scholarly journals Characteristics of Low-Oxygen Oxidation Ditch with Improved Nitrogen Removal

Water ◽  
2021 ◽  
Vol 13 (24) ◽  
pp. 3603
Author(s):  
Elena Gogina ◽  
Igor Gulshin

This article presents a study on the operational stability of laboratory oxidation ditches, designated for synthetic and real wastewater and operable at low concentrations of dissolved oxygen. The project encompassed the stability monitoring of activated sludge depending on sedimentation characteristics and hydrobiological indicator microorganisms, determining (1) the size of sludge floccules and (2) the main functional groups of microorganisms identified in the course of the PCR analysis and reaction rates, plotted using the Michaelis–Menten enzymatic kinetics for the mixed culture biomass. The most stable system involves a bioreactor featuring dissolved oxygen gradients that range from 1.9 to 0.15 mg/L s, a specific organic load of 0.21 gBOD/g/d and a hydraulic retention time of 12 h. A built-in settling tank allows the consideration of the potential generation of large floccules of activated sludge in oxidation ditches (at least 300 μm) that increase the efficiency of simultaneous nitrification and denitrification. Thus, the obtained reaction rates can be used in calculations and simulations of the operation of oxidation ditches at low concentrations of dissolved oxygen.

2014 ◽  
Vol 9 (4) ◽  
pp. 551-557
Author(s):  
Y. V. Mikhailova ◽  
M. V. Kevbrina ◽  
V. A. Grachev ◽  
Y. A. Nikolaev ◽  
V. G. Aseeva

Low content of ammonia in the treated water is one of the most important indicators of the efficiency of biological wastewater treatment. Oxidation of ammonium to nitrate (nitrification) is carried out by nitrifying bacteria, which have low growth rates and are very sensible to certain unfavorable technological factors, such as low oxygen concentration and toxicants). To stabilize the number of nitrifying bacteria, increasing their activity in bioreactors with activated sludge and, therefore, to achieve stable and efficient removal of nitrogen compounds, various techniques are used, one of which is bioaugmentation technology. Bioaugmentation implies addition of the necessary microorganisms or creation of the conditions favoring their development in order to increase the specific activity of biological systems, such as activated sludge. In the Engineering and Technological Centre of JSC ‘Mosvodokanal’ for the first time in world practice, we studied the efficiency of nitrification in a plant operating under the scheme of the University of Cape Town process, in combination with an additional bioaugmentation reactor. Activated sludge in the reactor was enriched with nitrifying bacteria. At higher ammonium loads, which were modeled by adding the liquid phase of digested sludge, the main line did not remove ammonium to the maximum permissible concentration for fishery water bodies. The use of a bioaugmentation reactor resulted in ammonium concentration decrease from 40–50 to 0.4 mg N-NH4/l. This approach increased the stability of the activated sludge nitrifying bacteria to toxicants (thiourea).


1994 ◽  
Vol 30 (6) ◽  
pp. 91-100 ◽  
Author(s):  
Ewa Lie ◽  
Thomas Welander

The influence of low concentrations of dissolved oxygen (DO) and the oxidation-reduction potential (ORP) on the denitrification activity of activated sludge has been studied in batchwise experiments. The ORP was maintained at different levels by automatic titration with air and the denitrification activity was determined by following the disappearance of nitrate. Oxygen was found to have a negative effect on denitrification even at lower concentrations than can be measured with conventional oxygen probes (<0.1 mg/L). The ORP was found to be a useful indicator of the DO concentration at this low level and the denitrification rate was found to decrease linearly with increasing ORP. However, the effect of the ORP on denitrification differed between sludges from different treatment plants. A linear relationship was also found between the ORP and the DO concentration in the region of measurable DO concentrations. Extrapolation of this straight line into the region where DO was under the detection limit indicated that oxygen exerts an inhibitory effect on denitrification at such low concentrations as a few μg/L.


1977 ◽  
Vol 16 (04) ◽  
pp. 157-162 ◽  
Author(s):  
C. Schümichen ◽  
B. Mackenbrock ◽  
G. Hoffmann

SummaryThe bone-seeking 99mTc-Sn-pyrophosphate compound (compound A) was diluted both in vitro and in vivo and proved to be unstable both in vitro and in vivo. However, stability was much better in vivo than in vitro and thus the in vitro stability of compound A after dilution in various mediums could be followed up by a consecutive evaluation of the in vivo distribution in the rat. After dilution in neutral normal saline compound A is metastable and after a short half-life it is transformed into the other 99mTc-Sn-pyrophosphate compound A is metastable and after a short half-life in bone but in the kidneys. After dilution in normal saline of low pH and in buffering solutions the stability of compound A is increased. In human plasma compound A is relatively stable but not in plasma water. When compound B is formed in a buffering solution, uptake in the kidneys and excretion in urine is lowered and blood concentration increased.It is assumed that the association of protons to compound A will increase its stability at low concentrations while that to compound B will lead to a strong protein bond in plasma. It is concluded that compound A will not be stable in vivo because of a lack of stability in the extravascular space, and that the protein bond in plasma will be a measure of its in vivo stability.


2008 ◽  
Vol 3 (1) ◽  
Author(s):  
Young H. Yoon ◽  
Jae R. Park ◽  
Sang W. Ahn ◽  
Kwang B. Ko ◽  
Kyung J. Min ◽  
...  

Hybrid Activated Sludge Process (HASP) with IMET was developed and applied to an activated sludge process for the advanced nutrient treatment in Korea. The characteristics of nitrogen removal from the HASP were investigated through a kinetic study by batch-type experiment. Online DB analysis produced from the IMET was conducted for the nutrient removal performance in the field demonstration plant treating 10,000 m3/day in G city of Korea. In this paper, we aimed to determine the effect of increasing NHM4+-N load on the specific nitrification rate (SNR) and the specific denitrification rate (SDNR) through a batch-type experiment, and to estimate the net reaction time for the phase-transfer rate using online DB analysis in the HASP operation. Experimental results include: (1) both the nitrification and denitrification followed first-order kinetics; (2) the maximum SNR and SDNR were 4.0301 mgN/gVSS·hr and 2.785 mgN/gVSS·hr, respectively; (3) comparison of reaction rates between nitrification and denitrification from the non-linear regression analysis found that nitrification rate was higher than denitrification.


1977 ◽  
Vol 12 (1) ◽  
pp. 191-212
Author(s):  
B. Volesky ◽  
Q. Samak ◽  
P. Waller

Abstract Review of the available results appearing in the recent literature is presented focusing particularly upon the effects of metallic ions such as Cr, Cu, Zn, Cd, Hg, V, Zn, Ni and Co. Some original data involving the effects of Na are presented and discussed. Development of parameters used in evaluating the influence of toxic or inhibitory species on the mixed microbial population of an activated sludge system is of crucial importance and different techniques employed such as BOD-COD-TOC-removal rates, Oxygen Uptake Rate, and others are discussed, showing relative inadequacy of currently applied assays. From the data available, certain trends can be discerned. There is a definite threshold concentration for each metallic ion, depending on the organic load of the feed. In the order of increasing toxicity to activated sludge systems reflected in lower BOD removals the following metals have been listed as inhibiting factors at concentrations starting from 1 ppm applied on a continuous basis: hexavalent chromium, cobalt, zinc, cadmium, trivalent chromium, copper and nickel. Metals in combination have not been reported to exhibit any significantly different effects as compared to those observed with individually introduced metallic ions. Tolerance of some activated sludge systems to shock loadings by various inorganic ions and metals is reviewed. The conclusions are of particular importance for estimating the performance of biox systems handling industrial effluents which are likely to contain toxic components of inorganic or metallic nature.


1980 ◽  
Vol 15 (1) ◽  
pp. 73-82 ◽  
Author(s):  
J.G. Henry ◽  
E.E. Salenieks

Abstract This study examined the effect of temperature on the settleabi1ity of activated sludge at various organic loading rates. Five completely mixed, bench-scale, activated sludge plants, operating under similar conditions at 5, 10 and 19°C, were continuously fed diluted, settled sewage supplemented with carbohydrate (sucrose). Hydraulic loading rates, MLSS and pH were maintained at constant levels during the experiments to eliminate these factors are variables. Dissolved oxygen was kept in excess of 3 mg/1 so that it would not be a limiting factor. Sludge Volume Indices (SVI ) and zone settling velocities were used to indicate changes in sludge settleability. Microscopic examination of the activated sludge indicated significant differences in the morphological features of filamentous microorganisms present at the two temperature extremes. At 19°C, the predominant forms were characterized by long curving trichomes, occasionally falsely branching, containing short cylindrical cells. At 5 °C, much smaller straight filaments, composed of long, narrow, rod-shaped cells appeared to be the principal microorganisms responsible for bulking. Various other filamentous forms were always present at each of the temperatures studied. Stirred sludge settling tests of moderately bulking sludges generally exhibited much higher settling velocities and lower SVI's than unstirred bulking samples. However, extremely filamentous bulking sludge exhibited comparable stirred and unstirred settling velocity and SVI values. The standard SVI test was found to be an inadequate indicator of the extent of bulking when trying to correlate the SVI failures from bench-scale performance with the results from continuous units. Lower temperature had no appreciable effect on COD removal efficiency as long as bulking did not cause a loss of solids in the effluent. However, results suggested that less than half the organic load could be accepted at 5°C, that could be handled at 19°C, before filamentous bulking occurred. A plot of loading versus temperature for various SVI's provided a visual indication of the safe loading limit below which bulking was unlikely to occur. The study clearly demonstrated that temperature can have a significant effect on sludge settleability.


1991 ◽  
Vol 23 (7-9) ◽  
pp. 1503-1507 ◽  
Author(s):  
L. M. Triet ◽  
N. T. Viet ◽  
T. V. Thinh ◽  
H. D. Cuong ◽  
J. C. L. van Buuren

The effluent from activated sludge treatment of petroleum wastewater was treated with the aid of a ponding system using aquatic plants (Water Hyacinth, Chlorella, Reed). A good result was obtained in this study. Pilot pond system shows that the purification efficiency depends on the residence time of about 14 days. The petroleum removal waa 97-98 %, the COD removal was from 88-93 %. The dissolved oxygen amount (with Chlorella) increased from 0.7 mg/l to 9.8 mg/l and the pH increased from 6.9 to 8-8.6. The application of 3 step biological pond with the use of Water Hyacinth, Chlorella, Reeds for post treatment of petroleum wastewater is appropriate in Vietnam.


1996 ◽  
Vol 33 (3) ◽  
pp. 185-194 ◽  
Author(s):  
M. Sarioglu ◽  
N. Horan

Anoxic zones are designed for the removal of nitrogen in nitrifying activated sludge plants. This can be carried out either to achieve a nitrogen discharge consent or to eliminate the problem of rising sludges. The rising sludge problem is mostly encountered in medium and small size plants in warm conditions and there is limited information as to the appropriate design of anoxic zones to protect against rising sludges in the secondary sedimentation tanks. Therefore a series of batch experiments were undertaken in order to establish the critical concentration of nitrate-nitrogen which causes rising sludge in the secondary settling tank and the effect of environmental factors such as temperature (15°C to 30°C) and residual carbon source (100 to 600 mg/1 COD) were examined. Based on the results of these experiments an empirical equation was presented which can be used to size an anoxic zone to eliminate rising sludges. The application of this equation at full-scale plants is discussed.


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