Rubber compounding ingredients. Carbon black. Determination of sieve residue

2007 ◽  
Keyword(s):  
2020 ◽  
Vol 9 (1) ◽  
pp. 170-181 ◽  
Author(s):  
Shangyong Zhang ◽  
Ruipeng Zhong ◽  
Ruoyu Hong ◽  
David Hui

AbstractThe surface activity of carbon black (CB) is an important factor affecting the reinforcement of rubber. The quantitative determination of the surface activity (surface free energy) of CB is of great significance. A simplified formula is obtained to determine the free energy of CB surface through theoretical analysis and mathematical derivation. The surface free energy for four kinds of industrial CBs were measured by inverse gas chromatography, and the influential factors were studied. The results showed that the aging time of the chromatographic column plays an important role in accurate measurement of the surface free energy of CB, in comparison with the influences from the inlet pressure and carrier gas flow rate of the chromatographic column filled with CB. Several kinds of industrial CB were treated at high temperature, and the surface free energy of CB had a significant increase. With the increase of surface free energy, the maximum torque was decreased significantly, the elongation at break tended to increase, the heat generation of vulcanizates was increased, and the wear resistance was decreased.


AIHAJ ◽  
1982 ◽  
Vol 43 (12) ◽  
pp. 908-911 ◽  
Author(s):  
J.E. MEHLER ◽  
R.O. LANKENAU ◽  
F. STEVENS MEES

1928 ◽  
Vol 1 (3) ◽  
pp. 485-497 ◽  
Author(s):  
C. R. Johnson

Abstract The rates of evolution of gas from carbon black with variation of time, temperature, and pressure have been determined. Complete analyses have been made of five types of carbon black, which involve an organic combustion of the original sample, an organic combustion of the sample after the gases have been removed, a determination of the loss in weight represented by the gases removed, analyses of the gases removed, and finally a complete accounting, or balance, of the carbon in the steps considered. In an attempt to supply some missing information not revealed by the foregoing, some special gas analyses under varying conditions were made. The relationship between the amount and composition of volatile matter evolved from carbon blacks and the properties imparted to vulcanized rubber when compounded with these blacks has been studied.


1980 ◽  
Vol 52 (13) ◽  
pp. 2033-2036 ◽  
Author(s):  
Alessandro. Bacaloni ◽  
Giancarlo. Goretti ◽  
Aldo. Lagana ◽  
Bianca Maria. Petronio ◽  
Mauro. Rotatori

1997 ◽  
Vol 70 (2) ◽  
pp. 222-230 ◽  
Author(s):  
Emma Thorn-Csányi ◽  
Hans-Detlef Luginsland

Abstract Intermolecular metathetic polymer degradation opens up an analytic method to identify the quality and quantity of the components in blends of different types of rubber even if they are crosslinked and filled with carbon black, mineral oil, etc.. Furthermore the amount of soluble and insoluble additives can be determined. Moreover, metathetic degradation allows for determination of detailed information about the chemical microstructure (e.g. sequence length distribution of 1,2-butadiene and styrene units) of the rubbers used. This method is suitable for analysis of rubber components in tires.


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