scholarly journals A Field Pilot Study on Treating Groundwater Contaminated with Sulfolane Using UV/H2O2

Water ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 1200 ◽  
Author(s):  
Linlong Yu ◽  
Sobhan Iranmanesh ◽  
Ian Keir ◽  
Gopal Achari
Keyword(s):  
Water Flow ◽  
Cost Model ◽  
Electrical Energy ◽  
Pilot Scale ◽  
Process Efficiency ◽  
Contaminated Groundwater ◽  
Operational Parameters ◽  
Flow Rates ◽  
Electrical Energy Per Order ◽  
H2o2 System

Sulfolane is an emerging contaminant in the groundwater and soil nearby gas plants, which has attracted much attention from many researchers and regulatory agencies in the past ten years. In this paper, a field pilot-scale ultraviolet (UV)/hydrogen peroxide (H2O2) system was investigated for treating sulfolane contaminated groundwater. Different groundwater, as well as different operational parameters such as influent sulfolane concentration, H2O2 dosage, and water flow rates, were studied. The results showed that a pilot-scale UV/H2O2 system can successfully treat sulfolane contaminated groundwater in the field, although the presence of iron and other groundwater limited the process efficiency. The lowest electrical energy per order of reduction for treating sulfolane in groundwater by using the pilot-scale UV/H2O2 system was 1.4 kWh m−3 order−1. The investigated sulfolane initial concentrations and the water flow rates did not impact the sulfolane degradation. The enhancement of sulfolane degradation in an open reservoir by adding ozone was not observed in this study. Furthermore, an operational cost model was formulated to optimize the dosage of H2O2, and a stepwise procedure was developed to determine the power necessary of the UV unit.

Optimization and Modeling of Photooxidative Process for the Degradation of Reactive Red223

2020 ◽  
Vol 42 (1) ◽  
pp. 42-42
Author(s):  
Abdul Rauf Shah Abdul Rauf Shah ◽  
Hajira Tahir and Tahira Yasmeen Hajira Tahir and Tahira Yasmeen
Keyword(s):  
Figure Of Merit ◽  
Irradiation Time ◽  
Electrical Energy ◽  
Order Kinetic ◽  
Operational Parameters ◽  
Contour Plots ◽  
Pseudo Second Order ◽  
Electrical Energy Per Order ◽  
The Cost ◽  
Central Composite

The optimization of the photooxidative process was carried out with the application of Response Surface Methodology (RSM) to degrade Reactive Red 223 (RR223) dye. Operational parameters of U.V/H2O2 process such as irradiation time, initial [dye], initial [H2O2] and distance between U.V lamp and the solution were optimized with Central Composite Design (CCD). Correlation coefficient value of the CCD was obtained to be 79 %, showing the correctness of the model and the successful utilization of CCD in getting desired levels of the factors of the process. Moreover, the optimum points were located with the graphical surface and contour plots. At the optimal conditions, the photooxidative removal of the color and COD were observed to be 68%, 81%, respectively. Furthermore, the pseudo-second order kinetic was guiding the removal of the dye in the process. Subsequently, the electrical energy consumption was estimated in term of the merit electrical energy per order (EEO). The figure of merit of the process was found to be 252 kWhm−3 order−1. The cost of the treatment was also calculated to be US$ 25/m3.

scholarly journals The efficiency of a membrane bioreactor in drinking water denitrification

2015 ◽  
Vol 21 (2) ◽  
pp. 269-275
Author(s):  
Aleksandra Petrovic ◽  
Marjana Simonic
Keyword(s):  
Drinking Water ◽  
Flow Rate ◽  
Membrane Bioreactor ◽  
Nitrate Removal ◽  
Maximum Flow ◽  
Pilot Scale ◽  
Operational Parameters ◽  
Flow Rates ◽  
Removal Capacity ◽  
Removal Efficiencies

The membrane bioreactor (MBR) system was investigated regarding its nitrate removal capacity from drinking water. The performance of a pilot-scale MBR was tested, depending on the operational parameters, using sucrose as a carbon source. Drinking water from the source was introduced into the reactor in order to study the influence of flow-rate on the nitrate removal and denitrification efficiency of drinking water. The content of the nitrate was around 70 mg/L and the C/N ratio was 3:1. Nitrate removal efficiencies above 90% were obtained by flow-rates lower than 4.8 L/h. The specific denitrification rates varied between 0.02 and 0.16 g/L NO3/ (g/L MLSS?d). The efficiencies and nitrate removal were noticeably affected by the flow-rate and hydraulic retention times. At the maximum flow-rate of 10.2 L/h still 68% of the nitrate had been removed, whilst the highest specific denitrification rate was achieved at 0.2738 g/L NO3/ (g/L) MLSS?d). The maximum reactor removal capacity was calculated at 8.75 g NO3/m3?h.

A pilot-scale investigation of ozonation and advanced oxidation processes at Choa Chu Kang Waterworks

2015 ◽  
Vol 10 (1) ◽  
pp. 43-49 ◽  
Author(s):  
Jenny Wang ◽  
Achim Ried ◽  
Harald Stapel ◽  
Yaning Zhang ◽  
Minghui Chen ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Organic Contaminants ◽  
Advanced Oxidation Processes ◽  
Advanced Oxidation ◽  
Electrical Energy ◽  
Pilot Scale ◽  
Oxidation Processes ◽  
Water Matrix ◽  
Electrical Energy Per Order ◽  
Efficient Option

A two-year comprehensive advanced oxidation processes (AOPs) pilot test was completed for a Singapore waterworks in 2011–2013. This study focused on oxidative removal of spiked organic contaminants with ozone and ozone-based AOPs (ozone application together with hydrogen peroxide, which is necessary for AOPs). The ‘optimized H2O2 dosage’ test philosophy was verified during the test period – keeping the residual ozone at 0.3 mg/L in the water for disinfection purpose by minimizing the H2O2 dosage. This study also monitored the bromate concentration in both ozone- and AOP-treated water, and all the samples reported below the laboratory detection limit (<5 µg/L), which is also lower than the WHO Guidelines for Drinking Water Quality (<10 µg/L). For comparison, a low pressure UV-based AOP test was conducted in the final stage of the study. The electrical energy per order (EEO) value is compared with ozone- and UV-based AOPs as well. The results indicated that ozone-based AOP with an optimized hydrogen peroxide dosage could be the most energy efficient option for this specific water matrix in terms of most selected compounds.

scholarly journals Application of central composite design for the optimization of photo-destruction of a textile dye using UV/S2O82- process

2009 ◽  
Vol 11 (4) ◽  
pp. 38-45 ◽  
Author(s):  
A. Khataee
Keyword(s):  
Reaction Time ◽  
Central Composite Design ◽  
Electrical Energy ◽  
Textile Dye ◽  
Operational Parameters ◽  
Destruction Efficiency ◽  
Uv Lamp ◽  
Electrical Energy Per Order ◽  
Experimental Values ◽  
Central Composite

Application of central composite design for the optimization of photo-destruction of a textile dye using UV/S2O82- process The photooxidative destruction of C. I. Basic Red 46 (BR46) by UV/S2O82- process is presented. Central Composite Design (CCD) was employed to optimize the effects of operational parameters on the photooxidative destruction efficiency. The variables investigated were the initial dye and S2O82- concentrations, reaction time and distance of the solution from UV lamp. The predicted values of the photodestruction efficiency were found to be in good agreement with the experimental values (R2 = 0.9810, Adjusted R2 = 0.9643). The results of the optimization predicted by the model showed that the maximum decolorization efficiency (>98%) was achieved at the optimum conditions of the reaction time 10 min, initial dye concentration 10 mg/l, initial peroxydisulfate concentration 1.5 mmol/l and distance of UV lamp from the solution 6 cm. The figure-of-merit electrical energy per order (EEo) was employed to estimate the electrical energy consumption and related treatment costs.

On-site and in situ bioremediation of wood-preservative contaminated groundwater

2000 ◽  
Vol 42 (5-6) ◽  
pp. 371-376 ◽  
Author(s):  
J.A. Puhakka ◽  
K.T. Järvinen ◽  
J.H. Langwaldt ◽  
E.S. Melin ◽  
M.K. Männistö ◽  
...  
Keyword(s):  
Iron Oxidation ◽  
Wood Preservative ◽  
Pilot Scale ◽  
High Rate ◽  
Contaminated Groundwater ◽  
Groundwater Temperature ◽  
In Situ Bioremediation ◽  
Contaminated Aquifer ◽  
Fluidized Bed Process

This paper reviews ten years of research on on-site and in situ bioremediation of chlorophenol contaminated groundwater. Laboratory experiments on the development of a high-rate, fluidized-bed process resulted in a full-scale, pump-and-treat application which has operated for several years. The system operates at ambient groundwater temperature of 7 to 9°C at 2.7 d hydraulic retention time and chlorophenol removal efficiencies of 98.5 to 99.9%. The microbial ecology studies of the contaminated aquifer revealed a diverse chlorophenol-degrading community. In situ biodegradation of chlorophenols is controlled by oxygen availability, only. Laboratory and pilot-scale experiments showed the potential for in situ aquifer bioremediation with iron oxidation and precipitation as a potential problem.

scholarly journals Geometrical Optimization of a Venturi-Type Microbubble Generator Using CFD Simulation and Experimental Measurements

Designs ◽  
2021 ◽  
Vol 5 (1) ◽  
pp. 4
Author(s):  
Dillon Alexander Wilson ◽  
Kul Pun ◽  
Poo Balan Ganesan ◽  
Faik Hamad
Keyword(s):  
Water Flow ◽  
Flow Rate ◽  
Cfd Simulation ◽  
Air Flow ◽  
Bubble Diameter ◽  
Diameter Ratio ◽  
Experimental Measurements ◽  
Cfd Model ◽  
Flow Rates ◽  
Throat Diameter

Microbubble generators are of considerable importance to a range of scientific fields from use in aquaculture and engineering to medical applications. This is due to the fact the amount of sea life in the water is proportional to the amount of oxygen in it. In this paper, experimental measurements and computational Fluid Dynamics (CFD) simulation are performed for three water flow rates and three with three different air flow rates. The experimental data presented in the paper are used to validate the CFD model. Then, the CFD model is used to study the effect of diverging angle and throat length/throat diameter ratio on the size of the microbubble produced by the Venturi-type microbubble generator. The experimental results showed that increasing water flow rate and reducing the air flow rate produces smaller microbubbles. The prediction from the CFD results indicated that throat length/throat diameter ratio and diffuser divergent angle have a small effect on bubble diameter distribution and average bubble diameter for the range of the throat water velocities used in this study.

scholarly journals Comparison of Optimization-Regulation Algorithms for Secondary Cooling in Continuous Steel Casting

Metals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 237
Author(s):  
Michal Brezina ◽  
Tomas Mauder ◽  
Lubomir Klimes ◽  
Josef Stetina
Keyword(s):  
Convergence Rate ◽  
Water Flow ◽  
Steel Casting ◽  
Casting Process ◽  
Continuous Steel Casting ◽  
Continuous Steel ◽  
Cooling Zone ◽  
Secondary Cooling ◽  
Flow Rates ◽  
Secondary Cooling Zone

The paper presents the comparison of optimization-regulation algorithms applied to the secondary cooling zone in continuous steel casting where the semi-product withdraws most of its thermal energy. In steel production, requirements towards obtaining defect-free semi-products are increasing day-by-day and the products, which would satisfy requirements of the consumers a few decades ago, are now far below the minimum required quality. To fulfill the quality demands towards minimum occurrence of defects in secondary cooling as possible, some regulation in the casting process is needed. The main concept of this paper is to analyze and compare the most known metaheuristic optimization approaches applied to the continuous steel casting process. Heat transfer and solidification phenomena are solved by using a fast 2.5D slice numerical model. The objective function is set to minimize the surface temperature differences in secondary cooling zones between calculated and targeted surface temperatures by suitable water flow rates through cooling nozzles. Obtained optimization results are discussed and the most suitable algorithm for this type of optimization problem is identified. Temperature deviations and cooling water flow rates in the secondary cooling zone, together with convergence rate and operation times needed to reach the stop criterium for each optimization approach, are analyzed and compared to target casting conditions based on a required temperature distribution of the strand. The paper also contains a brief description of applied heuristic algorithms. Some of the algorithms exhibited faster convergence rate than others, but the optimal solution was reached in every optimization run by only one algorithm.

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