scholarly journals Preliminary Evaluation of Heavy Metal Contamination and Source Identification in Kuala Lumpur SMART Stormwater Pond Sediments Using Pb Isotopic Signature

2021 ◽  
Vol 13 (16) ◽  
pp. 9020
Author(s):  
Nabeel Abdullah Alrabie ◽  
Ferdaus Mohamat-Yusuff ◽  
Rohasliney Hashim ◽  
Zufarzaana Zulkeflee ◽  
Mohammad Noor Azmai Amal ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Coal Combustion ◽  
Inductively Coupled Plasma ◽  
Heavy Metal Contamination ◽  
Isotope Ratios ◽  
Isotopic Signature ◽  
Preliminary Evaluation ◽  
Kuala Lumpur ◽  
Pb Isotope ◽  
Urban Stormwater

Uncontrolled urbanization and growing industrialization are major sources of pollutants that affect the urban stormwater quality and, therefore, the receiving aquatic environment. The concentrations of heavy metals (As, Cd, Cr, Cu, Fe, Ni, Pb, and Zn), and Pb isotope ratios in surface sediment samples obtained from SMART holding and storage ponds located in Kuala Lumpur were investigated using inductively coupled plasma-mass spectrometry (ICP-MS). The highest metal concentrations were found at the SMART holding pond (SHP), the first recipient of urban stormwater runoff from the SMART system catchment area. As, Cd, Pb, and Zn are the dominant metal contaminants in the sediments of both SMART ponds, with values exceeding the average shale values. According to contamination indices applied to evaluate the environmental risk caused by heavy metals, As had the highest values among the metals examined, denoting moderate contamination. Hence, it can frequently cause harmful effects on the sediment-living species. The Pb isotope ratios (206Pb/207Pb and 208Pb/207Pb) indicated that coal combustion was the foremost source of anthropogenic Pb in the sediments of both SMART ponds. The control of coal combustion and sites undergoing intensive human activities should be given priority in the foreseeable future.

scholarly journals Determination of heavy metals and selenium content in chicken liver at Erbil city, Iraq

2020 ◽  
Vol 9 (3) ◽  
Author(s):  
Hoshyar Saadi Ali ◽  
Dhary Alewy Almashhadany ◽  
Hawraz Sami Khalid
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Inductively Coupled Plasma ◽  
Heavy Metal Contamination ◽  
Optical Emission ◽  
Critical Issue ◽  
Chicken Liver ◽  
Poultry Meat ◽  
Emission Spectrometry ◽  
Toxic Heavy Metals

Heavy metal contamination of poultry meat is a critical issue for human health due to associated risks of cytotoxicity and systemic pathologies after ingestion of such metals. A total of twenty chicken liver samples were collected from markets of Erbil city and analyzed for ten heavy metals contents by Inductively Coupled Plasma Optical Emission Spectrometry. The targeted metals were cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), manganese (Mn), nickel (Ni), lead (Pb), mercury (Hg), zinc (Zn) and selenium (Se). The average concentrations (mg/kg) of targeted trace elements were 0.06±0.027, 0.06±0.05, 2.05±0.34, 1.85±0.47, 0.15±0.17, and 33.53±5.24 for Co, Cr, Cu, Mn, Ni, and Zn respectively. Copper (Cu) levels significantly exceeded the maximum permissible limit of WHO. Moreover, the average concentrations of toxic heavy metals and selenium were 0.07±0.037, 0.278±0.10, 0.11±0.083, and 2.01±0.454 mg/kg for Cd, Pb, Hg, and Se respectively. Hg and Pb levels exceeded the permissible limits of WHO. Higher levels of Cu and Hg in poultry may pose a serious threat to consumers which demand countermeasures and precautions to be taken. Iraqi Standards Authority and relevant official institutions are strongly recommended to regulate safe disposal of heavy metal waste in the environment to reduce animal exposure to such metals.

scholarly journals Heavy metal contamination and ecological risk assessment of the agricultural soil in Shanxi Province, China

2020 ◽  
Vol 7 (10) ◽  
pp. 200538
Author(s):  
Hongxue Qi ◽  
Bingqing Zhao ◽  
Lihong Li ◽  
Xiuling Chen ◽  
Jing An ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Ecological Risk ◽  
Inductively Coupled Plasma ◽  
Agricultural Soil ◽  
Heavy Metal Contamination ◽  
Microwave Digestion ◽  
Risk Index ◽  
Shanxi Province ◽  
Ecological Risks ◽  
Geo Accumulation

To assess contamination levels and ecological risks of heavy metals in agricultural soil from Shanxi Province of China, a total of 33 samples in the surface soil were collected from 11 cities in Shanxi. The soil samples were digested by a mixed acid of nitric acid and hydrofluoric acid on a microwave digestion system, then the levels of eight heavy metals were analysed using an inductively coupled plasma mass spectrometer. The pollution levels of soil heavy metals were evaluated using a geo-accumulation index and their ecological risks were assessed using risk index calculated by Hakanson's method. As a result, the average concentrations of the heavy metals As, Cd, Cr, Cu, Hg, Ni, Pb and Zn were 12.9 ± 4.8, 0.35 ± 0.23, 43 ± 14, 27 ± 19, 0.25 ± 0.14, 21.7 ± 5.7, 17 ± 13 and 89 ± 53 mg kg −1 , respectively. By comparison to the Chinese soil environmental quality (GB15618-2018), only 9% of Cd samples and 3% of Cu samples exceeded their corresponding screening criteria. Subsequently, the results of geo-accumulation indices suggested that Shanxi's soil suffered from moderate to heavy contamination posed by Cd and Hg, and risk indices exhibited a similar trend that Cd and Hg were the main contributors for considerable to very high ecological risk. Finally, the analysis of variance indicated that the mean levels of Cd significantly occurred at Yuncheng areas among the 11 cities ( n = 3, p < 0.05), but Hg concentrations did not have significantly statistical differences. This study demonstrated that metals Cd and Hg had higher levels and ecological risks for agricultural soil in Shanxi, especially, Yuncheng City suffered from heavy Cd contamination. The findings of the present study will provide basic information on management and control of the agricultural soil contamination in Shanxi Province, China.

scholarly journals Heavy Metal Contamination in Drinking Water Supplies in the Villages of Divandarreh: The Use of Geographic Information System

2020 ◽  
Vol 7 (2) ◽  
pp. 86-91
Author(s):  
Esmaeil Ghahramani ◽  
Ramin Khoshniyat ◽  
Sonia Chavoshi ◽  
Farhad Ahmadi Kani Golzar
Keyword(s):  
Heavy Metals ◽  
Drinking Water ◽  
Rural Areas ◽  
Inductively Coupled Plasma ◽  
Heavy Metal Contamination ◽  
Grab Sampling ◽  
Inductively Coupled ◽  
Iron And Zinc ◽  
Dry Seasons ◽  
Two Phases

One of the important aspects of drinking water pollution is the presence of heavy metals that can create hazards for consumer’s health. This study was performed to find the concentration of heavy metals (arsenic, lead, iron, and zinc) in drinking water sources of Divandarreh in Kurdistan province and prepare its zoning map. A total of 99 wells, springs, and reservoirs were selected for sampling in 78 rural areas of Divandarreh County. Samples were collected from each source using grab sampling methods in two phases (rainy and dry seasons). To find the concentration of lead, the atomic absorption device (VARIAN 240 AA) was used, and Inductively Coupled Plasma (ICP: VARIAN 710) was used for determining the concentration of arsenic, iron, and zinc. Analysis of data was done using SPSS version 22.0 and the analysis of spatial variability and estimation of the concentration of heavy metals (preparation of zoning map) in the study area were carried out by ArcGIS software. The average concentrations of arsenic, lead, iron, and zinc in dry and rainy seasons were 1, 0.6, 62.9, 31.4, and 0.13, 2.16, 11.5, 19.8, respectively. Zinc, iron, and lead concentrations in sample No. 36 were higher than the standard level; therefore, it can be inferred that these three elements can create health problems in the future.

Classification of the geographic origin of cigarettes according to Pb isotope ratios by inductively coupled plasma dynamic reaction cell mass spectrometry

2015 ◽  
Vol 30 (4) ◽  
pp. 986-993 ◽  
Author(s):  
Wei Guo ◽  
Shenghong Hu ◽  
Zhiwei Wu ◽  
Gaoyong Lan ◽  
Lanlan Jin ◽  
...  
Keyword(s):  
Inductively Coupled Plasma ◽  
Cell Mass ◽  
Geographic Origin ◽  
Isotope Ratios ◽  
Pb Isotope ◽  
Dynamic Reaction Cell ◽  
Reaction Cell ◽  
Plasma Dynamic ◽  
Inductively Coupled ◽  
Geographic Origins

ICP-DRC-MS was developed for the determination of Pb isotope ratios to distinguish between the geographic origins of cigarettes.

Pb–Zn occurrences and their Pb-isotopic signatures bearing on metallogeny and mineral exploration—Paleozoic sedimentary rocks, northern Appalachians, Quebec

1988 ◽  
Vol 25 (11) ◽  
pp. 1777-1790 ◽  
Author(s):  
K. Schrijver ◽  
E. Marcoux ◽  
G. Beaudoin ◽  
J. Y. Calvez
Keyword(s):  
Continental Crust ◽  
Mineral Exploration ◽  
Sedimentary Rocks ◽  
Isotope Ratios ◽  
Isotopic Signature ◽  
Coarse Grained ◽  
Pb Isotope ◽  
Isotopic Signatures ◽  
Fine Grained ◽  
Quartz Veins

Galena Pb-isotope ratios of epithermal vein and disseminated sulfide occurrences in the Taconian Orogen and Siluro-Devonian basin cluster around 17.90–18.05 for 206Pb/204Pb and 37.70–38.00 for 208Pb/204Pb. The major source of Pb in most, if not all, occurrences is a fairly common continental crust, a characteristic found in published analyses of Grenville feldspar Pb. A southwest to northeast increase in galena 206Pb/204Pb ratios is ascribed to the supply of several types of detritus from Grenville basement during the Cambro-Ordovician: coarse-grained, K-feldspar-bearing in the southwest, grading into fine-grained phyllitic, and relatively more highly radiogenic in the northeast.Emplacement (i) of Pb–Zn–barite veins and disseminations, commonly of homogeneous crustal Pb-isotopic signature, was late Taconian; (ii) of Pb–Zn–quartz veins, of less homogeneous signature, was post-Taconian; and (iii) of Pb–Zn–carbonate veins, relatively highly radiogenic and commonly homogeneous, was late or post-Acadian. Signatures of the first-mentioned group seem to be most useful in exploration.

scholarly journals Lead Isotopes in Exploration for Basement-Hosted Structurally Controlled Unconformity-Related Uranium Deposits: Kiggavik Project (Nunavut, Canada)

Minerals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 512
Author(s):  
David Quirt ◽  
Antonio Benedicto
Keyword(s):  
Inductively Coupled Plasma ◽  
Structural Control ◽  
Lead Isotopes ◽  
Isotope Ratios ◽  
Uranium Content ◽  
Weak Acid ◽  
Pb Isotopes ◽  
Pb Isotope ◽  
Acid Leach ◽  
Partial Digestion

Pb-isotopes have been proposed as pathfinders for sandstone-hosted unconformity-related U deposits, with isotope ratios providing information on mineralization timing and element remobilization and migration. Pb-isotopes proximal to mineralization display radiogenic signatures, often with ‘excess Pb’ suggestive of derivation from greater U concentrations than are currently present. The U deposits in the Kiggavik project area (west of Baker Lake, NU, Canada) are basement-hosted, contain several generations of pitchblende mineralization, display a strong structural control, and are located in fault-related fracture systems and foliation-parallel veinlets. Drill core samples were analysed by Inductively-Coupled Plasma-Mass Spectrometer (ICP-MS) for Pb isotopes following multi-acid total-digestion, reverse Aqua Regia partial-digestion, and weak-acid-leach attacks, to evaluate the utility of the respective dissolution methods in Pb-isotope pathfinder geochemistry. Partial-digestion results are similar to weak-acid-leach results, indicating that interpretation of Pb-isotope signatures can be carried out from partial-digestion data if weak-acid-leach data are unavailable. Application of this pathfinder method at Kiggavik shows that Pb-isotope ratios display systematic trends useful for exploration vectoring. Uranium-content-adjusted 206Pb/204Pb ratios and 206Pb/204Pb ‘excess-lead’ data highlight anomalous isotopic values. 207Pb/206Pb ratios display downhole trends complementary to location of mineralization. Three-dimensional (3D) distributions of Pb-isotope data at the Contact U prospect show systematic trends and form halos around the mineralization. Isotopic footprints are limited to <50 m from the mineralization outline, reflecting host-rock and structural control, but indicate areas with elevated potential for U mineralization and provide vectoring information within basement lithologies.

scholarly journals Assessment of Heavy Metal Contamination in Soil in and around Sohar Industrial Port Area, Oman

2019 ◽  
Vol 24 (1) ◽  
pp. 1 ◽  
Author(s):  
Maha Al-Jabri ◽  
Daniel Moraetis ◽  
Reginald Victor
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Inductively Coupled Plasma ◽  
Heavy Metal Contamination ◽  
Anthropogenic Impacts ◽  
International Standards ◽  
Anthropogenic Sources ◽  
Emission Spectrometry ◽  
High Background ◽  
Port Area

The increase in the number of heavy metal emitting sources in industrial areas is a serious issue in pollution science. Sohar Industrial Port (SIP) area is located in the northern part of Oman where different industrial activities like petrochemical production, metal processing, and waste disposal are prevalent. This study comprehensively identified the presence and quantities of heavy metals in the soils of Sohar Industrial Port area and traced their origin to geogenic or anthropogenic sources. Bulk geochemical and mineralogical analyses were carried out on all samples. Environmentally available and bioavailable heavy metals were extracted by diethylenetriaminepentaacetic acid (DTPA) and were finally analyzed using Inductively Coupled Plasma-Optical Emission spectrometry (ICP-OES). The environmentally available metals that showed higher concentrations when compared to international standards were Ni and Cd. The geochemical evidence showed a strong geochemical signature of the ophiolite rocks in the soils as indicated by the significant correlation between Cr and Ni (P< 0.05). In addition, the Cd content showed significant correlations with Ni and Cr (P< 0.05). Other metals like Pb and Zn, possibly also were geogenic in origin, but with significantly elevated concentrations in samples close to a national highway (P< 0.05). The present study demonstrated the significance of understanding the geological framework of an industrial area, which is already imposing high background concentrations of Cr, Ni and Cd, and also the possible anthropogenic impacts in the cases of Pb and Cd that exceeded internationally permissible limits.

scholarly journals Determination of Heavy Metals in Groundwater Around Al-Buraihi Sewage Station in Taiz City, Yemen

2021 ◽  
Vol 11 (30) ◽  
Author(s):  
Raya Qaid Alansi ◽  
Abdelhafeez M.A. Mohammed ◽  
Mahmoud M. Ali ◽  
Wadie Ahmed Mokbel Ghalib ◽  
Sajan Chimmikuttanda Ponnappa
Keyword(s):  
Heavy Metals ◽  
Inductively Coupled Plasma ◽  
Heavy Metal Contamination ◽  
Pearson Correlation ◽  
Optical Emission ◽  
International Standards ◽  
Emission Spectrometry ◽  
Inductively Coupled ◽  
Financial Interests ◽  
Wastewater Samples

Background. In recent years, mitigation of groundwater contamination resulting from the limited availability of freshwater for domestic use has become an important issue. The presence of heavy metals in water could have adverse effects on both plant and animal life. Objectives. The main objective of the present study was to determine possible heavy metal contamination in groundwater around Al-Buraihi sewage station in Taiz, Yemen and to understand possible sources of contamination and their relationships with groundwater. Methods. Wastewater samples were collected from a wastewater stabilization pond from Al-Buraihi sewage station and borewell water samples were collected from the vicinity. The presence of heavy metals was quantified using inductively coupled plasma-optical emission spectrometry (ICP-OES). Pearson correlation test was performed to understand the relationship between wastewater and groundwater samples. Results. Physical variables including pH, electrical conductivity (EC), dissolved oxygen (DO) and temperature and elements such as silver (Ag), arsenic (As), aluminum (Al), barium (Ba), boron (B), cadmium (Cd), chromium (Cr), iron (Fe), molybdenum, nickel (Ni), selenium (Se) and zinc (Zn) exceeded the permissible limits recommended by international standards in wastewater samples. Conclusions. Treated sewage wastewater in the study area is not suitable for irrigation as the elements/heavy metals are accumulated in soil and plants and may be accumulated in humans and animals through bio-accumulation. In addition, these heavy metals reach the water table and aquifers through percolation, thereby polluting groundwater. Competing Interests. The authors declare no competing financial interests.

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