scholarly journals Changes in the Content of Heavy Metals in Bílina River during 2012–2017: Effects of Flood and Industrial Inputs

Water ◽  
2019 ◽  
Vol 11 (3) ◽  
pp. 481 ◽  
Author(s):  
Jiří Čmelík ◽  
Taťjána Brovdyová ◽  
Josef Trögl ◽  
Martin Neruda ◽  
Matěj Kadlečík ◽  
...  

This article presents the development of selected heavy metals contained in river sediments at selected sites along the Bílina River. It describes the situation before the large flood in 2013, the situation just after that flood, the situation approximately 1 year after the flood, and 4 years after the flood. The contents of selected heavy metals from industrial pollution originating from transport and industry located along the river flow were monitored. Since the situation in the river before the flood was also known, it was possible to assess the impact of the 2013 flood on the distribution of heavy metals in the settled sediments. The results obtained show that the heavy metal content has changed significantly. During the flood in 2013 there was an increase in the concentration of almost all the monitored elements compared to the situation before the flood and one year after the flood. This could be caused by the churning of sediments as a result of the flood. The only exception was Cd, the concentration of which did not change significantly. However, Cd is present in the sediment samples at a low concentration at the limit of quantification (LOQ), so the change may not be noticeable. In 2017, four years after the flood, an increase in the concentration of all the monitored elements was found. The highest increase in the content of the monitored elements was observed at the sites with the highest industrial pollution. Following the flood in 2014, there was a situation where no significant differences were observed in the content of metals at the individual sampling points in contrast to the values obtained in 2012, 2013, and 2017. As a result of sediment churning and re-settlement during and after the flood, the sediment became homogenized along the entire river flow. After a longer period of time that was not accompanied by floods, a significant increase in the heavy metal concentration was observed due to anthropogenic pollution. The results show that the effect of flooding is only temporal and that anthropogenic pollution is more important than the impact of floods.

Author(s):  
Audronė Mikalajunė ◽  
Lina Jakučionytė

Vehicles release large amounts of heavy metals to the environment. There have been done a lot of investigations analysing the distribution of heavy metals in soils near intensive regional roads. However, there is lack of investigations into the impact of small-intensity gravel roads on roadside soil contamination with heavy metals. The object of this investigation is four gravel roads of local significance connecting small villages. The intensity of these roads is very low. The gravel roads are chosen according to application of dust-minimizing materials, for example, CaCl2 and oil emulsion. According to our results, none of the soil samples had an excess of heavy metal concentration limit. Besides, heavy metal concentrations were decreasing with a distance from the road increasing. We can make an assumption that road dust-minimizing materials do not have a significant impact on heavy metal distribution in roadside soils. The major factors of heavy metal pollution distribution in roadside soils are traffic intensity, roadside trenches, and topographic conditions. Santrauka Eksploatuojant autotransportą, į aplinką patenka daug sunkiųjų metalų. Atlikta nemažai tyrimų sunkiųjų metalų paplitimuidirvožemyje šalia intensyvių magistralinių kelių nustatyti, tačiau mažo intensyvumo keliai šiuo požiūriu tiriami mažai.Tirti pasirinkta 4 žvyrkeliai – vietinės reikšmvs keliai, jungiantys nedideles gyvenvietes. Eismo intensyvumas šiuose keliuose mažas. Žvyrkeliai pasirinkti pagal taikomas priemones dulkėtumui mažinti, t. y. du nagrinvjami žvyrkeliai apdorotiCaCl2, kiti du – naftos emulsija. Nė viename mėginyje sunkiųjų metalų koncentracijos neviršijo DLK, o tolstant nuo važiuojamosios kelio dalies sunkiųjų metalų koncentracijos buvo mažesnės. Galima daryti prielaidą, kad kelio apdorojimo medžiagos dulkėtumui mažinti žymios įtakos sunkiųjų metalų pasiskirstymui pakelių dirvožemyje nedaro, lemia transporto srauto intensyvumas, kelio grioviai pakelėse bei reljefo sąlygos. Резюме При эксплуатации автомобилей в окружающую среду попадает много тяжелых металлов. Проведено немалоисследований, посвященных анализу распространения тяжелых металлов в почве обочин интенсивно эксплуатируемых магистральных дорог, однако исследований, касающихся аналогичных проблем дорог малой интенсивности, в настоящее время имеется немного. В настоящей работе в качестве объекта исследований выбраны четыредороги местного значения с гравийным покрытием, соединяющие небольшие поселения. Интенсивность дорог небольшая. Гравийные дороги выбраны с учетом их обработки для уменьшения пыльности – две дороги обработаны с применением CaCl2, а две другие – с применением нефтяной эмульсии. Ни в одной пробе не былозафиксировано концентраций тяжелых металлов, превышающих допустимые нормами. С удалением от проезжей части концентрации тяжелых металлов уменьшались. На основании исследований можно сделать вывод о том,что материалы, применявшиеся для уменьшения пыльности дорог, большого влияния на распространениетяжелых металлов в почве обочин дорог не оказывают. На распространение тяжелых металлов в почве обочин оказывает влияние интенсивность транспортного потока, кюветы на обочинах и условия рельефа.


Baltica ◽  
2019 ◽  
Vol 32 (1) ◽  
pp. 51-62
Author(s):  
Alexander Krek ◽  
Aleksandr Danchenkov ◽  
Marina Ulyanova ◽  
Darya Ryabchuk

The scope of the study was to assess the impact of potential sources of Cu, Zn, Co, Ni, and Cr on bottom sediments of the Russian sector of the south-eastern Baltic Sea. A total of 68 samples were taken and analyzed for grain-size (laser diffraction and sieve method) and heavy metal concentration (atomic absorption spectroscopy method). To avoid the influence of the sorption capacity of the fine-grained sediments to accumulate the pollutants, the normalization of the heavy metal concentration to Fe was applied. The environmental indices (contamination factor and modified degree of contamination) were calculated. The research has shown the contribution of oil platform, pipelines, ports and wastewater treatment facilities on the geochemical composition of bottom sediments. The authors have identified the level of heavy metals contamination of the middle parts of the Curonian and Vistula spits as a result of alongshore transport of pollutants.


Author(s):  
Ngo The Cuong ◽  
Tran Hoan Quoc ◽  
Svetlana Vasilievna Zolotokopova

The article focuses on the study of change of containing heavy metals (zinc, copper, iron, cadmium, lead, arsenic) in the abiotic and biotic components of the Serepok river (Vietman) influenced by wastewater discharge from industrial areas. Heavy metal content was determined in the river water and bottom sediments in the four zones: above and within the boundaries of industrial regions Xoa Phu and Tam Thang and in two water reservoirs situated below the boundaries of those industrial areas. Tilapia Galilean ( Sarotherodon galilaeus ), Hemibagrus ( Hemibagrus ), and sazan ( Cyprinus carpio ) caught in these areas were the hydrobionts under study in which liver, gills, skeleton and muscles accumulation of heavy metals was detected. In the organs of fish caught in the river within industrial region, heavy metals concentration was 3-7 times higher. The greatest concentration of heavy metals was found in the liver and gills of fish caught in the boundaries of industrial regions, the least concentration was in the muscles. In most cases, significant correlation between heavy metal concentration in organs of fishes and in river water, bottom sediments has been revealed.


Author(s):  
MdDidarul Islam, Ashiqur Rahaman, Aboni Afrose

This study was based on determining concentration of essential and toxic heavy metal in coconut water available at a local Hazaribagh area in Dhaka, Bangladesh. All essential minerals, if present in the drinking water at high concentration or very low concentration, it has negative actions. In this study, fifteen samples and eight heavy metals were analyzed by Atomic Absorption Spectroscopy (AAS) method which was followed by wet ashing digestion method. The concentration obtained in mg/l were in the range of 0.3 to 1.5, 7.77 to 21.2, 0 to 0.71, 0 to 0.9, 0 to 0.2, 0.9 to 17.3, 0.1 to 0.9, 0 to 0.9 and 0 to 0.7 for Fe, Ni, Cu, Cd, Cr, Zn, Pb and Se respectively. From this data it was concluded that any toxic heavy metals like Cd, Cr, Pb and Ni exceed their toxicity level and some essential nutrients were in low concentration in those samples. 


2018 ◽  
Vol 69 (7) ◽  
pp. 1695-1698
Author(s):  
Marin Rusanescu ◽  
Carmen Otilia Rusanescu ◽  
Gheorghe Voicu ◽  
Mihaela Begea

A calcium bentonite from Orasu Nou deposit (Satu Mare Romania) was used as raw material. We have conducted laboratory experiments to determine the influence of bentonite on the degree of heavy metal retention. It has been observed that the rate of retention increases as the heavy metal concentration decreases. Experimental studies have been carried out on metal retention ( Zn) in bentonite. In this paper, we realized laboratory experiments for determining the influence of metal (Zn) on the growth and development of two types of plants (Pelargonium domesticum and Kalanchoe) and the effect of bentonite on the absorption of pollutants. These flowers were planted in unpolluted soil, in heavy metal polluted soil and in heavy metal polluted soil to which bentonite was added to observe the positive effect of bentonite. It has been noticed that the flowers planted in unpolluted soil and polluted with heavy metals to which bentonite has been added, the flowers have flourished, the leaves are still green and the plants whose soils have been polluted with heavy metals began to dry after 6 days, three weeks have yellowish leaves and flowers have dried. Experiments have demonstrated the essential role of bentonite for the removal of heavy metals polluted soil.


2016 ◽  
Vol 5 (10) ◽  
pp. 4933
Author(s):  
Sabia Sultana ◽  
A. K. M. Nur Alam Siddiki ◽  
Md. Rokonujjaman ◽  
M. Niamul Naser ◽  
Abdus Salam ◽  
...  

The heavy metal concentration (e.g., Mn, Zn, Pb and Ni) were determined in soft tissues and shells of freshwater mussels (Lamellidens marginalis) at the various sites of Dhanmondi lake, Dhaka, Bangladesh between the period April, 2010 and March 2011. The heavy metal concentrations in shells and soft tissues of freshwater mussels were tended to vary significantly among sampling points and seasons in Dhanmondi Lake. Distribution of heavy metals in shell and soft tissue of Lamellidens marginalis followed the order Mn>Zn>Pb>Ni, respectively. According to the t-test, level of manganese, zinc and lead under investigation between shell and tissue showed statistically significant differences [Mn: t=-11.387; df=16; P=0.000; Zn: t=-2.590; df=16; P=0.020 and Pb: t=-2.8679; df=16; P=0.011].


2021 ◽  
Vol 11 (15) ◽  
pp. 7099
Author(s):  
Inkyeong Moon ◽  
Honghyun Kim ◽  
Sangjo Jeong ◽  
Hyungjin Choi ◽  
Jungtae Park ◽  
...  

In this study, the geochemical properties of heavy metal-contaminated soils from a Korean military shooting range were analyzed. The chemical behavior of heavy metals was determined by analyzing the soil pH, heavy metal concentration, mineral composition, and Pb isotopes. In total, 24 soil samples were collected from a Korean military shooting range. The soil samples consist of quartz, albite, microcline, muscovite/illite, kaolinite, chlorite, and calcite. Lead minerals, such as hydrocerussite and anglesite, which are indicative of a transformation into secondary mineral phases, were not observed. All soils were strongly contaminated with Pb with minor concentrations of Cu, Ni, Cd, and Zn. Arsenic was rarely detected. The obtained results are indicated that the soils from the shooting range are contaminated with heavy metals and have evidences of different degree of anthropogenic Pb sources. This study is crucial for the evaluation of heavy metal-contaminated soils in shooting ranges and their environmental effect as well as for the establishment of management strategies for the mitigation of environmental risks.


Foods ◽  
2021 ◽  
Vol 10 (6) ◽  
pp. 1310
Author(s):  
Matúš Várady ◽  
Sylwester Ślusarczyk ◽  
Jana Boržíkova ◽  
Katarína Hanková ◽  
Michaela Vieriková ◽  
...  

The aim of this study was to determine the effect of roasting on the contents of polyphenols (PPH), acrylamide (AA), and caffeine (CAF) and to analyze heavy metals in specialty coffee beans from Colombia (COL) and Nicaragua (NIC). Samples of NIC were naturally processed and COL was fermented anaerobically. Green beans from COL (COL-GR) and NIC (NIC-GR) were roasted at two levels, light roasting (COL-LIGHT and NIC-LIGHT) and darker roasting (COL-DARK and NIC-DARK), at final temperatures of 210 °C (10 min) and 215 °C (12 min), respectively. Quantitative analyses of PPH identified caffeoylquinic acids (CQA), feruloylquinic acids, and dicaffeoylquinic acids. Isomer 5-CQA was present at the highest levels and reached 60.8 and 57.7% in COL-GR and NIC-GR, 23.4 and 29.3% in COL-LIGHT and NIC-LIGHT, and 18 and 24.2% in COL-DARK and NIC-DARK, respectively, of the total PPH. The total PPH contents were highest in COL-GR (59.76 mg/g dry matter, DM). Roasting affected the contents of PPH, CAF, and AA (p < 0.001, p < 0.011 and p < 0.001, respectively). Nickel and cadmium contents were significantly higher in the COL-GR than in the NIC-GR beans. Darker roasting decreased AA content, but light roasting maintained similar amounts of CAF and total PPH.


Author(s):  
Pedro Alexandre Sodrzeieski ◽  
Leonardo Capeleto de Andrade ◽  
Tales Tiecher ◽  
Flávio Anastácio de Oliveira Camargo

Dilúvio Stream flows through an area with a great population density in Porto Alegre, Southern Brazil. The anthropogenic influence in the surroundings impacted negatively the quality of the sediments of Dilúvio Stream and Lake Guaíba. This study evaluated the physico-chemical variability of surface sediments in a non-channeled section of Dilúvio Stream. Additionally, we compared the concentration of several heavy metals in this section with data from previous studies in the margins of Lake Guaíba near the outflow of Dilúvio Stream in order to evaluate the impact of urbanization on sediment pollution. The pH, bulk density, particle-size distribution, electrical conductivity, organic carbon, assimilable phosphorus, total nitrogen, mineralogical composition (X-ray diffractogram) and pseudo total concentration of several metals (Fe, Al, Ca, Mg, Na, K, Mn, Ba, Zn, V, As, Pb, Cu, Cr, Co, Ni, Cd, Mo, and Se) were evaluated. The results showed that the sediments in the non-channeled section of Dilúvio Stream are predominantly sandy, with heavy metal contents below the quality reference values. Quartz and feldspar predominated in all sites. The concentration of Zn, Pb, Cu, Cr, and Ni were lower than that observed in the margins of Lake Guaíba near the outflow of Dilúvio Stream, possibly due to pollution input throughout the channeled section. The Dilúvio Stream shows indications of an anthropogenic influence in the heavy metals concentration through the channeled area.


Cosmetics ◽  
2020 ◽  
Vol 7 (4) ◽  
pp. 78
Author(s):  
Claire Tubia ◽  
Alfonso Fernández-Botello ◽  
Jan Dupont ◽  
Eni Gómez ◽  
Jérôme Desroches ◽  
...  

As an external appendage, hair is exposed to multiple stresses of different origins such as particles and gases in air, or heavy metals and chemicals in water. So far, little research has addressed the impact of water pollution on hair. The present study describes a new ex vivo model that allowed us to document the adverse effects of water pollutants on the structure of hair proteins, as well as the protective potential of active cosmetic ingredients derived from a biomimetic exopolysaccharide (EPS). The impact of water pollution was evaluated on hair from a Caucasian donor repeatedly immersed in heavy metal-containing water. Heavy metal retention in and on hair was then quantified using Inductively Coupled Plasma Spectrometry (ICP/MS). The adverse effects of heavy metals on the internal structure of hair and its prevention by the EPS were assessed through measurement of keratin birefringence. Notably, the method allows the monitoring of the organization of keratin fibers and therefore the initial change on it in order to modulate the global damage in the hair. Results revealed an increasing amount of lead, cadmium and copper, following multiple exposures to polluted water. In parallel, the structure of keratin was also altered with exposures. However, heavy metal-induced keratin fiber damage could be prevented in the presence of the tested EPS, avoiding more drastic hair problems, such as lack of shine, or decrease in strength, due to damage accumulation.


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