scholarly journals Urban Groundwater Processes and Anthropogenic Interactions (Porto Region, NW Portugal)

Water ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2797
Author(s):  
Maria José Afonso ◽  
Liliana Freitas ◽  
José Manuel Marques ◽  
Paula M. Carreira ◽  
Alcides J.S.C. Pereira ◽  
...  
Keyword(s):  
Urban Groundwater ◽  
Urban Region ◽  
Flow Paths ◽  
Isotopic Signatures ◽  
Mainland Portugal ◽  
Potential Index ◽  
Groundwater Systems ◽  
Human Wastes ◽  
Groundwater Infiltration

Groundwater in fissured rocks is one of the most important reserves of available fresh water, and urbanization applies an extremely complex pressure which puts this natural resource at risk. Two-thirds of Portugal is composed of fissured aquifers. In this context, the Porto urban region is the second biggest metropolitan area in mainland Portugal. In this study, a multidisciplinary approach was developed, using hydrogeological GIS-based mapping and modeling, combining hydrogeochemical, isotopic, and hydrodynamical data. In addition, an urban infiltration potential index (IPI-Urban) was outlined with the combination of several thematic layers. Hydrogeochemical signatures are mainly Cl-Na to Cl-SO4-Na, being dependent on the geographic proximity of this region to the ocean, and on anthropogenic and agricultural contamination processes, namely fertilizers, sewage, as well as animal and human wastes. Isotopic signatures characterize a meteoric origin for groundwater, with shallow flow paths and short residence times. Pumping tests revealed a semi- to confined system, with low long-term well capacities (<1 L/s), low transmissivities (<4 m2/day), and low storage coefficients (<10−2). The IPI-Urban index showed a low groundwater infiltration potential, which was enhanced by urban hydraulic and sanitation features. This study assessed the major hydrogeological processes and their dynamics, therefore, contributing to a better knowledge of sustainable urban groundwater systems in fractured media.

scholarly journals Semi-Analytical Solution to Assess CO2 Leakage in the Subsurface through Abandoned Wells

Energies ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2452
Author(s):  
Tian Qiao ◽  
Hussein Hoteit ◽  
Marwan Fahs
Keyword(s):  
Analytical Solution ◽  
Storage Site ◽  
Co2 Leakage ◽  
Transient Pressure ◽  
Flow Paths ◽  
Abandoned Wells ◽  
Diffusivity Equation ◽  
Carbon Dioxide Co2 ◽  
Good Agreement

Geological carbon storage is an effective method capable of reducing carbon dioxide (CO2) emissions at significant scales. Subsurface reservoirs with sealing caprocks can provide long-term containment for the injected fluid. Nevertheless, CO2 leakage is a major concern. The presence of abandoned wells penetrating the reservoir caprock may cause leakage flow-paths for CO2 to the overburden. Assessment of time-varying leaky wells is a need. In this paper, we propose a new semi-analytical approach based on pressure-transient analysis to model the behavior of CO2 leakage and corresponding pressure distribution within the storage site and the overburden. Current methods assume instantaneous leakage of CO2 occurring with injection, which is not realistic. In this work, we employ the superposition in time and space to solve the diffusivity equation in 2D radial flow to approximate the transient pressure in the reservoirs. Fluid and rock compressibilities are taken into consideration, which allow calculating the breakthrough time and the leakage rate of CO2 to the overburden accurately. We use numerical simulations to verify the proposed time-dependent semi-analytical solution. The results show good agreement in both pressure and leakage rates. Sensitivity analysis is then conducted to assess different CO2 leakage scenarios to the overburden. The developed semi-analytical solution provides a new simple and practical approach to assess the potential of CO2 leakage outside the storage site. This approach is an alternative to numerical methods when detailed simulations are not feasible. Furthermore, the proposed solution can also be used to verify numerical codes, which often exhibit numerical artifacts.

scholarly journals Biosignatures of ancient microbial life are present across the igneous crust of the Fennoscandian shield

2021 ◽  
Vol 2 (1) ◽  
Author(s):  
Henrik Drake ◽  
Nick M. W. Roberts ◽  
Manuel Reinhardt ◽  
Martin Whitehouse ◽  
Magnus Ivarsson ◽  
...  
Keyword(s):  
Fennoscandian Shield ◽  
Stable Carbon ◽  
Deep Biosphere ◽  
Isotopic Signatures ◽  
Microbial Life ◽  
Carbon Isotopic ◽  
Terrestrial Life ◽  
Vein Mineral ◽  
Methyl Branched Fatty Acids

AbstractEarth’s crust contains a substantial proportion of global biomass, hosting microbial life up to several kilometers depth. Yet, knowledge of the evolution and extent of life in this environment remains elusive and patchy. Here we present isotopic, molecular and morphological signatures for deep ancient life in vein mineral specimens from mines distributed across the Precambrian Fennoscandian shield. Stable carbon isotopic signatures of calcite indicate microbial methanogenesis. In addition, sulfur isotope variability in pyrite, supported by stable carbon isotopic signatures of methyl-branched fatty acids, suggest subsequent bacterial sulfate reduction. Carbonate geochronology constrains the timing of these processes to the Cenozoic. We suggest that signatures of an ancient deep biosphere and long-term microbial activity are present throughout this shield. We suggest that microbes may have been active in the continental igneous crust over geological timescales, and that subsurface investigations may be valuable in the search for extra-terrestrial life.

scholarly journals CONSTRUCTION AND ANALYSIS OF LONG-TERM SURFACE TEMPERATURE DATASET IN FUJIAN PROVINCE

2017 ◽  
Vol XLII-2/W7 ◽  
pp. 1223-1227 ◽  
Author(s):  
W. E. Li ◽  
X. Q. Wang ◽  
H. Su
Keyword(s):  
Time Series ◽  
Surface Temperature ◽  
Land Surface ◽  
Rapid Development ◽  
Temporal Distribution ◽  
Heat Fluxes ◽  
Urban Region ◽  
Fujian Province ◽  
Spatio Temporal

Land surface temperature (LST) is a key parameter of land surface physical processes on global and regional scales, linking the heat fluxes and interactions between the ground and atmosphere. Based on MODIS 8-day LST products (MOD11A2) from the split-window algorithms, we constructed and obtained the monthly and annual LST dataset of Fujian Province from 2000 to 2015. Then, we analyzed the monthly and yearly time series LST data and further investigated the LST distribution and its evolution features. The average LST of Fujian Province reached the highest in July, while the lowest in January. The monthly and annual LST time series present a significantly periodic features (annual and interannual) from 2000 to 2015. The spatial distribution showed that the LST in North and West was lower than South and East in Fujian Province. With the rapid development and urbanization of the coastal area in Fujian Province, the LST in coastal urban region was significantly higher than that in mountainous rural region. The LST distributions might affected by the climate, topography and land cover types. The spatio-temporal distribution characteristics of LST could provide good references for the agricultural layout and environment monitoring in Fujian Province.

scholarly journals δ 13 C methane source signatures from tropical wetland and rice field emissions

2021 ◽  
Vol 380 (2215) ◽  
Author(s):  
James L. France ◽  
Rebecca E. Fisher ◽  
David Lowry ◽  
Grant Allen ◽  
Marcos F. Andrade ◽  
...  
Keyword(s):  
Rice Field ◽  
Ambient Air ◽  
Atmospheric Methane ◽  
Isotopic Signatures ◽  
Methane Budget ◽  
Significant Seasonal Variation ◽  
Methane Source ◽  
Wetland Extent ◽  
Term Monitoring

The atmospheric methane (CH 4 ) burden is rising sharply, but the causes are still not well understood. One factor of uncertainty is the importance of tropical CH 4 emissions into the global mix. Isotopic signatures of major sources remain poorly constrained, despite their usefulness in constraining the global methane budget. Here, a collection of new δ 13 C CH 4 signatures is presented for a range of tropical wetlands and rice fields determined from air samples collected during campaigns from 2016 to 2020. Long-term monitoring of δ 13 C CH 4 in ambient air has been conducted at the Chacaltaya observatory, Bolivia and Southern Botswana. Both long-term records are dominated by biogenic CH 4 sources, with isotopic signatures expected from wetland sources. From the longer-term Bolivian record, a seasonal isotopic shift is observed corresponding to wetland extent suggesting that there is input of relatively isotopically light CH 4 to the atmosphere during periods of reduced wetland extent. This new data expands the geographical extent and range of measurements of tropical wetland and rice δ 13 C CH 4 sources and hints at significant seasonal variation in tropical wetland δ 13 C CH 4 signatures which may be important to capture in future global and regional models. This article is part of a discussion meeting issue ‘Rising methane: is warming feeding warming? (part 2)’.

Biology and Management of Dogfish Sharks

2009 ◽  
Keyword(s):  
Stable Isotope ◽  
Isotope Composition ◽  
Feeding Habits ◽  
Important Species ◽  
Isotopic Signatures ◽  
Ecological Changes ◽  
Varied Diet ◽  
Commercially Important ◽  
C And N

Abstract.—Spiny dogfish <em>Squalus acanthias </em>are an abundant and commercially important species of fish off both the Atlantic and Pacific coasts of North America. They are opportunistic feeders and have a varied diet that can include many fish species, especially small forage fish such as herring, capelin, and sand lance as well as crustaceans, worms, euphausiids, gelatinous zooplankton, and cephalopods. The purpose of our present study is to investigate the utility of the second dorsal spine in providing multiyear information on the feeding habits of dogfish using stable isotope (C and N) analysis. The outer dentine and enamel layers of a spine from three dogfish (caught off the coast of British Columbia) were analyzed to obtain their stable nitrogen and carbon isotope composition (δ<sup>15</sup>N and δ<sup>13</sup>C, respectively). Each sample had annuli from multiple years, allowing possible seasonal migrations to be averaged over samples. The δ<sup>15</sup>N ranged from a low of 11.6‰ to a high of 14.9‰ over the three spines and δ<sup>13</sup>C ranged from –11.5‰ to –18.4‰. The variable isotopic signatures along the spine indicate that the method may be used to assess ecological changes. Stable isotope measurements of dogfish spines could be a valuable means of determining long-term changes in habitat usage and feeding ecology.

Soil Material Quality and Environmental Potential of Metallically Contaminated Soils

2020 ◽  
Vol 838 ◽  
pp. 164-169
Author(s):  
Juraj Fazekaš ◽  
Danica Fazekašova ◽  
Jana Chovancová
Keyword(s):  
Contaminated Soils ◽  
Agricultural Land ◽  
Mining Activity ◽  
Limit Values ◽  
Soil Material ◽  
Risk Elements ◽  
Average Value ◽  
Potential Index ◽  
Environmental Functions

The paper presents the results of the evaluation of the environmental potential of soils in the area affected by the long-term mining activity. The environmental potential index consists of a numerical expression of the ability to provide water storage, immobilization of risk elements, and immobilization and transformation of organic pollutants. The exceedance of the limit values Hg, Cu, Zn, As, Cd and Pb was found in the soils of the investigated area of central Spiš. The rate of soil immobilization of risk elements is very low to high. The point value expressing the ability of agricultural lands to provide environmental functions is very low to medium in the studied areas, the financial expression of the values of the environmental potentials indexes is in the range of 7 100 to 14 000 € ha-1, while the average value of 1 ha of agricultural land in Slovakia is about 14 200 €.

The dissolution of asbestos fibres in water

Clay Minerals ◽  
1987 ◽  
Vol 22 (1) ◽  
pp. 21-35 ◽  
Author(s):  
Janet R. Gronow
Keyword(s):  
Natural Waters ◽  
Activation Energies ◽  
Factors Affecting ◽  
Controlled Processes ◽  
Rate Laws ◽  
Prolonged Contact ◽  
Congruent Dissolution ◽  
Groundwater Systems ◽  
Apparent Activation Energies

AbstractThe interaction of chrysotile and crocidolite with water has been investigated in an attempt to identify the factors affecting the rate and the degree of dissolution of asbestos fibres within groundwater systems at landfill sites. Dissolution experiments were used to investigate rate laws and to obtain apparent activation energies for the dissolution of the two minerals. The activation energies related to transport-controlled processes, but as the overall dissolution occurred so slowly it was unlikely to be controlled by processes with such low activation energies. Congruent dissolution of both minerals tended to increase with temperature and time, suggesting that in the long-term environmental situation, congruent dissolution of these two asbestos minerals would occur. However these experiments show that, as the reaction was so slow, there is little likelihood of reduction of the asbestos pollution hazard by the complete dissolution of fibres on prolonged contact with natural waters.

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