  
Design Time ◽  
Design Process Model

Background: In the whole design process of modular fuel tank, there are some unreasonable phenomena. As a result, there are some defects in the design of modular fuel tank, and the function does not meet the requirements in advance. This paper studies this problem. Objective: Through on-the-spot investigation of the factory, a mechanical design process model is designed. The model can provide reference for product design participants on product design time and design quality, and can effectively solve the problem of low product design quality caused by unreasonable product design time arrangement. Methods: After sorting out the data from the factory investigation, computer software is used to program, simulate the information input of mechanical design process, and the final reference value is got. Results: This mechanical design process model is used to guide the design and production of a new project, nearly 3 months ahead of the original project completion time. Conclusion: This mechanical design process model can effectively guide the product design process, which is of great significance to the whole mechanical design field.

Compensating Resonant Frequency via Adjusting Adjustable Coil Automatically

2019 ◽  
Vol 12 (5) ◽  
pp. 432-438
Author(s):  
Jin Xu ◽  
Yuting Zhao
Keyword(s):  
Resonant Frequency ◽  
Power Transmission ◽  
Reference Value ◽  
Transmission Efficiency ◽  
Theoretical Research ◽  
Future Research ◽  
Wireless Power ◽  
Wireless Power Transmission ◽  
Resonant Coupling ◽  
Transmission Distance

Background: Detuning is the main problem that affects the efficiency and transmission distance of the resonant coupling Wireless Power Transmission (WPT). The distance of load and the offset of the load position could cause serious detuning. Methods: This paper presents an adjustable coil in which inductance can be adjusted. Then a model of WPT was established that could compensate resonant frequency automatically using the adjustable coil. Next, the relationship between the primary resonant frequency and the transmission efficiency is analyzed from the circuit. The analysis proved that the design of the adjustable coil could improve the transmission efficiency of the WPT system. Finally, a prototype of WPT system was built. Results: The experimental results showed that WPT system with adjustable coil can improve the transmission efficiency which proves the theoretical research. At the same time, it has essential reference value for the future research of WPT. Conclusion: In this paper, aiming at the system detuning caused by some other factors, such as the position shift of the load during the wireless power transmission, an adjustable coil is proposed.

scholarly journals An Intelligent Evaluation Method to Analyze the Competitiveness of Airlines

2020 ◽  
Vol 2020 ◽  
pp. 1-9
Author(s):  
Jun Zhao ◽  
Xumei Chen
Keyword(s):  
Neural Network ◽  
Prior Knowledge ◽  
Evaluation Method ◽  
Standard Sample ◽  
Reference Value ◽  
The Self ◽  
Index Data ◽  
Som Neural Network ◽  
Simulation Results ◽  
Self Organizing

An intelligent evaluation method is presented to analyze the competitiveness of airlines. From the perspective of safety, service, and normality, we establish the competitiveness indexes of traffic rights and the standard sample base. The self-organizing mapping (SOM) neural network is utilized to self-organize and self-learn the samples in the state of no supervision and prior knowledge. The training steps of high convergence speed and high clustering accuracy are determined based on the multistep setting. The typical airlines index data are utilized to verify the effect of the self-organizing mapping neural network on the airline competitiveness analysis. The simulation results show that the self-organizing mapping neural network can accurately and effectively classify and evaluate the competitiveness of airlines, and the results have important reference value for the allocation of traffic rights resources.

scholarly journals Direct measurement of stool consistency by texture analyzer and calculation of reference value in Belgian general population

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Kazunori Matsuda ◽  
Takuya Akiyama ◽  
Satoshi Tsujibe ◽  
Kaihei Oki ◽  
Agata Gawad ◽  
...  
Keyword(s):  
Water Content ◽  
Direct Measurement ◽  
Direct Method ◽  
Reference Value ◽  
Stool Consistency ◽  
Texture Analyzer ◽  
Simple Protocol ◽  
Stool Form ◽  
Micro Systems ◽  
And Function

AbstractStool consistency is evaluated mainly in reference to indirect indicators such as water content or the appearance of stool forms using Bristol Stool Form Scale (BSFS). Methods of measurement are limited. We thus aimed to develop a simple protocol for direct measurement of stool consistency using the TA.XTExpress Texture Analyser (Stable Micro Systems Ltd.). We developed a protocol which enables mechanical quantification of the gram-force against a cylindrical probe (ø 6 mm) pushed into the stool surface at 2.0 mm/s to 5 mm depth. The consistency of 252 stools collected from 40 healthy Belgians was evaluated by the direct method and by the indirect indicators (water content and BSFS) for comparison. The log-transformed stool consistency values measured by the texture analyzer had a negative linear correlation with the stool water contents (rrm = − 0.781) with homoscedastic variance, suggesting the appropriateness of the new protocol. They showed a similar correlation with the BSFS, but with a large variance in the consistency values of normal stool forms. This correlation was much smaller for BSFS scored by subjects (rrm = − 0.587) than by experts (rrm = − 0.789), collectively indicating BSFS as a rough indicator of stool consistency susceptible to subjective bias despite its effectiveness in clinical use. The optimized direct method using the texture analyzer enables the accurate quantification of stool consistency, which facilitates understanding of the intestinal environment and function and thus may enhance the value of the stool as a predictor of human health.

Design and simulation research of the double-spin folding mechanism based on a suspended missile

2021 ◽  
pp. 154851292110231
Author(s):  
ZH Yuan ◽  
SY Guo ◽  
SN Zhang ◽  
JQ Zhao ◽  
WJ Lu ◽  
...  
Keyword(s):  
High Reliability ◽  
Lift Coefficient ◽  
Great Influence ◽  
Reference Value ◽  
Aerodynamic Characteristics ◽  
Simulation Software ◽  
Fluid Simulation ◽  
Simulation Research ◽  
Double Spin ◽  
Locking Mechanism

Based on the suspension of a missile using folding rotary wings and airbags, in order to improve the basic parameters and motion characteristics of the rotor during the unfolding process and analyze the aerodynamic characteristics of the entire device in the suspension state, after proposing a scheme of double-spin mechanism, the main folding and unfolding mechanism, initial driving device, rotating driving device, and locking mechanism were designed, and the simulation research is studied by the Automatic Dynamic Analysis of Mechanical System and Ansys Fluent Fluid Simulation software, respectively. The results show that the rotation rate was controlled at 41.8 mm/s, the various motion parameters are reasonable, and the operation process is relatively smooth, with high reliability. The speed and pressure value at the tip of the rotor are higher and the aerodynamic disturbance is obvious, which has a great influence on the aerodynamic performance. The speed and pressure distribution of the surrounding flow field is stable, the lift provided is 46 N, and the lift coefficient is 0.55, which can ensure the long-time suspension state of the missile. This paper puts forward a valuable design idea and has practical reference value for the research of the suspended missile.

scholarly journals Probabilistic Assessment of Roof Snow Load and the Calibration of Shape Coefficients in the Eurocodes

2021 ◽  
Vol 11 (7) ◽  
pp. 2984
Author(s):  
Pietro Croce ◽  
Paolo Formichi ◽  
Filippo Landi
Keyword(s):  
Conversion Factor ◽  
Reference Value ◽  
Construction Site ◽  
Probability Of Exceedance ◽  
Snow Load ◽  
Shape Coefficient ◽  
Annual Probability ◽  
Wind Exposure ◽  
Design Values ◽  
One Year

In modern structural codes, the reference value of the snow load on roofs is commonly given as the product of the characteristic value of the ground snow load at the construction site multiplied by the shape coefficient. The shape coefficient is a conversion factor which depends on the roof geometry, its wind exposure, and its thermal properties. In the Eurocodes, the characteristic roof snow load is either defined as the value corresponding to an annual probability of exceedance of 0.02 or as a nominal value. In this paper, an improved methodology to evaluate the roof snow load characterized by a given probability of exceedance (e.g., p=0.02 in one year) is presented based on appropriate probability density functions for ground snow loads and shape coefficients, duly taking into account the influence of the roof’s geometry and its exposure to wind. In that context, the curves for the design values of the shape coefficients are provided as a function of the coefficient of variation (COVg) of the yearly maxima of the snow load on the ground expected at a given site, considering three relevant wind exposure conditions: sheltered or non-exposed, semi-sheltered or normal, and windswept or exposed. The design shape coefficients for flat and pitched roofs, obtained considering roof snow load measurements collected in Europe during the European Snow Load Research Project (ESLRP) and in Norway, are finally compared with the roof snow load provisions given in the relevant existing Eurocode EN1991-1-3:2003 and in the new version being developed (prEN1991-1-3:2020) for the “second generation” of the Eurocodes.

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