scholarly journals A New Constructive Method for Solving the Schrödinger Equation

Symmetry ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1879
Author(s):  
Kazimierz Rajchel

In this paper, a new method for the exact solution of the stationary, one-dimensional Schrödinger equation is proposed. Application of the method leads to a three-parametric family of exact solutions, previously known only in the limiting cases. The method is based on solutions of the Ricatti equation in the form of a quadratic function with three parameters. The logarithmic derivative of the wave function transforms the Schrödinger equation to the Ricatti equation with arbitrary potential. The Ricatti equation is solved by exploiting the particular symmetry, where a family of discrete transformations preserves the original form of the equation. The method is applied to a one-dimensional Schrödinger equation with a bound states spectrum. By extending the results of the Ricatti equation to the Schrödinger equation the three-parametric solutions for wave functions and energy spectrum are obtained. This three-parametric family of exact solutions is defined on compact support, as well as on the whole real axis in the limiting case, and corresponds to a uniquely defined form of potential. Celebrated exactly solvable cases of special potentials like harmonic oscillator potential, Coulomb potential, infinite square well potential with corresponding energy spectrum and wave functions follow from the general form by appropriate selection of parameters values. The first two of these potentials with corresponding solutions, which are defined on the whole axis and half axis respectively, are achieved by taking the limit of general three-parametric solutions, where one of the parameters approaches a certain, well-defined value.

Author(s):  
Frank S. Levin

Chapter 7 illustrates the results obtained by applying the Schrödinger equation to a simple pedagogical quantum system, the particle in a one-dimensional box. The wave functions are seen to be sine waves; their wavelengths are evaluated and used to calculate the quantized energies via the de Broglie relation. An energy-level diagram of some of the energies is constructed; on it are illustrations of the corresponding wave functions and probability distributions. The wave functions are seen to be either symmetric or antisymmetric about the midpoint of the line representing the box, thereby providing a lead-in to the later exploration of certain symmetry properties of multi-electron atoms. It is next pointed out that the Schrödinger equation for this system is identical to Newton’s equation describing the vibrations of a stretched musical string. The different meaning of the two solutions is discussed, as is the concept and structure of linear superpositions of them.


2012 ◽  
Vol 27 (20) ◽  
pp. 1250112 ◽  
Author(s):  
DAVIDS AGBOOLA ◽  
YAO-ZHONG ZHANG

We present exact solutions of the Schrödinger equation with spherically symmetric octic potential. We give closed-form expressions for the energies and the wave functions as well as the allowed values of the potential parameters in terms of a set of algebraic equations.


Open Physics ◽  
2014 ◽  
Vol 12 (10) ◽  
Author(s):  
Vladimír Tichý ◽  
Lubomír Skála ◽  
René Hudec

AbstractThis paper presents a direct algebraic method of searching for analytic solutions of the two-dimensional time-independent Schrödinger equation that is impossible to separate into two one-dimensional ones. As examples, two-dimensional polynomial and Morse-like potentials are discussed. Analytic formulas for the ground state wave functions and the corresponding energies are presented. These results cannot be obtained by another known method.


2019 ◽  
Vol 34 (14) ◽  
pp. 1950107 ◽  
Author(s):  
V. H. Badalov ◽  
B. Baris ◽  
K. Uzun

The formal framework for quantum mechanics is an infinite number of dimensional space. Hereby, in any analytical calculation of the quantum system, the energy eigenvalues and corresponding wave functions can be represented easily in a finite-dimensional basis set. In this work, the approximate analytical solutions of the hyper-radial Schrödinger equation are obtained for the generalized Wood–Saxon potential by implementing the Pekeris approximation to surmount the centrifugal term. The energy eigenvalues and corresponding hyper-radial wave functions are derived for any angular momentum case by means of state-of-the-art Nikiforov–Uvarov and supersymmetric quantum mechanics methods. Hence, the same expressions are obtained for the energy eigenvalues, and the expression of hyper-radial wave functions transforming each other is shown owing to these methods. Furthermore, a finite number energy spectrum depending on the depths of the potential well [Formula: see text] and [Formula: see text], the radial [Formula: see text] and [Formula: see text] orbital quantum numbers and parameters [Formula: see text], [Formula: see text], [Formula: see text] are also identified in detail. Next, the bound state energies and corresponding normalized hyper-radial wave functions for the neutron system of the [Formula: see text]Fe nucleus are calculated in [Formula: see text] and [Formula: see text] as well as the energy spectrum expressions of other higher dimensions are revealed by using the energy spectrum of [Formula: see text] and [Formula: see text].


2021 ◽  
pp. 2150206
Author(s):  
E. I. Jafarov ◽  
S. M. Nagiyev

In this paper, exactly solvable model of the quantum harmonic oscillator is proposed. Wave functions of the stationary states and energy spectrum of the model are obtained through the solution of the corresponding Schrödinger equation with the assumption that the mass of the quantum oscillator system varies with position. We have shown that the solution of the Schrödinger equation in terms of the wave functions of the stationary states is expressed by the pseudo Jacobi polynomials and the mass varying with position depends from the positive integer [Formula: see text]. As a consequence of the positive integer [Formula: see text], energy spectrum is not only non-equidistant, but also there are only a finite number of energy levels. Under the limit, when [Formula: see text], the dependence of effective mass from the position disappears and the system recovers known non-relativistic quantum harmonic oscillator in the canonical approach where wave functions are expressed by the Hermite polynomials.


2019 ◽  
Vol 34 (23) ◽  
pp. 1950183 ◽  
Author(s):  
S. Sargolzaeipor ◽  
H. Hassanabadi ◽  
W. S. Chung

In this paper, we solved the Schrödinger equation in the commutative and non-commutative (NC) spaces under the presence of magnetic field. In other words, we obtained the energy spectrum and wave functions in terms of Heun functions. When we considered the case [Formula: see text], we observed that the NC space converts to the commutative space.


2015 ◽  
Vol 58 (1) ◽  
pp. 1-6
Author(s):  
Theodor-Felix Iacob ◽  
Marina Lute ◽  
Felix Iacob

Abstract The Schrödinger equation with pseudo-Gaussian potential is investigated. The pseudo-Gaussian potential can be written as an infinite power series. Technically, by an ansatz to the wave-functions, exact solutions can be found by analytic approach [12]. However, to calculate the solutions for each state, a condition that will stop the series has to be introduced. In this way the calculated energy values may suffer modifications by imposing the convergence of series. Our presentation, based on numerical methods, is to compare the results with those obtained in the analytic case and to determine if the results are stable under different stopping conditions.


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