Fire hazard testing. Heat release

2001 ◽  
Keyword(s):  
Heat Release ◽  
Fire Hazard

scholarly journals Synthesis of a Novel Phosphorous-Nitrogen Based Charring Agent and Its Application in Flame-retardant HDPE/IFR Composites

Polymers ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 1062 ◽  
Author(s):  
Junlei Chen ◽  
Jihui Wang ◽  
Aiqing Ni ◽  
Hongda Chen ◽  
Penglong Shen
Keyword(s):  
Thermal Stability ◽  
Heat Release ◽  
Flame Retardant ◽  
Flame Retardancy ◽  
Fire Hazard ◽  
Weight Ratio ◽  
Charring Agent ◽  
Migration Percentage ◽  
Ul 94 ◽  
Thermal Stability Of

In this work, a novel phosphorous–nitrogen based charring agent named poly(1,3-diaminopropane-1,3,5-triazine-o-bicyclic pentaerythritol phosphate) (PDTBP) was synthesized and used to improve the flame retardancy of high-density polyethylene (HDPE) together with ammonium polyphosphate (APP). The results of Fourier transform infrared spectroscopy (FTIR) and 13C solid-state nuclear magnetic resonance (NMR) showed that PDTBP was successfully synthesized. Compared with the traditional intumescent flame retardant (IFR) system contained APP and pentaerythritol (PER), the novel IFR system (APP/PDTBP, weight ratio of 2:1) could significantly promote the flame retardancy, water resistance, and thermal stability of HDPE. The HDPE/APP/PDTBP composites (PE3) could achieve a UL-94 V-0 rating with LOI value of 30.8%, and had a lower migration percentage (2.2%). However, the HDPE/APP/PER composites (PE5) had the highest migration percentage (4.7%), lower LOI value of 23.9%, and could only achieve a UL-94 V-1 rating. Besides, the peak of heat release rate (PHRR), total heat release (THR), and fire hazard value of PE3 were markedly decreased compared to PE5. PE3 had higher tensile strength and flexural strength of 16.27 ± 0.42 MPa and 32.03 ± 0.59 MPa, respectively. Furthermore, the possible flame-retardant mechanism of the APP/PDTBP IFR system indicated that compact and continuous intumescent char layer would be formed during burning, thus inhibiting the degradation of substrate material and improving the thermal stability of HDPE.

Heat release rate: The single most important variable in fire hazard

1992 ◽  
Vol 18 (3) ◽  
pp. 255-272 ◽  
Author(s):  
Vytenis Babrauskas ◽  
Richard D. Peacock
Keyword(s):  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Fire Hazard ◽  
Important Variable ◽  
In Fire

scholarly journals INVESTIGATION THE FIRE HAZARD OF PLYWOODS USING A CONE CALORIMETER

Wood Research ◽  
2021 ◽  
Vol 66 (6) ◽  
pp. 933-942
Author(s):  
ZHIGANG WU ◽  
XUE DENG ◽  
LIFEN LI ◽  
LIPING YU ◽  
JIE CHEN ◽  
...  
Keyword(s):  
Oxygen Consumption ◽  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Cone Calorimeter ◽  
High Efficiency ◽  
Fire Hazard ◽  
Mass Loss Rate ◽  
Fire Retardant ◽  
Safety Level

A high-efficiency fire retardant composition was prepared with dicyandiamide, phosphoric acid, boric acid, borax, urea and magnesium sulfate and it was used to process veneers which were then to prepare the plywood. Meanwhile, heat release and smoke release from combustion of plywood were tested by a cone calorimeter, including heat release rate, mass loss rate, CO yield, CO2 yield and oxygen consumption. Results showed that the plywood with this fire retardant treatment had the better flame-retardant performance and smoke suppression effect as well as the stronger char-forming capability compared to plywood without fire retardant treatment. The average heat release rate, total heat release, average effective heat of combustion, total smoke release, CO yield and oxygen consumption of the plywood with fire retardant treatment were decreased by 63.72%, 91.94%, 53.70%, 76.81%, 84.99% and 91.86%, respectively. Moreover, the fire growth index of plywood treated by fire retardant was relatively low (3.454 kW·m-2·s-1) and it took longer time to reach the peak heat release rate, accompanied with slow fire spreading. The fire performance index was relatively high (0.136 s·m2·kW-1) and it took longer time to be ignited, thus leaving a long time for escaping at fire accidents. The fire hazard of plywood with fire retardant treatment was low, and its safety level was high.

An investigation on fire hazard and smoke toxicity of epoxy FRP composites

2017 ◽  
Vol 8 (3) ◽  
pp. 230-237
Author(s):  
Saeed Bakhtiyari ◽  
Leila Taghi Akbari ◽  
Masoud Jamali Ashtiani
Keyword(s):  
Heat Release ◽  
Construction Industry ◽  
Fire Hazard ◽  
Test Method ◽  
Fiber Reinforced Polymers ◽  
Content Type ◽  
Frp Composites ◽  
Reinforced Polymer ◽  
Cone Calorimeter Test ◽  
Fibre Reinforced Polymer

PurposeThe purpose of this study is assessment of fire and smoke hazards of some fiber reinforced polymers (FRP). The use of FRP strengthening strips has been found rapid growth in construction industry of Iran and many other countries. However, the fire and smoke hazards of these materials in both construction and use phases need to be determined and the appropriated measures against fire should be taken. Design/methodology/approachThe fire hazards of two types of fibre-reinforced epoxy composites (graphite fibre-reinforced polymer and carbon fibre-reinforced polymer) were investigated in bench-scale using cone calorimeter test method. Time to ignition, heat release rate, total heat release, smoke release and carbon monoxide production were measured and analysed. Time to flashover of an assumed room lined with the tested FRP was analysed with Conetools software. Smoke production and toxicity of the considered composites were also analysed and discussed, using the fractional effective dose parameter. FindingsThe results showed that the tested FRP products had a high fire hazard and a potential high contribution to fire growth. The tests also proved that the used epoxy resin had a low glass transition temperature, around 50°C; therefore, the mechanical strength of the product could be drastically reduced at first stages of a probable fire incident. This also showed that a regular thermal barrier, typically used for protection of plastic foams against fire, could not be sufficient for the protection of strengthening FRP composites. Originality/valueThis research was carried out for the first time for the materials used in construction industry of Iran. The results and achievements were very useful for safe use and development of proper details of application of the system.

scholarly journals Fire Behavior of Thermally Thin Materials in Cone Calorimeter

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1297
Author(s):  
Marouane El El Gazi ◽  
Rodolphe Sonnier ◽  
Stéphane Giraud ◽  
Marcos Batistella ◽  
Shantanu Basak ◽  
...  
Keyword(s):  
Heat Flux ◽  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Cone Calorimeter ◽  
Fire Hazard ◽  
Heat Of Combustion ◽  
Sample Weight ◽  
Effective Heat ◽  
Effective Heat Of Combustion

In this study, a representative set of thermally thin materials including various lignocellulosic and synthetic fabrics, dense wood, and polypropylene sheets were tested using a cone calorimeter at different heat fluxes. Time-to-ignition, critical heat flux, and peak of heat release rate (pHRR) were the main parameters considered. It appears that the flammability is firstly monitored by the sample weight. Especially, while the burning rate of thermally-thin materials does never reach a steady state in cone calorimeter, their pHRR appears to be mainly driven by the fire load (i.e., the product of sample weight and effective heat of combustion) with no or negligible influence of textile structure. A simple phenomenological model was proposed to calculate the pHRR taking into account only three parameters, namely heat flux, sample weight, and effective heat of combustion. The model allows predicting easily the peak of heat release rate, which is often considered as the main single property informing about the fire hazard. It also allows drawing some conclusions about the flame retardant strategies to reduce the pHRR.

scholarly journals A Simplified Analysis to Predict the Fire Hazard of Primary Lithium Battery

2018 ◽  
Vol 8 (11) ◽  
pp. 2329 ◽  
Author(s):  
Mingyi Chen ◽  
Jiahao Liu ◽  
Ouyang Dongxu ◽  
Shuchao Cao ◽  
Zhi Wang ◽  
...  
Keyword(s):  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Lithium Batteries ◽  
Lithium Battery ◽  
Fire Hazard ◽  
Ignition Time ◽  
Combustion Properties ◽  
Primary Lithium Battery ◽  
Simplified Analysis

To better understand the fire risk of primary lithium batteries, the combustion properties of different numbers of primary lithium batteries were investigated experimentally in this work. Based on the t2 fire principle and total heat release results from the experiments, a simplified analysis was developed to predict the fire hazard, and especially the heat release rate, of primary lithium batteries. By comparing the experiment and simulation results, the simulation line agrees well with the heat release rate curve based on the oxygen consumption measurements of a single primary lithium battery. When multiple batteries are burned, each battery ignites at different times throughout the process. The ignition time difference parameter is introduced into the simulation to achieve similar results as during multiple batteries combustion. These simulation curves conform well to the experimental curves, demonstrating that this heat release rate simulation analysis is suitable for application in batteries fires.

scholarly journals Inversion for Fire Heat-Release Rate Using Heat Flux Measurements

2020 ◽  
Vol 142 (5) ◽  
Author(s):  
Andrew J. Kurzawski ◽  
Ofodike A. Ezekoye
Keyword(s):  
Heat Flux ◽  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Fire Hazard ◽  
Computational Cost ◽  
Inversion Algorithm ◽  
Fire Dynamics ◽  
Oxygen Consumption Calorimetry ◽  
Flux Measurements

Abstract In fire hazard calculations, knowledge of the heat-release rate (HRR) of a burning item is imperative. Typically, room-scale calorimetry is conducted to determine the HRRs of common combustible items. However, this process can be prohibitively expensive. In this work, a method is proposed to invert for the HRR of a single item burning in a room using transient heat flux measurements at the walls and ceiling near the item. The primary device used to measure heat flux is the directional flame thermometer (DFT). The utility of the inverse method is explored on both synthetically generated and experimental data using two so-called forward models in the inversion algorithm: fire dynamics simulator (FDS) and the consolidated model of fire and smoke transport (CFAST). The fires in this work have peak HRRs ranging from 200 kW to 400 kW. It was found that FDS outperformed CFAST as a forward model at the expense of increased computational cost and that the error in the inverse reconstruction of a 400 kW steady fire was on par with room-scale oxygen consumption calorimetry.

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