scholarly journals Evidence of Natural and Anthropogenic Impacts on Rainwater Trace Metal Geochemistry in Central Mexico: A Statistical Approach

Water ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 192 ◽  
Author(s):  
D. M. Rivera-Rivera ◽  
D. C. Escobedo-Urías ◽  
M. P. Jonathan ◽  
S. B. Sujitha ◽  
S. Chidambaram
Keyword(s):  
Trace Metals ◽  
Trace Metal ◽  
Statistical Approach ◽  
Anthropogenic Impacts ◽  
Human Consumption ◽  
Monthly Basis ◽  
Air Masses ◽  
Local Transport ◽  
High Concentrations ◽  
Toxic Potential

Trace metals Fe, Mn, Cr, Cu, Ni, Co, Pb, Zn, Cd, and As were determined on a monthly basis in a total of 52 rain samples collected from six different locations in the central region of Mexico during March 2016–April 2017. The average concentrations of trace metals (mg/L) in the rainwater samples showed an order of Zn (0.873) > Fe (0.395) > Mn (0.083) > Cr (0.041) ≥ Cu (0.041) > Pb (0.031) > Ni (0.020) > Co (0.013) > As (0.0003) > Cd (0.002). The differences observed in metal concentrations are related to variations in the influence of continental air masses, local transport, regional advection, and the solubility of trace metals. High concentrations of metals were observed in the months of March to May at all sites, probably due to the less extensive removal of air/air pollutants. The values obtained from the enrichment factor (EF) per metal showed relatively high values for Cd, Zn, Cu, Pb, Co, Ni, and Cr, suggesting anthropogenic origin. Pearson’s correlation matrix validated the distribution of trace metal sources and their relationships with local/regional meteorological characteristics. This paper presents relevant basic information for the evaluation of the toxic potential of rainwater and the possible health risks when using this source of water for human consumption.

scholarly journals Metal contamination and oxidative stress biomarkers in estuarine fish following a mine tailing disaster

2020 ◽  
Author(s):  
Fabrício Ângelo Gabriel ◽  
Rachel Ann Hauser-Davis ◽  
Lorena Oliveira Souza Soares ◽  
Ana Carolina de Azevedo Mazzuco ◽  
Rafael Christian Chávez Rocha ◽  
...  
Keyword(s):  
Trace Metals ◽  
Trace Metal ◽  
Muscle Tissue ◽  
Fish Species ◽  
Metal Contamination ◽  
Contaminated Sediments ◽  
Estuarine Sediments ◽  
Estuarine Fish ◽  
Human Consumption ◽  
Metal Concentrations

AbstractThe Rio Doce estuary in Brazil was impacted by the deposition of mine tailings caused by the collapse of a mining dam in 2015. Since the disaster, the estuary is experiencing chronic trace metal contamination effects, but potential trace metal accumulation in fishes has not been reported. Trace metals in aquatic ecosystems pose severe threats to the aquatic biota, so we hypothesized that the accumulation of trace metals in estuarine sediments nearly two years after the disaster would cause contaminant bioaccumulation, resulting in the biosynthesis of metal-responsive proteins in fishes. We determined trace metal concentrations in sediment samples, metal concentrations, and quantified stress protein concentrations in the liver and muscle tissue of five different fish species in the estuary. Our results revealed high concentrations of trace metals in estuarine sediments when compared to published baseline values for this estuary. The demersal fish species Cathorops spixii and Genidens genidens had the highest Hg, As, Se, Cr, and Mn concentrations in both hepatic and muscle tissues. Metal bioaccumulation in fish was statistically correlated with the biosynthesis of metallothionein and reduced glutathione in both fish liver and muscle tissue. The trace metals detected in fish tissues resemble those in the contaminated sediments present at the estuary at the time of this study and were also significantly correlated to protein levels. Trace metals in fish muscle were above the maximum permissible limits for human consumption, suggesting potential human health risks that require further determination. Our study supports the high biogeochemical mobility of trace metals between contaminated sediments and local biota in estuarine ecosystems.

scholarly journals Trace Metals Contamination in Bread Ingredients and Bread from Bakeries in Nigeria

2020 ◽  
pp. 26-37
Author(s):  
V. O. E. Akpambang ◽  
A. P. Onifade
Keyword(s):  
Trace Metals ◽  
Trace Metal ◽  
Human Consumption ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer ◽  
Regular Consumption ◽  
Metal Contents ◽  
Wheat Flours ◽  
Toxic Trace Metals ◽  
Range Of Values

Bread loaves and bread ingredients (wheat flours, salt, sugar, yeast and water) were randomly sampled from ten bakeries within Akure metropolis of south western Nigeria and analysed to determine their safety levels for human consumption with respect to trace metal contents. The trace metals (Cu, Zn, Mn, Cr, Cd and Pb) were analysed in the samples using flame atomic absorption spectrophotometer. Results obtained revealed that toxic trace metals such as Cr, Cd and Pb were not detected in any of the samples. However, the levels of essential trace metals such as Cu, Zn and Mn had range of values in mg/kg: (0.039 – 0.091), (0.837 – 3.310) and (0.035 – 3.148); (0.056 – 0.091), (0.034 – 2.755) and (0.054 – 1.054) in the wheat flours and bread samples analysed respectively. This study revealed that the bread ingredients and loaves of bread sampled contained essential trace metals at levels that could not threaten the health of consumers over prolonged regular consumption.

Elemental distribution in trace metal-treated Pisolithus tinctorius prepared by propane jet and high pressure freezing methods

1992 ◽  
Vol 50 (1) ◽  
pp. 730-731
Author(s):  
C.J. McQuattie ◽  
K.L. Klomparens ◽  
J.I. Wood ◽  
J.W. Heckman
Keyword(s):  
High Pressure ◽  
Trace Metals ◽  
Trace Metal ◽  
Freeze Substitution ◽  
Pisolithus Tinctorius ◽  
Elemental Distribution ◽  
Forest Trees ◽  
High Pressure Freezing ◽  
Protective Function ◽  
High Concentrations

Localization of trace metals on or within mycorrhizal (M) fungi may serve a protective function for roots of forest trees growing in soils containing high concentrations of metals such as Pb and Al. The presence of both Pb and Al have been demonstrated in the M fungus Pisolithus tinctorius after preparation by propane jet (PJ) freezing and freeze substitution. High pressure freezing (HPF) is an alternative method of cryopreparation that has demonstrated excellent ultrastructural preservation in studies of developing ascospores. The purpose of this study was to compare ultrastructural preservation and trace metal localization in P. tinctorius using PJ freezing and HPF methods.

Degraded peatlands of South East Asia : a source of Trace Metal to surface waters

2020 ◽  
Author(s):  
Laure Gandois ◽  
Alison M. Hoyt ◽  
Stéphane Mounier ◽  
Gaël Le Roux ◽  
Charles F. Harvey ◽  
...  
Keyword(s):  
Trace Metals ◽  
Trace Metal ◽  
Surface Waters ◽  
Strong Association ◽  
Secondary Source ◽  
Carbon Export ◽  
West Kalimantan ◽  
Tropical Peatlands ◽  
High Concentrations ◽  
First Time

<p>Worldwide, peatlands are important sources of dissolved organic matter (DOM) and trace metals (TM) to surface waters and these fluxes may increase with peatland degradation. In Southeast Asia, tropical peatlands are being rapidly deforested and drained. The black rivers draining these peatland areas have high concentrations of DOM. However, the fate of this fluvial carbon export is uncertain, and its role as a trace metal carrier has never been investigated. This work aims to address these gaps in our understanding of tropical peatland DOM and associated elements in the context of degraded tropical peatlands of Indonesian Borneo. We quantified dissolved organic carbon and trace metals concentrations in the dissolved, fine colloidal and coarse colloidal fractions and determined the characteristics (optical and isotopic) of the peatland-derived DOM as it drains from peatland canals, flows along black river and eventually mixes with the Kapuas Kecil River before meeting the ocean near the city of Pontianak in West Kalimantan, Indonesia. Black rivers draining degraded peatlands show significantly higher concentrations of Al, Fe, Pb, As, Ni, and Cd, compared the white river. A strong association is observed between DOM, Fe, As, Cd and Zn in the dissolved and fine colloid fraction, while Al is associated to Pb and Ni and present in a higher proportion in the coarse colloidal fraction. We additionally measured the isotopic composition of lead released from degraded tropical peatlands for the first time and show that Pb originates from anthropogenic atmospheric deposition. Degraded tropical peatlands are important sources of DOM and trace metals to rivers and a secondary source of atmospherically deposited contaminants.</p>

scholarly journals From Canals to the Coast: Dissolved Organic Matter and Trace Metal Composition in Rivers Draining Degraded Tropical Peatlands in Indonesia

2019 ◽  
Author(s):  
Laure Gandois ◽  
Alison May Hoyt ◽  
Stéphane Mounier ◽  
Gaël Le Roux ◽  
Charles Franklin Harvey ◽  
...  
Keyword(s):  
Organic Matter ◽  
Trace Metals ◽  
Dissolved Organic Matter ◽  
Trace Metal ◽  
Carbon Export ◽  
Tropical Peatlands ◽  
Metal Composition ◽  
High Concentrations ◽  
Peatland Degradation ◽  
Co2 Release

Abstract. Worldwide, peatlands are important sources of dissolved organic matter (DOM) and trace metals (TM) to surface waters and these fluxes may increase with peatland degradation. In Southeast Asia, tropical peatlands are being rapidly deforested and drained. The black rivers draining these peatland areas have high concentrations of DOM, and the potential to be hotspots for CO2 release. However, the fate of this fluvial carbon export is uncertain, and its role as a trace metal carrier has never been investigated. This work aims to address these gaps in our understanding of tropical peatland DOM and associated elements in the context of degraded tropical peatlands of Indonesian Borneo. We quantified dissolved organic carbon and trace metals concentrations in the dissolved and fine colloidal (

scholarly journals Marine ammonia-oxidising archaea and bacteria occupy distinct iron and copper niches

2021 ◽  
Vol 1 (1) ◽  
Author(s):  
Roxana T. Shafiee ◽  
Poppy J. Diver ◽  
Joseph T. Snow ◽  
Qiong Zhang ◽  
Rosalind E. M. Rickaby
Keyword(s):  
Comparative Genomics ◽  
Trace Metals ◽  
Trace Metal ◽  
Ammonia Oxidation ◽  
Testable Hypothesis ◽  
Niche Separation ◽  
Toxicity Threshold ◽  
Geologic Time ◽  
Additional Explanation ◽  
Ammonia Oxidising Archaea

AbstractAmmonia oxidation by archaea and bacteria (AOA and AOB), is the first step of nitrification in the oceans. As AOA have an ammonium affinity 200-fold higher than AOB isolates, the chemical niche allowing AOB to persist in the oligotrophic ocean remains unclear. Here we show that marine isolates, Nitrosopumilus maritimus strain SCM1 (AOA) and Nitrosococcus oceani strain C-107 (AOB) have contrasting physiologies in response to the trace metals iron (Fe) and copper (Cu), holding potential implications for their niche separation in the oceans. A greater affinity for unchelated Fe may allow AOB to inhabit shallower, euphotic waters where ammonium supply is high, but competition for Fe is rife. In contrast to AOB, AOA isolates have a greater affinity and toxicity threshold for unchelated Cu providing additional explanation to the greater success of AOA in the marine environment where Cu availability can be highly variable. Using comparative genomics, we predict that the proteomic and metal transport basis giving rise to contrasting physiologies in isolates is widespread across phylogenetically diverse marine AOA and AOB that are not yet available in pure culture. Our results develop the testable hypothesis that ammonia oxidation may be limited by Cu in large tracts of the open ocean and suggest a relatively earlier emergence of AOB than AOA when considered in the context of evolving trace metal availabilities over geologic time.

scholarly journals Significance of building and plumbing specifics on trace metal concentrations in drinking water

1991 ◽  
Vol 18 (6) ◽  
pp. 893-903 ◽  
Author(s):  
Inderjit Singh ◽  
Donald S. Mavinic
Keyword(s):  
Drinking Water ◽  
Trace Metals ◽  
Trace Metal ◽  
Water Samples ◽  
First Flush ◽  
Single Family ◽  
Metal Concentrations ◽  
Building Height ◽  
High Rise ◽  
Family House

Samples were taken from 72 high-rise apartment suites (6 suites in 12 individual high-rise towers) and 60 single-family houses located within the Greater Vancouver Regional District. The influence of the following factors on trace metal concentrations in 1-L first-flush drinking water samples and “running” hot water samples was investigated: building height, location, plumbing age, type of plumbing, and type of building. Results of this survey show that with the exception of building height, all factors had a correlation with one or more of the trace metals investigated. The trace metals examined were lead, copper, iron, and zinc. Lead was influenced primarily by building type, copper by plumbing age and type of plumbing, and iron by location. Elevated lead levels were associated with high-rise samples. New copper plumbing systems resulted in high copper levels. Highest iron levels in the drinking water were measured in the East Vancouver location. Zinc did not show a distinct correlation with any of the factors investigated. Brass faucets were the primary source of zinc in tap water. They also contributed substantially to the lead detected in the 1-L first-flush sample. Metal concentrations measured in the high-rise and house samples were compared with the U.S. Environmental Protection Agency's (USEPA) maximum contaminant levels (MCLs) and the proposed “no-action” level for lead. In high-rise samples, the 0.01 mg/L “no-action” level proposed for lead was exceeded in 43% of the samples, and 62% of the samples exceeded the current 1.0 mg/L MCL standard for copper. In single-family house samples, these values were 47% and 73%, respectively. The average lead concentrations were 0.020 mg/L for all high-rise samples and 0.013 mg/L for house samples. Regulatory levels stated above would still be exceeded in 6% of the cases for lead and 9% of the cases for copper, even after prolonged flushing of the tap in a high-rise building. In all cases associated with single-family houses, flushing the cold water tap for 5 minutes was successful in achieving compliance levels. Key words: aggressive water, compliance, corrosive, drinking water, first-flush, GVRD, high-rise, single-family house, trace metals, USEPA.

The Influence of Oceanic Air Masses on Concentration of Major Ions and Trace Metals in PM2.5 Fraction at a Coastal European Suburban Site

2014 ◽  
Vol 226 (1) ◽  
Author(s):  
Jorge Moreda-Piñeiro ◽  
Isabel Turnes-Carou ◽  
Elia Alonso-Rodríguez ◽  
Carmen Moscoso-Pérez ◽  
Gustavo Blanco-Heras ◽  
...  
Keyword(s):  
Trace Metals ◽  
Major Ions ◽  
Air Masses ◽  
Suburban Site

scholarly journals Multivariate statistical air mass classification for the high-alpine observatory at the Zugspitze Mountain, Germany

2019 ◽  
Vol 19 (19) ◽  
pp. 12477-12494 ◽  
Author(s):  
Armin Sigmund ◽  
Korbinian Freier ◽  
Till Rehm ◽  
Ludwig Ries ◽  
Christian Schunk ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Real Time ◽  
Statistical Approach ◽  
Free Troposphere ◽  
Time Data ◽  
Detection Scheme ◽  
Air Mass ◽  
Thermally Induced ◽  
Air Masses ◽  
Mechanistic Approach

Abstract. To assist atmospheric monitoring at high-alpine sites, a statistical approach for distinguishing between the dominant air masses was developed. This approach was based on a principal component analysis using five gas-phase and two meteorological variables. The analysis focused on the Schneefernerhaus site at Zugspitze Mountain, Germany. The investigated year was divided into 2-month periods, for which the analysis was repeated. Using the 33.3 % and 66.6 % percentiles of the first two principal components, nine air mass regimes were defined. These regimes were interpreted with respect to vertical transport and assigned to the BL (recent contact with the boundary layer), UFT/SIN (undisturbed free troposphere or stratospheric intrusion), and HYBRID (influences of both the boundary layer and the free troposphere or ambiguous) air mass classes. The input data were available for 78 % of the investigated year. BL accounted for 31 % of the cases with similar frequencies in all seasons. UFT/SIN comprised 14 % of the cases but was not found from April to July. HYBRID (55 %) mostly exhibited intermediate characteristics, whereby 17 % of the HYBRID class suggested an influence from the marine boundary layer or the lower free troposphere. The statistical approach was compared to a mechanistic approach using the ceilometer-based mixing layer height from a nearby valley site and a detection scheme for thermally induced mountain winds. Due to data gaps, only 25 % of the cases could be classified using the mechanistic approach. Both approaches agreed well, except in the rare cases of thermally induced uplift. The statistical approach is a promising step towards a real-time classification of air masses. Future work is necessary to assess the uncertainty arising from the standardization of real-time data.

Ferritin Crystals in the Gut Caeca of a Deep-Sea Hydrothermal Vent Stegocephalid (Crustacea: Amphipoda)

1997 ◽  
Vol 77 (1) ◽  
pp. 269-272 ◽  
Author(s):  
P.G. Moore ◽  
P.S. Rainbow
Keyword(s):  
Trace Metals ◽  
Hydrothermal Vent ◽  
Tectonic Activity ◽  
Amphipod Species ◽  
Single Pair ◽  
Thin Sections ◽  
Widespread Occurrence ◽  
X Ray ◽  
Mid Atlantic Ridge ◽  
High Concentrations

Ferritin crystals and calcium granules are reported from the ventral ceaca of Steleuthera ecoprophycea (Amphipoda: Stegocephalidae) collected from the Snake Pit hydrothermal vent, Mid-Atlantic Ridge (3520 m).In a series of earlier papers (Moore & Rainbow, 1984, 1989, 1992; Moore et al., 1994), the authors described the widespread occurrence of intracellular, octahedral crystals of ferritin in the ventral caeca of a range of stegocephalid amphipod species from the continental shelf epibenthos and oceanic plankton. The discovery at 3500 m of a new Steleuthera species (S. ecoprophycea), from a hydrothermal vent on the Mid-Atlantic Ridge was announced recently by Bellan-Santini & Thurston (1996), and a complete description is provided therein.Oceanic ridge sites are notable for their tectonic activity and the presence of a diversity of trace metals at high concentrations is to be expected in hydrothermal plumes emanating from such regions (German & Angel, 1995). The detoxification of accumulated trace metals in the ventral ceaca of stegocephalid amphipods from uncontaminated environments is now relatively well known (see above), so it was of interest to investigate whether a vent stegocephalid showed an atypical presence of trace metals in detoxified form in cells of the ventral caeca. The results following from an opportunity to investigate this are reported herein.Material was derived from a dive made by the submersible ‘Alvin’ at Snake Pit hydrothermal field, Mid-Atlantic Ridge (23°23′N 44°56′W), 3520 m, on 16 June 1993 (see Bellan-Santini & Thurston, 1996). Steleuthera ecoprophycea was preserved in 70% alcohol. Subsequently to dissection, the single pair of ventral caeca from each of the four damaged amphipods investigated were post-fixed in 4% glutaraldehyde. For electron microscopy and x-ray microanalysis in STEM mode, ventral caecal tissues were then dehydrated through 95% and absolute ethanol, cleared in propylene oxide, embedded in TAAB resin, sectioned at 0·5 μm (semi-thin sections) on a Reichert OmU2 ultramicrotome and examined without staining in a JEOL 100C electron microscope equipped with LINK system EDX energy dispersive x-ray microanalyser.

Sign in / Sign up

Export Citation Format

Share Document