scholarly journals Geochemical Characteristics of Rare Earth Elements in Soils from Puding Karst Critical Zone Observatory, Southwest China

2019 ◽  
Vol 11 (18) ◽  
pp. 4963 ◽  
Author(s):  
Qian Zhang ◽  
Guilin Han ◽  
Man Liu ◽  
Lingqing Wang

Soil samples from eight soil profiles under different land-use types were collected at the Puding Karst Critical Zone Observatory, Southwest China, to investigate the distribution, fractionation, and controlling factors of rare earth elements (REEs). The total REEs contents in topsoil ranged from 149.97 to 247.74 mg kg−1, the contents in most topsoil were higher than local soil background value (202.60 mg kg−1), and the highest content was observed in topsoil under cropland. The REEs contents in surface soils from lower slopes sites were higher than that of middle and upper slope sites, and the highest contents were observed in cropland. The PAAS-normalized REEs pattern in soils showed MREEs significantly enriched relative to LREEs and HREEs, and HREEs were enriched relative to LREEs. The results showed that clay content, pH, soil organic carbon, total phosphorus, and Fe content were the main factors influencing the distribution of REEs in karst soils, and soil organic carbon (SOC), Fe content showed better linear relationship with REEs.

2019 ◽  
Vol 65 (No. 5) ◽  
pp. 253-259 ◽  
Author(s):  
Man Liu ◽  
Guilin Han ◽  
Zichuan Li ◽  
Qian Zhang ◽  
Zhaoliang Song

Soil organic carbon (SOC) sequestration in aggregates under land use change have been widely concerned due to intimate impacts on the sink (or source) of atmospheric carbon dioxide (CO<sub>2</sub>). However, the quantitative relationship between soil aggregation and SOC sequestration under land uses change has been poorly studied. Distribution of aggregates, SOC contents in bulk soils and different size aggregates and their contributions to SOC sequestration were determined under different land uses in the Puding Karst Ecosystem Observation and Research Station, karst Critical Zone Observatory (CZO), Southwest China. Soil aggregation and SOC sequestration increased in the processes of farmland abandonment and recovery. SOC contents in micro-aggregates were larger than those in macro-aggregates in restored land soils, while the opposite results in farmland soils were obtained, probably due to the hindrance of the C-enriched SOC transport from macro-aggregate into micro-aggregate by the disturbance of agricultural activities. SOC contents in macro-aggregates exponentially increased with their proportions along successional land uses. Macro-aggregates accounted for over 80% on the SOC sequestration in restored land soils, while they accounted for 31–60% in farmland soils. These results indicated that macro-aggregates have a great potential for SOC sequestration in karst soils.


2020 ◽  
Vol 12 (2) ◽  
pp. 457 ◽  
Author(s):  
Wenxiang Zhou ◽  
Guilin Han ◽  
Man Liu ◽  
Chao Song ◽  
Xiaoqiang Li

Exploring the distributions of rare earth elements (REEs) in soil profiles is essential to understanding how natural and anthropogenic factors influence the geochemical behaviors of REEs. This study aimed to learn about the distribution characteristics of REEs in soils, including their fractionation and enrichment, and to explore the influence of soil pH and soil organic carbon (SOC) on REEs. One hundred and three samples were collected from six soil profiles under different land uses (paddy field: T1, T3; forest land: T2, T6; wasteland: T4; building site: T5) in the Mun River Basin, Northeast Thailand. The average total REE contents (∑REE) are much lower (<80 mg kg−1) than that of Earth’s crust (153.80 mg kg−1) in soil profiles T2, T3, T4, and T6. The contents of REEs tend to increase slightly with depth in all soil profiles. The ratios of (La/Yb)N range from 0.35 to 0.96 in most samples, indicating that the enrichment of heavy REEs (HREEs) relative to light REEs (LREEs) is the main fractionation pattern. Samples from profile T2 show relatively obvious negative Ce anomalies (0.55–0.78) and positive Eu anomalies (1.41–1.56), but there are almost no anomalies of Ce and Eu in other soil profiles. Enrichment factors of LREEs (EFLREEs) range from 0.23 to 1.54 and EFHREEs range from 0.34 to 2.27, which demonstrates that all soil samples show no LREE enrichment and only parts of samples show minor HREE enrichment. Soil organic carbon (SOC) contents positively correlate with the enrichment factors of REEs (EFREE) in soil profiles T1 (R = 0.56, p < 0.01) and T6 (R = 0.71), while soil pH values correlate well with EFREE in soil profiles T2 (R = 0.75) and T4 (R = −0.66, p < 0.01), indicating the important influence of soil pH and SOC on the mobility of REEs in some soil profiles.


2021 ◽  
Vol 2021 ◽  
pp. 1-15
Author(s):  
Alice Mufur Magha ◽  
Primus Azinwi Tamfuh ◽  
Lionelle Estelle Mamdem ◽  
Marie Christy Shey Yefon ◽  
Bertrand Kenzong ◽  
...  

Water budgeting in agriculture requires local soil moisture information as crops depend mainly on moisture available at root level. The present paper aims to evaluate the soil moisture characteristics of Gleysols in the Bamenda (Cameroon) wetlands and to evaluate the link between soil moisture content and selected soil characteristics affecting crop production. The work was conducted in the field and laboratory, and data were analyzed by simple descriptive statistics. The main results showed that the soils had a silty clayey to clayey texture, high bulk density, high soil organic carbon content, and high soil organic carbon stocks. The big difference between moisture contents at wilting point and at field capacity testified to very high plant-available water content. Also, the soils displayed very high contents of readily available water and water storage contents. The soil moisture characteristics give sigmoid curves and enabled noting that the Gleysols attain their full water saturation at a range of 57.68 to 91.70% of dry soil. Clay and SOC contents show a significant positive correlation with most of the soil moisture characteristics, indicating that these soil properties are important for soil water retention. Particle density, coarse fragments, and sand contents correlated negatively with the soil moisture characteristics, suggesting that they decrease soil water-holding capacity. The principal component analysis (PCA) enabled reducing 17 variables described to only three principal components (PCs) explaining 73.73% of the total variance; the first PC alone expressed 45.12% of the total variance, associating clay, SOC, and six soil moisture characteristics, thus portraying a deep correlation between these eight variables. Construction of contoured ditches, deep tillage, and raised ridges management techniques during the rainy season while channeling water from nearby water bodies into the farmland, opportunity cropping, and usage of water cans and other irrigation strategies are used during the dry season to combat water constraints.


CATENA ◽  
2020 ◽  
Vol 194 ◽  
pp. 104650
Author(s):  
Aimin Chen ◽  
Zhengang Wang ◽  
Yongming Lin ◽  
Xiang Wang ◽  
Yanfei Li ◽  
...  

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