scholarly journals BTX Removal from Open Aqueous Systems by Modified Cellulose Fibers and Evaluation of Competitive Evaporation Kinetics

Water ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 3154
Author(s):  
Antonio Tursi ◽  
Francesco Chidichimo ◽  
Rita Bagetta ◽  
Amerigo Beneduci
Keyword(s):  
Organic Compounds ◽  
Low Cost ◽  
Water System ◽  
Open Water ◽  
Cellulose Fibers ◽  
Petroleum Products ◽  
Pollutant Concentrations ◽  
Surface Modified ◽  
Adsorption Desorption ◽  
Modified Cellulose

BTX stands for Benzene, Toluene, and Xylenes, which are volatile organic compounds contained in petroleum products such as gasoline. They have negative health effects and are sadly known for soil, air, and water contamination. This paper provides an investigation on BTX removal from open water systems like those represented by natural water bodies. In such systems, the evaporation process takes place, stealing the pollutants from the aqueous matrix by transferring them into the air, resulting in a secondary pollution. To prevent this situation, adsorption of these organic compounds on cellulose fibers, extracted from Spanish Broom vegetable, was studied. Raw and surface modified cellulose fibers were used for this purpose. The second ones were hydrophobized by two different green and low-cost functionalization systems (no solvent urethane functionalization and low pressure plasma treatments). Batch experiments were performed in an open system where BTX underwent two competing removing mechanisms: volatilization, and adsorption/desorption on/from the fibers dispersed in the water system. A mathematical model was implemented for the interpretation of the observed time-varying pollutant concentrations and the estimation of the kinetic constants for adsorption, desorption, and evaporation. The developed model, provided with the aforementioned parameters calibrated for each type of fibers, was then used for the prediction of their adsorption capacities both into open and closed systems.

Copper(I)oxide surface modified cellulose fibers—Synthesis, characterization and antimicrobial properties

2014 ◽  
Vol 254 ◽  
pp. 344-351 ◽  
Author(s):  
Hossam E. Emam ◽  
Avinash P. Manian ◽  
Barbora Široká ◽  
Heinz Duelli ◽  
Petra Merschak ◽  
...  
Keyword(s):  
Antimicrobial Properties ◽  
Cellulose Fibers ◽  
Oxide Surface ◽  
Surface Modified ◽  
Modified Cellulose

To the issue of water treatment by hydrocyclone on the systems of the combined irrigation

2020 ◽  
Vol 0 (2) ◽  
pp. 21-25
Author(s):  
Nikolay Dubenok ◽  
Andrey Novikov ◽  
Sergei Borodychev ◽  
Maria Lamskova
Keyword(s):  
Water Treatment ◽  
Organic Compounds ◽  
Irrigation Water ◽  
Irrigation System ◽  
Petroleum Products ◽  
Cylindrical Part ◽  
Agricultural Landscapes ◽  
Treatment Unit ◽  
Drain Pipe ◽  
Irrigation Network

At the stage of water treatment for irrigation systems, the efficiency capture coarse and fine mechanical impurities, as well as oil products and organic compounds affects the reliability of the equipment of the irrigation network and the safety of energy exchange processes in irrigated agricultural landscapes. The violation of work irrigation system can cause disruptions in irrigation schedules of agricultural crops, crop shortages, degradation phenomena on the soil and ecological tension. For the combined irrigation system, a water treatment unit has been developed, representing a hydrocyclone apparatus with a pipe filter in the case. For the capacity of 250 m3/h the main geometrical dimensions of hydrocyclone have been calculated. To organize the capture petroleum products and organic compounds, it has been proposed a modernization of a hydrocyclone unit, consisting in dividing the cylindrical part of the apparatus into two section. The first is section is for input irrigation water, the second one is for additional drainage of clarified irrigation water after sorption purification by the filter, placed on the disk and installed coaxially with the drain pipe and the pipe filter.

scholarly journals α-Cellulose Fibers of Paper-Waste Origin Surface-Modified with Fe3O4 and Thiolated-Chitosan for Efficacious Immobilization of Laccase

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 581
Author(s):  
Gajanan S. Ghodake ◽  
Surendra K. Shinde ◽  
Ganesh D. Saratale ◽  
Rijuta G. Saratale ◽  
Min Kim ◽  
...  
Keyword(s):  
Enzyme Immobilization ◽  
Photoelectron Spectroscopy ◽  
Cellulose Fibers ◽  
Relative Activity ◽  
Significant Activity ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Laccase Immobilization ◽  
Surface Modified

The utilization of waste-paper-biomass for extraction of important α-cellulose biopolymer, and modification of extracted α-cellulose for application in enzyme immobilization can be extremely vital for green circular bio-economy. Thus, in this study, α-cellulose fibers were super-magnetized (Fe3O4), grafted with chitosan (CTNs), and thiol (-SH) modified for laccase immobilization. The developed material was characterized by high-resolution transmission electron microscopy (HR-TEM), HR-TEM energy dispersive X-ray spectroscopy (HR-TEM-EDS), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared spectroscopy (FT-IR) analyses. Laccase immobilized on α-Cellulose-Fe3O4-CTNs (α-Cellulose-Fe3O4-CTNs-Laccase) gave significant activity recovery (99.16%) and laccase loading potential (169.36 mg/g). The α-Cellulose-Fe3O4-CTNs-Laccase displayed excellent stabilities for temperature, pH, and storage time. The α-Cellulose-Fe3O4-CTNs-Laccase applied in repeated cycles shown remarkable consistency of activity retention for 10 cycles. After the 10th cycle, α-Cellulose-Fe3O4-CTNs possessed 80.65% relative activity. Furthermore, α-Cellulose-Fe3O4-CTNs-Laccase shown excellent degradation of pharmaceutical contaminant sulfamethoxazole (SMX). The SMX degradation by α-Cellulose-Fe3O4-CTNs-Laccase was found optimum at incubation time (20 h), pH (3), temperatures (30 °C), and shaking conditions (200 rpm). Finally, α-Cellulose-Fe3O4-CTNs-Laccase gave repeated degradation of SMX. Thus, this study presents a novel, waste-derived, highly capable, and super-magnetic nanocomposite for enzyme immobilization applications.

Octadecylamine as chemical modifier for tuned hydrophobicity of surface modified cellulose: toward organophilic cellulose nanocrystals

Cellulose ◽  
2021 ◽  
Author(s):  
Mohammed Majdoub ◽  
Younes Essamlali ◽  
Othmane Amadine ◽  
Ikram Ganetri ◽  
Anass Hafnaoui ◽  
...  
Keyword(s):  
Cellulose Nanocrystals ◽  
Chemical Modifier ◽  
Surface Modified ◽  
Modified Cellulose

Anthraquinone-Decorated Graphene Hydrogel based on Carbonized Cotton Fiber for Flexible and High Performance Supercapacitors

2021 ◽  
Author(s):  
Mengying Jia ◽  
Yue Li ◽  
Linlin Cui ◽  
Yingrui An ◽  
Canping Pan ◽  
...  
Keyword(s):  
Cotton Fiber ◽  
High Performance ◽  
Low Cost ◽  
Cellulose Fibers

Recently, wood-derived electrochemical materials like cellulose fibers have attracted increased attention as they have unique characteristics, such as low cost, lightweight, earth-abundance, flexible and sustainable. Here, based on carbonized cotton...

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