scholarly journals Chemical Analysis of Wastewater from Unconventional Drilling Operations

Water ◽  
2015 ◽  
Vol 7 (12) ◽  
pp. 1568-1579 ◽  
Author(s):  
Jonathan Thacker ◽  
Doug Carlton ◽  
Zacariah Hildenbrand ◽  
Akinde Kadjo ◽  
Kevin Schug
Keyword(s):  
Chemical Analysis ◽  
Drilling Operations ◽  
Unconventional Drilling

scholarly journals Analysis on Combined Heat and Power and Combined Heat and Power Hybrid Systems for Unconventional Drilling Operations

2021 ◽  
Author(s):  
Diego Dranuta ◽  
Derek Johnson
Keyword(s):  
Natural Gas ◽  
Fuel Consumption ◽  
Marcellus Shale ◽  
The United States ◽  
Combined Heat And Power ◽  
Utilization Factor ◽  
Fossil Energy ◽  
Drilling Operations ◽  
Well Development ◽  
Unconventional Drilling

Abstract The United States (U.S.) has experienced a natural gas “boom” due to the development of unconventional shale plays, but well development is energy intensive. Operations use electric drilling rigs typically powered by either three high-horsepower diesel engines (HHPDE) or three dedicated natural gas engines (DNGE) and associated generators. From a first law analysis, HHPDEs peak at about 42% efficient at full load, while DNGE peak at about 30%. Most fuel energy is lost as heat rejected by the exhaust and radiators. Concurrently, during cold seasonsor or in cold regions rigs utilize boilers to provide steam throughout the rig to prevent freezing and provide comfort. Our analysis focused on a combined heat power (CHP) approach to improve the utilization factor (UF) of fossil energy consumed during unconventional drilling operations. Engine activity, boiler fuel consumption, and exhaust gas temperatures were recorded during winter drilling of an entire well in the Marcellus shale. Four characteristic activity cycles were extracted from recorded activity to represent four energy consumption scenarios. Exhaust and jacket water heat exchangers (E-HEX, JW-HEX) were designed and simulated, and results were analyzed in 0-D models for the four case scenarios. A 584-kWh hybrid energy management system (HEMS) was also designed and simulated into the model as another method to reduce fossil energy fuel consumption during well development. HHPDE UF improved on average from 35.7% to 55.7% if only E-HEX were used and improved to 72.7% if JW-HEX were also used. DNGE average UF increased from 19.0% to 34.9% using E-HEX only. HEMS utilization improved UF up to an average of 76.9% and 39.1% for HHPDE CHP and DNGE CHP systems, respectively.

Aspects of microanalysis in a transmission electron microscope

1978 ◽  
Vol 36 (1) ◽  
pp. 510-511
Author(s):  
R. Sinclair ◽  
B.E. Jacobson
Keyword(s):  
Grain Size ◽  
Electron Beam ◽  
Electron Microscope ◽  
Chemical Analysis ◽  
Transmission Electron Microscope ◽  
Vapor Deposition ◽  
Critical Currents ◽  
X Ray ◽  
Fine Grain ◽  
Transmission Electron

INTRODUCTIONThe prospect of performing chemical analysis of thin specimens at any desired level of resolution is particularly appealing to the materials scientist. Commercial TEM-based systems are now available which virtually provide this capability. The purpose of this contribution is to illustrate its application to problems which would have been intractable until recently, pointing out some current limitations.X-RAY ANALYSISIn an attempt to fabricate superconducting materials with high critical currents and temperature, thin Nb3Sn films have been prepared by electron beam vapor deposition [1]. Fine-grain size material is desirable which may be achieved by codeposition with small amounts of Al2O3 . Figure 1 shows the STEM microstructure, with large (∽ 200 Å dia) voids present at the grain boundaries. Higher quality TEM micrographs (e.g. fig. 2) reveal the presence of small voids within the grains which are absent in pure Nb3Sn prepared under identical conditions. The X-ray spectrum from large (∽ lμ dia) or small (∽100 Ǻ dia) areas within the grains indicates only small amounts of A1 (fig.3).

Integrated morphometrical and electron energy loss image analysis in cytochemistry

1989 ◽  
Vol 47 ◽  
pp. 402-403
Author(s):  
W.C. de Bruijn ◽  
A.A.W. de Jong ◽  
C.W.J. Sorber
Keyword(s):  
Image Analysis ◽  
Acid Phosphatase ◽  
Chemical Analysis ◽  
Active Form ◽  
List Type ◽  
Type Number ◽  
Enzyme Cytochemistry ◽  
Related Data ◽  
Endogenous Peroxidase ◽  
Electron Energy Loss

One aspect of enzyme cytochemistry is, whether all macrophage lysosomal hydrolytical enzymes are present in an active form, or are activated upon stimulation. Integrated morphometrical and chemical analysis has been chosen as a tool to illucidate that cytochemical problem. Mouse peritoneal resident macrophages have been used as a model for this complicated integration of morphometrical and element-related data. Only aldehyde-fixed cells were treated with three cytochemical reactions to detect different enzyme activities within one cell (for details see [1,2]). The enzyme-related precipitates anticipated to be differentiated, were:(1).lysosomal barium and sulphur from aryl sulphatase activity,(2).lysosomal cerium and phosphate from acid phosphatase activity and(3).platinum/di-amino-benzidine( D A B) complex from endogenous peroxidase activity.

Microdomains in BaFeO3-y (0.35 < y < 0.50)

1990 ◽  
Vol 48 (4) ◽  
pp. 780-781
Author(s):  
M. Vallet-Regí ◽  
M. Parras ◽  
J.M. González-Calbet ◽  
J.C. Grenier
Keyword(s):  
Electron Diffraction ◽  
Chemical Analysis ◽  
Monoclinic Phase ◽  
Orthorhombic Phase ◽  
Total Iron ◽  
Zone Axis ◽  
Electron Micrograph ◽  
X Ray Diffraction ◽  
X Ray ◽  
Compositional Variations

BaFeO3-y compositions (0.35<y<0.50) have been investigated by means of electron diffraction and microscopy to resolve contradictory results from powder X-ray diffraction data.The samples were obtained by annealing BaFeO2.56 for 48 h. in the temperature range from 980°C to 1050°C . Total iron and barium in the samples were determined using chemical analysis and gravimetric methods, respectively.In the BaFeO3-y system, according to the electron diffraction and microscopy results, the nonstoichiometry is accommodated in different ways as a function of the composition (y):In the domain between BaFeO2.5+δBaFeO2.54, compositional variations are accommodated through the formation of microdomains. Fig. la shows the ED pattern of the BaFeO2.52 material along thezone axis. The corresponding electron micrograph is seen in Fig. 1b. Several domains corresponding to the monoclinic BaFeO2.50 phase, intergrow with domains of the orthorhombic phase. According to that, the ED pattern of Fig. 1a, can be interpreted as formed by the superposition of three types of diffraction maxima : Very strong spots corresponding to a cubic perovskite, a set of maxima due to the superposition of three domains of the monoclinic phase along [100]m and a series of maxima corresponding to three domains corresponding to the orthorhombic phase along the [100]o.

High quality bergamot oil from Cephallonia (Greece): chemical analysis using enantiomeric GC-MS and larvicidal activity against mosquitoes

Planta Medica ◽  
2008 ◽  
Vol 74 (09) ◽  
Author(s):  
E Melliou ◽  
P Magiatis ◽  
A Michaelakis ◽  
G Koliopoulos ◽  
AL Skaltsounis
Keyword(s):  
Chemical Analysis ◽  
Larvicidal Activity ◽  
High Quality ◽  
Bergamot Oil

Chemical Analysis of an Ayurvedic Herbo-Metallic Preparation Containing Mercury: Speciation of Mercury

Planta Medica ◽  
2011 ◽  
Vol 77 (05) ◽  
Author(s):  
B Avula ◽  
YH Wang ◽  
CS Rumalla ◽  
AG Chittiboyina ◽  
A Srivastava ◽  
...  
Keyword(s):  
Chemical Analysis ◽  
Mercury Speciation
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