Multiphase Phase-Field Lattice Boltzmann Method for Simulation of Soluble Surfactants

This paper proposes a phase-field model for the lattice Boltzmann method which has discretized symmetrical directions of velocities in a cartesian grid, to simulate the soluble surfactant in a Multicomponent multiphase system. Despite other existing phase-field models following Langmuir relation, the interfacial tension can be calculated analytically in this proposed model. Parameters playing roles in the models and controlling the surfactant’s strength and interaction with other phases are obtained directly from a given initial interfacial tension and bulk surfactant. Consequently, there is no further need for trial-and-error simulations, and a real system, e.g., oil-water-surfactant, can be simulated with given initial parameters. The model is validated with the analytical result for a planar oil–water-surfactant system. Furthermore, the method for reobtaining numerical interfacial tension for five different cases is tested and compared with the given initial values for an oil droplet surrounded by water and surfactant. The results show that the obtained interfacial tension from the method is in good agreement with the given initial interfacial tension. Furthermore, the spurious velocity of the model is calculated and seen that the magnitude of spurious velocities is proportional to interfacial tension.