scholarly journals Benthic Metabolism in Fluvial Sediments with Larvae of Lampetra sp

Water ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1002
Author(s):  
Nerijus Nika ◽  
Mindaugas Zilius ◽  
Tomas Ruginis ◽  
Gianmarco Giordani ◽  
Kasparas Bagdonas ◽  
...  
Keyword(s):  
Nitrate Uptake ◽  
Fine Sand ◽  
Fluvial Sediments ◽  
Major Fraction ◽  
Benthic Metabolism ◽  
Size Dependent ◽  
Benthic Pelagic Coupling ◽  
Reactive Phosphorus ◽  
Excretion Rates

Lampreys spend their larval stage within fine sand fluvial sediments, where they burrow and act as filter feeders. Lamprey larvae (ammocoetes) can significantly affect benthic-pelagic coupling and nutrient cycling in rivers, due to high densities. However, their bioturbation, feeding and excretion activities are still poorly explored. These aspects were investigated by means of laboratory incubations of intact sediments added with ammocoetes and of animals alone. Oxygen respiration, nutrient fluxes and excretion rates were determined. Individual ammocoete incubations suggested that biomass-specific oxygen consumption and ammonium, reactive phosphorus and silica excretion were size-dependent, and greater in small compared to large individuals. The comparison of ammocoetes metabolic rates with rates measured in intact sediments revealed that ammocoetes activity decreases significantly when they are burrowed in sediments. Furthermore, results suggest that a major fraction of ammonium excreted by ammocoetes was assimilated by benthic microbes or microalgae to overcome in situ N-limitation. Alternatively, part of the excreted ammonium was oxidized and denitrified within sediments, as nitrate uptake rather increased along with ammocoetes density. Ammocoetes excreted reactive phosphorus and silica but such production was not apparent in bioturbated sediments, likely due to microbial or microalgal uptake or to immobilization in sediments.

Size dependent behavior of Fe3O4crystals during electrochemical (de)lithiation: an in situ X-ray diffraction, ex situ X-ray absorption spectroscopy, transmission electron microscopy and theoretical investigation

2017 ◽  
Vol 19 (31) ◽  
pp. 20867-20880 ◽  
Author(s):  
David C. Bock ◽  
Christopher J. Pelliccione ◽  
Wei Zhang ◽  
Janis Timoshenko ◽  
K. W. Knehr ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Structural Changes ◽  
Ex Situ ◽  
X Ray Diffraction ◽  
X Ray ◽  
Size Dependent ◽  
Transmission Electron ◽  
Dependent Behavior ◽  
X Ray Absorption

Crystal and atomic structural changes of Fe3O4upon electrochemical (de)lithiation were determined.

scholarly journals Effect of incubation time and substrate concentration on N-uptake rates by phytoplankton in the Bay of Bengal

2005 ◽  
Vol 2 (5) ◽  
pp. 1331-1352
Author(s):  
S. Kumar ◽  
R. Ramesh ◽  
S. Sardesai ◽  
M. S. Sheshshayee
Keyword(s):  
Incubation Time ◽  
Uptake Rate ◽  
Nitrate Uptake ◽  
N Uptake ◽  
Marine Phytoplankton ◽  
Total Production ◽  
New Production ◽  
Urea Uptake ◽  
Uptake Rates

Abstract. We report here the results of three experiments, which are slight variations of the 15N method (JGOFS protocol) for determination of new production. The first two test the effect of (i) duration of incubation time and (ii) concentration of tracer added on the uptake rates of various N-species (nitrate, ammonium and urea) by marine phytoplankton; while the third compares in situ and deck incubations from dawn to dusk. Results indicate that nitrate uptake can be underestimated by experiments where incubation times shorter than 4h or when more than 10% of the ambient concentration of nitrate is added prior to incubation. The f-ratio increases from 0.28 to 0.42 when the incubation time increases from two to four hours. This may be due to the observed increase in the uptake rate of nitrate and decrease in the urea uptake rate. Unlike ammonium [y{=}2.07x{-}0.002\\, (r2=0.55)] and urea uptakes [y{=}1.88x{+}0.004 (r2=0.88)], the nitrate uptake decreases as the concentration of the substrate (x) increases, showing a negative correlation [y{=}-0.76x+0.05 (r2=0.86)], possibly due to production of glutamine, which might suppress nitrate uptake. This leads to decline in the f-ratio from 0.47 to 0.10, when concentration of tracer varies from 0.01 to 0.04μ M. The column integrated total productions are 519 mg C m-2 d-1 and 251 mg C m-2 d-1 for in situ and deck incubations, respectively. The 14C based production at the same location is ~200 mg C m-2 d-1, which is in closer agreement to the 15N based total production measured by deck incubation.

scholarly journals Live-Scale Testing of Granular Materials Stabilized with Alkali-Activated Waste Glass and Carbide Lime

2021 ◽  
Vol 11 (23) ◽  
pp. 11286
Author(s):  
Marina Paula Secco ◽  
Débora Thaís Mesavilla ◽  
Márcio Felipe Floss ◽  
Nilo Cesar Consoli ◽  
Tiago Miranda ◽  
...  
Keyword(s):  
Portland Cement ◽  
Mechanical Performance ◽  
Raw Materials ◽  
Sodium Hydroxide Solution ◽  
Fine Sand ◽  
Field Application ◽  
Natural Soil ◽  
In Situ Tests ◽  
Alkali Activated

The increasingly strong search for alternative materials to Portland cement has resulted in the development of alkali-activated cements (AAC) that are very effective at using industrial by-products as raw materials, which also contributes to the volume reduction in landfilled waste. Several studies targeting the development of AAC—based on wastes containing silicon and calcium—for chemical stabilization of soils have demonstrated their excellent performance in terms of durability and mechanical performance. However, most of these studies are confined to a laboratory characterization, ignoring the influence and viability of the in situ construction process and, also important, of the in situ curing conditions. The present work investigated the field application of an AAC based on carbide lime and glass wastes to stabilize fine sand acting as a superficial foundation. The assessment was supported on the unconfined compressive strength (UCS) and initial shear modulus (G0) of the developed material, and the field results were compared with those prepared in the laboratory, up to 120 days curing. In situ tests were also developed on the field layers (with diameters of 450 and 900 mm and thickness of 300 mm) after different curing times. To establish a reference, the mentioned precursors were either activated with a sodium hydroxide solution or hydrated with water (given the reactivity of the lime). The results showed that the AAC-based mixtures developed greater strength and stiffness at a faster rate than the water-based mixtures. Specimens cured under controlled laboratory conditions showed better results than the samples collected in the field. The inclusion of the stabilized layers clearly increased the load-bearing capacity of the natural soil, while the different diameters produced different failure mechanisms, similar to those found in Portland cement stabilization.

scholarly journals Unraveling the Guest-Induced Switchability in the Metal-Organic Framework DUT-13(Zn)

2021 ◽  
Author(s):  
Bodo Felsner ◽  
Volodymyr Bon ◽  
Jack D. Evans ◽  
Friedrich Schwotzer ◽  
Ronny Grünker ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Conformational Isomerism ◽  
Hysteresis Width ◽  
Size Dependent ◽  
Semiempirical Approach ◽  
Contraction Mechanism ◽  
Metal Organic ◽  
Wide Hysteresis ◽  
Breathing Mechanism

A guest-induced flexibility in the framework DUT-13 was investigated in situ to analyze the breathing mechanism upon physisorption of nitrogen (77 K) and n-butane (273 K). The crystal structure of cp phase, solved from PXRD data using the computation-assisted semiempirical approach, shows two times smaller pore volume, compared to the op phase, which is consistent with the corresponding isotherms. The contraction mechanism is mainly based on the conformational isomerism of the benztb4- linker, which transforms from a staggered conformation in op phase to a more eclipsed in cp phase, leading to the contraction of the larger pore. A nearly complete op → cp → op transition was observed in the case of n-butane adsorption at 273 K, while in case of weakly interacting nitrogen molecules a portion of the sample remains in the op phase in the entire pressure range. Apparently, in case of DUT-13 the contraction is crystallite size-dependent, similarly as in a number of other switchable MOFs, which should be investigated more in detail in the future. Methane adsorption at varying temperatures showed a wide hysteresis at the temperatures between 111 K and 140 K. The hysteresis width decreases until it disappears completely at 170 K leading to a reversible isotherm, typical for rigid frameworks. The fact that breathing is observed in a broader temperature range in comparison to DUT‑49 demonstrates that thermodynamics and kinetics favour the DUT-13 contraction. Linker and hinges in DUT-13 are not stiff enough to support the metastable states required for NGA.

scholarly journals Caracterização de parâmetros hidráulicos em depósitos fluviais paleogênicos na Bacia de Volta Redonda, RJ

2007 ◽  
Vol 30 (2) ◽  
pp. 118-132
Author(s):  
Ana Carolina Lisbôa Barboza ◽  
Gerson Cardoso da Silva Jr ◽  
Claudio Limeira Mello
Keyword(s):  
Hydraulic Conductivity ◽  
Sedimentary Facies ◽  
Fine Sand ◽  
Sedimentary Deposits ◽  
Hydrogeological Parameters ◽  
Variable Head ◽  
Medium Reservoir ◽  
Maximum Permeability

The present study aims for the characterization of the hydrogeological parameters of the Paleogenic fluvial deposits of Volta Redonda Geological Basin, through hydraulic conductivity determinations and grain sized analyses. The overall goal was to produce a hydrogeological data base applicable to the characterization of hydrofacies (interconnected sedimentary bodies with distinct hydraulic properties) and the modeling groundwater flow. The used methods used consisted of in situ permeability determinations (Guelph permeameters) and laboratory tests (variable head permeameter), besides grain size analyses carried out in each sedimentary facies in the study area. These sedimentary facies were characterized by Marques (2006) and belong to the Resende and Pinheiral formations. The permeameter results were coherent to the sedimentological characteristics. The Resende Formation sedimentary deposits are constituted by medium to fine sand with presence of argillaceous matrix and present moderate to very low hydraulic conductivity, varying between 10-4 to 10-8 cm/s, which indicates a poor reservoir. The Pinheiral Formation presents sandy layers with conglomeratic lenses, limited by small thickness pelitic intervals, with a very low permeability, with a hydraulic conductivity varying between 10-5 to 10-7 cm/s. The upper layer has the maximum permeability, around 10-3 cm/s. This formation presents a medium reservoir characteristics and it must be taken into consideration that the upper layer has as role in recharge to the aquifer. From the results of hydraulic conductivity, that varies from 10-8 to 10-3 cm/s for the Resende and Pinheiral formations, it is concluded that these deposits a low to medium hydraulic conductivity, explaining the low productivity of the water-bearing multilayered aquifer of Volta Redonda Basin.

In situ multiphase fluidization ("upflow washing") for the remediation of hydrocarbon contaminated sands

1998 ◽  
Vol 35 (6) ◽  
pp. 938-960 ◽  
Author(s):  
Robert K Niven ◽  
Nasser Khalili
Keyword(s):  
Theoretical Analysis ◽  
Contaminated Soils ◽  
Fixed Bed ◽  
Fine Sand ◽  
In Situ Remediation ◽  
Pump And Treat ◽  
Wide Range ◽  
Phase Liquid ◽  
Regime Map

A new in situ remediation method is described, "upflow washing," in which contaminants are flushed to the surface within an in situ fluidized zone produced by a jet inserted into a granular formation. The suitability of the method for LNAPL (light non-aqueous phase liquid) remediation is examined by experiments on diesel-contaminated soils within column and tank settings. The experiments indicate significant reductions in diesel levels (96-99.9%) may be achieved by fluidization with water and gas (gas-liquid upflow washing, GLUW) for a wide range of initial diesel concentrations (10 000 to 150 000 mg/kg) and for soil fines contents of 0 to at least 10%. Final diesel levels of <1000 mg/kg in a uniform fine sand and <200 mg/kg in clayey sands can be achieved. The efficiency is much higher than that of fixed bed flushing (simulated pump-and-treat), as the method overcomes the trapping of NAPL ganglia. Fludization with water alone (liquid upflow washing, LUW) is less effective than fixed bed flushing in the uniform sand, but approaches that of GLUW in clayey and silty sands. The results are explained by theoretical analysis of the removability of isolated NAPL droplets and mixed solid - NAPL particles from a fluidized bed due to buoyancy and elutriation, which may be represented using a "removability regime map" for the diesel-water-sand system.Key words: fluidization, in situ, remediation, NAPL, diesel.

scholarly journals Benthic nutrient fluxes and sediment oxygen consumption in a full-scale facultative pond in Patagonia, Argentina

2013 ◽  
Vol 68 (8) ◽  
pp. 1770-1777 ◽  
Author(s):  
M. Faleschini ◽  
J. L. Esteves
Keyword(s):  
Oxygen Consumption ◽  
Advanced Degree ◽  
Benthic Fluxes ◽  
Temperate Region ◽  
Benthic Metabolism ◽  
Mineralization Of Organic Matter ◽  
A Site ◽  
Water Bottom ◽  
Raw Wastewater

The study of benthic metabolism is an interesting tool to understand the process that occurs in bottom water at wastewater stabilization ponds. Here, rates of benthic oxygen consumption and nutrient exchange across the water–sludge interface were measured in situ using a benthic chamber. The research was carried out during autumn, winter, and summer at a municipal facultative stabilization pond working in a temperate region (Puerto Madryn city, Argentina). Both a site near the raw wastewater inlet (Inlet station) and a site near the outlet (Outlet station) were sampled. Important seasonal and spatial patterns were identified as being related to benthic fluxes. Ammonium release ranged from undetectable (autumn/summer – Inlet station) to +30.7 kg-NH4+ ha−1 d−1 (autumn – Outlet station), denitrification ranged from undetectable (winter – in both sites) to −4.0 kg-NO3− ha−1 d−1 (autumn – Outlet station), and oxygen consumption ranged from 0.07 kg-O2ha−1 d−1 (autumn/summer – Outlet station) to 0.84 kg-O2ha−1 d−1 (autumn – Inlet station). During the warmer months, the mineralization of organic matter from the bottom pond acts as a source of nutrients, which seem to support the important development of phytoplankton and nitrification activity recorded in the surface water. Bottom processes could be related to the advanced degree and efficiency of the treatment, the temperature, and probably the strong and frequent wind present in the region.

Plant Taphonomy and Paleoecology of Late Pennsylvanian Intramontane Wetlands in the Graissessac-Lodève Basin (Languedoc, France)

Palaios ◽  
2005 ◽  
Vol 20 (3) ◽  
pp. 249-265 ◽  
Author(s):  
CARLES MARTÍN-CLOSAS ◽  
JEAN GALTIER
Keyword(s):  
Detailed Comparison ◽  
Alluvial Fans ◽  
Fluvial Sediments ◽  
Tree Fern ◽  
Massif Central ◽  
Fine Grained ◽  
Tree Ferns ◽  
First Time ◽  
Diverse Plant

Abstract The Late Pennsylvanian Graissessac-Lodève basin is a small, fluvio-palustrine depocenter located in the southern part of the Massif Central (France). A taphonomic and sedimentologic study carried out in this area allows a reconstruction of Late Carboniferous vegetation in an intramontane context. The paleoecology of such limnic settings is poorly known, and this study permits detailed comparison with paralic basins for the first time. The Graissessac peat mires developed in abandoned fluvial channels, in floodplains, and above distal alluvial fans. The vegetation was dominated by monospecific stands of the arborescent lycopsid Sigillaria brardii, whereas the tree fern Psaronius occurred during the later stages of mire accretion. This is in contrast to coeval North American peat mires, which generally were dominated by tree ferns and pteridosperms throughout the mire profile. Stephanian floodplains and distal alluvial fans of the Graissessac-Lodève Basin were devoid of vegetation, with the exception of isolated thickets of sphenopsids that were composed of Calamites and Sphenophyllum. These plants were found growing in situ in the floodplain mudstones as well as in fine-grained sands of secondary channels. Parautochthonous foliage assemblages of ferns and pteridosperms found in floodplain mudstones represent the most diverse plant community. The plants supplying these remains were growing in exposed areas close to floodplains. Large logs attributed to cordaitaleans and monotypic assemblages of large Cordaites leaves were found in fluvial sediments, and suggest that the plants were riparian elements in the basin.

scholarly journals Size-dependent stability of iron oxide evaluated through in-situ heating experiments

2017 ◽  
Vol 23 (S1) ◽  
pp. 1718-1719 ◽  
Author(s):  
Cecile Bonifacio Fittz ◽  
Hasti Majidi ◽  
Klaus van Benthem
Keyword(s):  
Iron Oxide ◽  
Size Dependent ◽  
In Situ Heating

Weathering and soil formation on dolerite in Tasmania with particular reference to several trace elements

Soil Research ◽  
1963 ◽  
Vol 1 (1) ◽  
pp. 74 ◽  
Author(s):  
KG Tiller
Keyword(s):  
Trace Elements ◽  
Soil Formation ◽  
Fine Sand ◽  
Climatic Conditions ◽  
Parent Material ◽  
Soil Profiles ◽  
Podzolic Soils ◽  
Nickel Copper ◽  
Soil Groups

The mineralogy and chemistry of weathering and soil formation have been studied at 17 widely separated sites with contrasting climatic conditions on comparatively uniform dolerite in Tasmania. The clay and fine sand mineralogy of the soils has been related to their degree of weathering. These studies have shown large chemical and mineralogical changes accompanying the initial stages of weathering in some krasnozem soils. The reorganization of cobalt, zirconium, nickel, copper, molybdenum, manganese, and zinc during genesis of four soil groups has been considered in terms of the factors involved. Some of these results indicate that the clay horizon of the podzolic soils has probably been formed by weathering in situ. Seasonal waterlogging in certain horizons has strongly mfluenced the chemistry and mineralogy of weathering in many of these soils. This study has shown that the composition of the parent material has only influenced the geochemistry of trace elements in less weathered soils and that pedogenic factors assumed greater significance as the soils became more strongly weathered. Geomorphic processes had a marked influence on the geochemistry of some soils by the truncation of mature soil profiles.

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