scholarly journals Immobilization of Cd, Pb and Zn through Organic Amendments in Wastewater Irrigated Soils

2021 ◽  
Vol 13 (4) ◽  
pp. 2392
Author(s):  
Kouser Majeed Malik ◽  
Khalid Saifullah Khan ◽  
Shah Rukh ◽  
Ahmad Khan ◽  
Saba Akbar ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Wheat Straw ◽  
Microbial Activity ◽  
Toxic Metals ◽  
Contaminated Soils ◽  
Microbial Biomass Carbon ◽  
Organic Amendments ◽  
Wastewater Irrigation ◽  
Economic Losses ◽  
Irrigated Soils

Due to the scarcity of water, raw sewage effluents are often used to irrigate arable suburban soils in developing countries, which causes soil contamination with toxic metals. Soil microorganisms involved in biochemical transformations are sensitive to heavy metals contamination. The study was designed to investigate the effect of organic amendments on the microbial activity of cadmium (Cd), lead (Pb) and zinc (Zn) fractions and their bioavailability in soils contaminated with wastewater irrigation. Three metal contaminated soils under wastewater irrigation were collected, ground, sieved and added to incubation jars. Two organic amendments: wheat straw and chickpea straw, were applied (1% w/w) to the soil before incubation for 84 days at 25 °C. The CO2-C evolution after 1, 2, 3, 5, 7, 10 and 14 days was measured and thereafter was also measured weekly. Soil samples collected at 0, 14, 28, 42, 56, 70 and 84 days after incubation were analyzed for microbial biomass carbon (MBC). Sequential extraction for metal fractionation of samples was carried out collected at 0, 28, 56 and 84 days. Three soils differed significantly in evolved MBC and ∑CO2-C. Chickpea straw addition significantly increased soil MBC as compared to the wheat straw. Organic amendments significantly increased ∑CO2-C evolution from the soils, which was higher from chickpea straw. The addition of crop residues did not affect total Pb, Cd and Zn contents in soils. The concentration of exchangeable, carbonate bound and residual fractions of Pb, Cd and Zn decreased (6–27%), while the organic matter bound fraction increased (4–75%) with straw addition. Overall, the organic amendments improved microbial activity and reduce the bioavailability of toxic metals in wastewater irrigated soils. Furthermore, organic amendments not only reduce economic losses as they are cheap to produce but also minimize human health risks from heavy metals by hindering their entry into the food chain.

scholarly journals Accumulation of Potentially Toxic Metals in Egyptian Alluvial Soils, Berseem Clover (Trifolium alexandrinum L.), and Groundwater after Long-Term Wastewater Irrigation

Agriculture ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 713
Author(s):  
Ahmed S. Abuzaid ◽  
Hossam S. Jahin ◽  
Amany A. Asaad ◽  
Mohamed E. Fadl ◽  
Mohamed A. E. AbdelRahman ◽  
...  
Keyword(s):  
Toxic Metals ◽  
Translocation Factor ◽  
Wastewater Irrigation ◽  
Alluvial Soils ◽  
Trifolium Alexandrinum ◽  
Potentially Toxic Metals ◽  
Groundwater Samples ◽  
Safe Limits ◽  
Berseem Clover ◽  
Irrigated Soils

The reduced availability of water resources in Egypt has imposed the need to intensify the use of wastewater for crop irrigation in the alluvial soils of anthropogenic origin. Relevant effects can derive from contents of potentially toxic metals (PTMs) in supply resources soils, crops, and groundwater in these areas. For this reason the PTM content has to be monitored to evaluate and minimize health hazards. Therefore, in this context, two areas of the SE Nile Delta subjected to 25 year of wastewater irrigation, using agricultural drainage water (ADW) and mixed wastewater (MWW) were chosen and compared with a nearby site irrigated with Nile freshwater (NFW). At each of the three sites, ten samples of irrigation water, topsoil, berseem clover (Trifolium alexandrinum L.) plants, and seven groundwater samples were collected and analyzed for Cr, Co, Cu, Pb, Ni, and Zn. Results indicate that the total contents of Co, Cu, Ni, and Zn in soils collected from the three sampling sites and Pb in the MWW-irrigated soils were higher than their average natural contents in the earth’s crust, indicating potential risks. The DTPA-extractable contents of Cu in the three sites, in addition to Pb and Zn in the MWW-irrigated soils, exceeded the safe limits. The MWW-irrigated soils showed a considerable degree of metal contamination, while the NFW- and ADW-irrigated soils showed moderate and low levels of contamination, respectively. The contents of the six PTMs in the three sites showed low individual ecological risks, except for Pb in the MWW-irrigated soils that showed a moderate risk; however, the overall ecological risk remained low in all samples. The values of Co, Cu, and Ni in berseem shoot in addition to Pb from the MWW-irrigated soils were over the maximum permissible levels for animal feeding. Values of root-to-shoot translocation factor were lower than 1.0 for Cr, Co and Ni but higher than 1.0 for Cu, Pb, and Zn. Berssem plant is a good candidate for phytofiltration of Cr, Co and Ni, while for extracting Cu, Pb and Zn from polluted soils. The groundwater samples collected from the three sampling sites showed lower metal concentrations than the safe limits for drinking standards. Further remediation studies should be taken into account to alleviate potential environmental and health-related risks when using supply resources different from freshwater.

scholarly journals Biochar alleviates metal toxicity and improves microbial community functions in a soil co-contaminated with cadmium and lead

Biochar ◽  
2021 ◽  
Author(s):  
Nahid Azadi ◽  
Fayez Raiesi
Keyword(s):  
Heavy Metals ◽  
Low Temperature ◽  
Organic Carbon ◽  
Enzymatic Activity ◽  
Microbial Activity ◽  
Contaminated Soils ◽  
Metal Availability ◽  
Soil Microbial ◽  
Labile C ◽  
Cadmium And Lead

AbstractSoil amendment with biochar alleviates the toxic effects of heavy metals on microbial functions in single-metal contaminated soils. Yet, it is unclear how biochar application would improve microbial activity and enzymatic activity in soils co-polluted with toxic metals. The present research aimed at determining the response of microbial and biochemical attributes to addition of sugarcane bagasse biochar (SCB) in cadmium (Cd)-lead (Pb) co-contaminated soils. SCBs (400 and 600 °C) decreased the available concentrations of Cd and Pb, increased organic carbon (OC) and dissolved organic carbon (DOC) contents in soil. The decrease of metal availability was greater with 600 °C SCB than with 400 °C SCB, and metal immobilization was greater for Cd (16%) than for Pb (12%) in co-spiked soils amended with low-temperature SCB. Biochar application improved microbial activity and biomass, and enzymatic activity in the soils co-spiked with metals, but these positive impacts of SCB were less pronounced in the co-spiked soils than in the single-spiked soils. SCB decreased the adverse impacts of heavy metals on soil properties largely through the enhanced labile C for microbial assimilation and partly through the immobilization of metals. Redundancy analysis further confirmed that soil OC was overwhelmingly the dominant driver of changes in the properties and quality of contaminated soils amended with SCB. The promotion of soil microbial quality by the low-temperature SCB was greater than by high-temperature SCB, due to its higher labile C fraction. Our findings showed that SCB at lower temperatures could be applied to metal co-polluted soils to mitigate the combined effects of metal stresses on microbial and biochemical functions.

scholarly journals Bioremoval of hazardous cobalt, nickel, chromium, copper and cadmium compounds from contaminated soil by Nicotiana tabacum plants and associated microbiome

2021 ◽  
Vol 29 (2) ◽  
pp. 88-93
Author(s):  
О. A. Havryliuk ◽  
V. M. Hovorukha ◽  
A. V. Sachko ◽  
G. V. Gladka ◽  
I. O. Bida ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Nicotiana Tabacum ◽  
Toxic Metals ◽  
Contaminated Soils ◽  
Plant Material ◽  
Soil Microorganisms ◽  
Dry Weight ◽  
Plant Tissues ◽  
Natural Ecosystems ◽  
High Concentration

Contamination of soils with heavy metals leads to reduction of soil fertility, destruction of natural ecosystems and detrimental effects on the health of society by increasing content of metals in the food chains from microorganisms to plants, animals and humans. Bioremediation is one of the most promising and cost-effective methods of cleaning soils polluted with toxic metals. According to current researchers, microorganisms and plants have the genetic potential to remove toxic metals from contaminated sites. The method of thermodynamic prediction was used to theoretically substantiate the mechanisms of interaction of soil microorganisms and plants with heavy metals. According to the our prediction, exometabolite chelators of anaerobic microorganisms may increase the mobility of metals and thereby contribute to the active transport of metals and their accumulation in plants. Plants of Nicotiana tabacum L. of Djubek cultivar were used as plant material for the current investigation. The examined toxicants were heavy metals, namely cobalt (II), nickel (II), chromium (VI), copper (II) and cadmium (II). The aqueous solutions of metal salts were added to the boxes after two months of plants growing to the final super-high concentration – 500 mg/kg of absolutely dry weight of soil. Quantitative assessments of copper and chromium-resistant microorganisms were made by cultivation on agar nutrient medium NA with a gradient of Cu(II) and Cr(VI). The concentration of metals in soil and plant material (leaves, stems and roots) was determined by atomic absorption method. The study revealed that heavy metals inhibited the growth of the examined tobacco plants. This was expressed by the necrosis of plant tissues and, ultimately, their complete death. Despite this, all investigated heavy metals were accumulated in plant tissues during 3–7 days before death of plants. The uptake of metals was observed in all parts of plants – leaves, stems and roots. The highest concentrations of Co(II), Ni(II), Cd(II), Cr(VI) were found in the leaves, Cu(II) – in the roots. The results show that the bioremoval efficiency of the investigated metals ranged 0.60–3.65%. Given the super-high initial concentration of each of the metals (500 mg/kg), the determined removal efficiency was also high. Cadmium was the most toxic to plants. Thus, the basic points of the thermodynamic prognosis of the possibility of accumulation of heavy metals by phytomicrobial consortium were experimentally confirmed on the example of N. tabacum plants and metal-resistant microorganisms. The study demonstrated that despite the high initial metals concentration, rate of damage and death of plants, metals are accumulated inplant tissues in extremely hight concentrations. Soil microorganisms were observed to have high adaptation potencial to Cu(II) and Cr(VI). In anaerobic conditions, microorganisms presumably mobilize heavy metals, which later are absorbed by plants. The obtained results are the basis for the development of environmental biotechnologies for cleaning contaminated soils from heavy metal compounds.

Microbial activity and diversity in long-term mixed contaminated soils with respect to polyaromatic hydrocarbons and heavy metals

2012 ◽  
Vol 99 ◽  
pp. 10-17 ◽  
Author(s):  
Palanisami Thavamani ◽  
Seidu Malik ◽  
Michael Beer ◽  
Mallavarapu Megharaj ◽  
Ravi Naidu
Keyword(s):  
Heavy Metals ◽  
Microbial Activity ◽  
Contaminated Soils ◽  
Polyaromatic Hydrocarbons

scholarly journals Heavy metals immobilization and improvement in maize (Zea mays L.) growth amended with biochar and compost

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Muhammad Irfan ◽  
Muhammad Mudassir ◽  
Muhammad Jamal Khan ◽  
Khadim Muhammad Dawar ◽  
Dost Muhammad ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Contaminated Soils ◽  
Low Cost ◽  
Soil Health ◽  
Organic Amendments ◽  
Available Phosphorus ◽  
Root Weight ◽  
Maximum Increase ◽  
Chlorophyll Contents ◽  
Cr Concentration

AbstractSoil with heavy metals contamination, mainly lead (Pb), cadmium (Cd), and chromium (Cr) is a progressively worldwide alarming environmental problem. Recently, biochar has been used as a soil amendment to remediate contaminated soils, but little work has been done to compare with other organic amendments like compost. We investigated biochar and compost's comparative effect on Pb, Cd, and Cr immobilization in soil, photosynthesis, and growth of maize plants. Ten kg soil was placed in pots and were spiked with Pb, Cd, and Cr at concentrations 20, 10, 20 mg kg−1. The biochar and compost treatments included 0, 0.5, 1, 2, and 4% were separately applied to the soil. The crop from pots was harvested after 60 days. The results show that the highest reduction of AB-DTPA extractable Pb, Cd, and Cr in soil was 79%, 61% and 78% with 4% biochar, followed by 61%, 43% and 60% with 4% compost compared to the control, respectively. Similarly, the highest reduction in shoot Pb, Cd, and Cr concentration was 71%, 63% and 78%with 4% biochar, followed by 50%, 50% and 71% with 4% compost than the control, respectively. The maximum increase in shoot and dry root weight, total chlorophyll contents, and gas exchange characteristics were recorded with 4% biochar, followed by 4% compost than the control. The maximum increase in soil organic matter and total nitrogen (N) was recorded at 4% biochar application while available phosphorus and potassium in the soil at 4% compost application. It is concluded that both biochar and compost decreased heavy metals availability in the soil, reducing toxicity in the plant. However, biochar was most effective in reducing heavy metals content in soil and plant compared to compost. In the future, more low-cost, eco-friendly soil remediation methods should be developed for better soil health and plant productivity.

scholarly journals Efficiency of Wheat Straw Biochar in Combination with Compost and Biogas Slurry for Enhancing Nutritional Status and Productivity of Soil and Plant

Plants ◽  
2020 ◽  
Vol 9 (11) ◽  
pp. 1516
Author(s):  
Aown Abbas ◽  
Muhammad Naveed ◽  
Muhammad Azeem ◽  
Muhammad Yaseen ◽  
Rehmat Ullah ◽  
...  
Keyword(s):  
Nutritional Status ◽  
Wheat Straw ◽  
Microbial Biomass Carbon ◽  
Block Design ◽  
Organic Amendments ◽  
Cost Effective ◽  
Biogas Slurry ◽  
Growth Physiology ◽  
Combined Use ◽  
The Impact

In the present study, we investigated the impact of different combinations of wheat straw biochar, compost and biogas slurry on maize growth, physiology, and nutritional status in less productive soils. The experiment was performed as a completely randomized block design in a greenhouse pot experiment. The compost and biogas slurry were applied with and without biochar. The results revealed that a combination of biochar, compost, and biogas slurry enhanced the cation exchange capacity (31%), carbon (83%), phosphorus (67%) and potassium (81%) contents in the soil. Likewise, a significant increase in soil microbial biomass carbon (15%) and nitrogen (37%) was noticed with the combined use of all organic amendments. Moreover, the combined application of biochar, compost and biogas slurry enhanced soil urease and β-glucosidase activity up to 96% and 67% over control respectively. In addition, plant height, chlorophyll content, water use efficiency and 1000-grain weight were also enhanced up to 54%, 90%, 53% and 21% respectively, with the combined use of all amendments. Here, biochar addition helped to reduce the nutrient losses of compost and biogas slurry as well. It is concluded that biochar application in combination with compost and biogas slurry could be a more sustainable, environment-friendly and cost-effective approach, particularly for less fertile soils.

scholarly journals Phytoremediation of Heavy Metal-Contaminated Soil by Switchgrass: A Comparative Study Utilizing Different Composts and Coir Fiber on Pollution Remediation, Plant Productivity, and Nutrient Leaching

2019 ◽  
Vol 16 (7) ◽  
pp. 1261 ◽  
Author(s):  
Paliza Shrestha ◽  
Korkmaz Bellitürk ◽  
Josef Görres
Keyword(s):  
Heavy Metals ◽  
Water Quality ◽  
Heavy Metal ◽  
Contaminated Soils ◽  
Organic Amendments ◽  
Plant Productivity ◽  
Nutrient Leaching ◽  
Control Treatment ◽  
Coir Fiber ◽  
Trade Offs

We investigated the effects of organic amendments (thermophilic compost, vermicompost, and coconut coir) on the bioavailability of trace heavy metals of Zn, Cd, Pb, Co, and Ni from heavy metal-spiked soils under laboratory conditions. To test switchgrass (Panicum virgatum) as a potential crop for phytoremediation of heavy metal from soil, we investigated whether the addition of organic amendments promoted switchgrass growth, and consequently, uptake of metals. Compost is a valuable soil amendment that supplies nutrients for plant establishment and growth, which is beneficial for phytoremediation. However, excess application of compost can result in nutrient leaching, which has adverse effects on water quality. We tested the nutrient leaching potential of the different organic amendments to identify trade-offs between phytoremediation and water quality. Results showed that the amendments decreased the amount of bioavailable metals in the soils. Organic amendments increased soil pH, electrical conductivity (EC), and soil nutrient status. Switchgrass shoot and root biomass was significantly greater in the amended soils compared to the non-amended control. Amended treatments showed detectable levels of heavy metal uptake in switchgrass shoots, while the control treatment did not produce enough switchgrass biomass to measure uptake. Switchgrass uptake of certain heavy metals, and concentrations of some leachate nutrients significantly differed among the amended treatments. By improving soil properties and plant productivity and reducing heavy metal solubility that can otherwise hamper plant survival, organic amendments can greatly enhance phytoremediation in heavy metal-contaminated soils.

scholarly journals Phytoremediation of Heavy Metals from Water of Yamuna River by Tagetes patula, Bassica scoparia, Portulaca grandiflora

2019 ◽  
pp. 1-14 ◽  
Author(s):  
Arpita Ghosh ◽  
Nikita Manchanda
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Toxic Metals ◽  
Contaminated Soils ◽  
Metal Contamination ◽  
Heavy Metal Contamination ◽  
Metal Removal ◽  
Tagetes Patula ◽  
Yamuna River ◽  
Portulaca Grandiflora

Heavy metal contamination is a worldwide problem, causing many serious diseases and the levels of contamination varied from place to place. Heavy metals like cadmium (Cd), mercury (Hg), zinc (Zn), chromium (Cr), and lead (Pb) etc. are very injurious even at low concentration and are present in Yamuna river water. Phytoremediation has great potential as an efficient cleanup technology for contaminated soils, groundwater, and wastewater. It is a cheap and very efficient technique for metal removal. A study had been carried out to detect the efficiency of phytoremediation technique for removal of heavy toxic metals from water of Yamuna river. This study also focused on the phytoremediation capacity of all of three selected plants: Tagetes patula, Bassica scoparia, and Portulaca grandiflora. Bioaccumulation of heavy metals in various parts of plants has also been checked.

Study of the Cu(II) removal from aqueous solutions by adsorption on titania

2013 ◽  
Vol 12 (3) ◽  
pp. 239-247
Keyword(s):  
Heavy Metals ◽  
Ionic Strength ◽  
Toxic Metals ◽  
Low Cost ◽  
Lateral Interaction ◽  
Tio2 Surface ◽  
High Toxicity ◽  
Removal Of Heavy Metals ◽  
Solution Parameters ◽  
Kinetics Of

The removal of heavy metals from wastewaters is a matter of paramount importance due to the fact that their high toxicity causes major environmental pollution problems. One of the most efficient, applicable and low cost methods for the removal of toxic metals from aqueous solutions is that of their adsorption on an inorganic adsorbent. In order to achieve high efficiency, it is important to understand the influence of the solution parameters on the extent of the adsorption, as well as the kinetics of the adsorption. In the present work, the adsorption of Cu(II) species onto TiO2 surface was studied. It was found that the adsorption is a rapid process and it is not affected by the value of ionic strength. In addition, it was found that by increasing the pH, the adsorbed amount of Cu2+ ions and the value of the adsorption constant increase, whereas the value of the lateral interaction energy decreases.

Synergistic Effect of Rhamnolipid and Saponin Biosurfactants on Removal of Heavy Metals from Oil Contaminated Soils

2020 ◽  
Vol 57 (2) ◽  
pp. 109-114
Author(s):  
Amirhossein Dolatzadeh khiyavi ◽  
Reza Hajimohammadi ◽  
Hossein Amani ◽  
Hadi Soltani
Keyword(s):  
Heavy Metals ◽  
Synergistic Effect ◽  
Contaminated Soils ◽  
Removal Of Heavy Metals
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