scholarly journals Particle Size and Potential Toxic Element Speciation in Municipal Solid Waste Incineration (MSWI) Bottom Ash

2021 ◽  
Vol 13 (4) ◽  
pp. 1911
Author(s):  
Luciana Mantovani ◽  
Mario Tribaudino ◽  
Chiara De Matteis ◽  
Valerio Funari

The speciation of potentially toxic elements (PTE) in bottom ashes from municipal solid waste incineration (MSWI) and their relationship with grain size is investigated. The proposed enrichment of several potential toxic elements in lower sized grains is discussed, comparing the literature and new data on Parma’s waste incinerator. Results from X-ray fluorescence spectrometry (XRF), SEM-EDS, and XRD analyses on different grain size show (1) a positive Si-trend, correlated with grain size and few lithophile elements, such as Zr and Rb. In Parma, Al, K, Mg, and Fe also correlate with Si for the portion below 2 mm; (2) a Ca-trend, with a strong negative correlation with Si and a positive correlation with loss on ignition (LOI), S, Cl, Ti, Zn, Pb, and Sn. Mineralogical composition shows a little change in grain size, as in previous investigations, but with substantial differences in amorphous content. SEM-EDS analysis shows that the amorphous portion is highly heterogeneous, with portions coming from melting during incineration, residual glass, and unburnt loss on ignition (LOI). The above results show that PTE elements are either present as metals (such as Cu and Ni, or Zn, Pb and Sn) in carbonate, sulfate, and amorphous residual LOI portions.

Resources ◽  
2020 ◽  
Vol 9 (6) ◽  
pp. 66 ◽  
Author(s):  
Iveta Vateva ◽  
David Laner

Municipal solid waste incineration (MSWI) is a major element of modern waste management and produces annually around 5.7 million tonnes of bottom ash (BA) in Germany. In order to save natural resources and protect the environment, utilisable materials need to be recovered from BA. It was the aim of the present study to determine metal and mineral resource potentials of MSWI BA based on a characterisation study of raw and aged BA of the MSWI plant in Kassel (Germany). The BA investigated consisted of 82.2% mineral materials, 16.3% metals, and 1.5% unburnt organic matter. Overall, 12.1% and 3.6% of the MSWI BA were theoretically recoverable as native ferrous (Fe) and non-ferrous (NFe) metals, respectively. Assuming state-of-the-art recovery technology, 10.7% and 2.0% of the BA were actually extractable as Fe and NFe metals. The processed BA, as a mixture, did not comply with current German limit values for use as a construction material mainly due to excessive soluble salt contents. Coarser grain size fractions were less contaminated, resulting in a utilisable potential of less than 30% of the BA as a construction material. Hence, grain-size specific processing routes need to be developed for MSWI BA to fully exploit its mineral resource potential.


2021 ◽  
Vol 121 ◽  
pp. 33-41
Author(s):  
Yanjun Hu ◽  
Lingqin Zhao ◽  
Yonghao Zhu ◽  
Bennong Zhang ◽  
Guixiang Hu ◽  
...  

Buildings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 179
Author(s):  
Jad Bawab ◽  
Jamal Khatib ◽  
Said Kenai ◽  
Mohammed Sonebi

Waste management is a vital environmental issue in the world today. Municipal solid wastes (MSWs) are discarded in huge quantities on a daily basis and need to be well controlled. Incineration is a common method for reducing the volume of these wastes, yet it produces ashes that require further assessment. Municipal solid waste incineration bottom ash (MSWI-BA) is the bulk byproduct of the incineration process and has the potential to be used in the construction sector. This paper offers a review of the use of MSWI-BA as aggregates in cementitious materials. With the growing demand of aggregates in cementitious materials, MSWI-BA is considered for use as a partial or full alternative. Although the physical and chemical properties of MSWI-BA are different than those of natural aggregates (NA) in terms of water absorption, density, and fineness, they can be treated by various methods to ensure suitable quality for construction purposes. These treatment methods are classified into thermal treatment, solidification and stabilization, and separation processes, where this review focuses on the techniques that reduce deficiencies limiting the use of MSWI-BA as aggregates in different ways. When replacing NA in cementitious materials, MSWI-BA causes a decrease in workability, density, and strength. Moreover, they cause an increase in water absorption, air porosity, and drying shrinkage. In general, the practicality of using MSWI-BA in cementitious materials is mainly influenced by its treatment method and the replacement level, and it is concluded that further research, especially on durability, is required before MSWI-BA can be efficiently used in the production of sustainable cementitious materials.


2011 ◽  
Vol 474-476 ◽  
pp. 1099-1102
Author(s):  
Hai Ying Zhang ◽  
Yi Zheng ◽  
Hong Tao Hu ◽  
Jing Yu Qi

Bottom ash from municipal solid waste incineration (MSWI) has been previously suggested as an adsorbent for removing heavy metals from wastewater due to its high porosity and large surface area. In this study the adsorption characteristics of heavy metals were investigated using various particle sizes of MSWI bottom ash. The adsorption experiment was conducted using synthetic wastewater containing Cu, Zn, Pb and Cd as a function of residence time, initial pH, ash dosage and particle size, respectively. The adsorption rate increased with decreasing particle size and with increasing residence time. Through the above analysis, this work proved that bottom ash was effective in adsorbing the four heavy metals.


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